• Title/Summary/Keyword: Top coat

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Thermal Fatigue Behavior of Thermal Barrier Coatings by Air Plasma Spray (대기플라즈마 용사법으로 제조된 열차폐코팅의 열피로특성 평가)

  • Lee, Han-sang;Kim, Eui-hyun;Lee, Jung-hyuk
    • Korean Journal of Metals and Materials
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    • v.46 no.6
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    • pp.363-369
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    • 2008
  • Effects of top coat morphology and thickness on thermal fatigue behavior of thermal barrier coatings (TBC) were investigated in this study. Thermal fatigue tests were conducted on three coating specimens with different top coat morphology and thickness, and then the test data were compared via microstructures, cycles to failure, and fracture surfaces. In the air plasma spray specimens (APS1, APS2), top coat were 200 and $300{\mu}m$ respectively. The thickness of top coat was about $700{\mu}m$ in the perpendicular cracked specimen (PCS). Under thermal fatigue condition at $1,100^{\circ}C$, the cycles to top coat failure of APS1, APS2, and PCS were 350, 560 and 480 cycles, respectively. The cracks were initiated at the interface of top coat and thermally grown oxide (TGO) and propagated into TGO or top coat as the number of thermal fatigue cycles increased. For the PCS specimen, additive cracks were initiated and propagated at the starting points of perpendicular cracks in the top coat. Also, the thickness of TGO and the decrease of aluminium concentration in bond coat do not affect the cycles to failure.

A Study on the Adhesion Strength and Residual Stress Measurement of Plasma Sprayed Cr$_3$C$_2$-NiCr Coating (크롬탄화물 용사피막의 접착력 및 잔류응력측정에 관한 연구)

  • ;;Kim, E. H.;Kwun, S. I.
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.43-52
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    • 1996
  • The plasma sprayed Cr$_{2}$C$_{2}$-NiCr coatings are widely used as wear-resistant and corrosion-resistant materials. The mechanical properties of the plasma sprayed Cr$_{2}$C$_{2}$-NiCr coatings were examined in this study. The distribution of the residual stress with the coating thickness was also examined by X-ray diffraction method. The pore in the coatings could be classified into two types ; one is the intrinsic pore originated from the spraying powder, the other is the extrinsic pore formed during spraying. During the tensile adhesion test, the fracture occurred at the interface of top coat and substrate or top coat and bond coat depending on the existence of bond coat. It was found that the compressive residual stress near the interface decreased with the increase of the top coat thickness. The tensile adhesion strength of the coating without bond coat was higher than that with bond coat, because the coating with bond coat has higher horizontal crack density near the interface between bond coat and top coat.

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A Study on the Effects of the Thickness of Top Coat on the Thermal Stresses of a Sprayed Thermal Barrier Coating (용사 열차폐 코팅층의 두께가 열응력에 미치는 영향)

  • 김형남;양승한
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.223-225
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    • 2004
  • Based on the principle of complementary energy an analytical method is developed for determining thermal stress distribution in an thermal barrier coating. This method gives the stress distributions which satisfy the stress-free boundary conditions at the edge. Numerical examples are given in order to verify the method and to investigate the thickness effects of the ZrO$_2$-8wt%Y$_2$O$_3$ top coat on the integrity of thermal barrier coating consisted of IN738LC substrate and MCrAlY bond coat.

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Effect of Oxidation of Bond Coat on Failure of Thermal Barrier Coating (Bond Coat의 산화가 Thermal Barrier Coating의 파괴에 미치는 영향)

  • 최동구;최함메;강병성;최원경;최시경;김재철;박영규;김길무
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.88-94
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    • 1997
  • The oxidation behavior of the NiCrAlY bond coat and thermal fatigue failure in the plasma-sprayed thermal barrier coating system, ZrO2.8wt%Y2O3 top coat/Ni-26Cr-5Al-0.5Y bond coat/Hastelloy X superalloy substrate, in commercial use for finned segment of gas turbine burner were investigated. The main oxides formed in the bond coat were NiO, Cr2O3, and Al2O3. It divided the oxide distribution at this interface into two types whether an Al2O3 thin layer existed beneath ZrO2/bond coat interface before operation at high temperature or not. While a continuous layer of NiO was formed mainly in the region where the Al2O3 thin layer was present, the absence of it resulted in the formation of mixture of Cr2O3 and Al2O3 beneath NiO layer. Analyses on the fracture surface of specimen spalled by thermal cycling showed that spalling occurred mainly along the ceram-ic coat near ZrO2/bond coat oxide layer interface, but slightly in the oxide layer region.

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Corrosion Resistance of Non-Chrome Magni 565 Coating and Characteristics of Its Coating Film (Non-Chrome Magni 565 코팅 피막의 특성과 내식성)

  • Kim, Sang-Su;Jeong, Byeong-Ho;Mun, Myeong-Jun;Kim, Mu-Gil
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.4
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    • pp.200-207
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    • 2006
  • In addition to the basic properties of the base and top coating agents, corrosion resistance of non-chrome magni 565 coating and characteristics of coating film when coated to steel substrate were studied. The system had a good wettability at room temperature. Moreover, both the contact angle and surface tension were affected little by the viscosity of coating agent and surface roughness of the steel substrate. And the samples coated with optimal conditions showed a great corrosion resistance in salt spray test with 1500 hours or longer of initial appearance time of rust. The coating film was composed of overlapping layer of zinc and aluminium flakes, and the thickness of base coat increased with an increase of base coat viscosity. Based on the C-F peaks of 1,1-Difluoroethaen homo-polymer, it was thought that the base coat was an inorganic polymer bond layer. Meanwhile, the top coat showed C-F peaks of polytetrafluoroethylene with C-H peaks of phenol in FT-IR analysis. From the lower weight loss of base coat in TG analysis, it was thought that cross linking density of base coat was larger than that of top coat. It was thought that the small exothermic reactions observed in DSC curves were due to the thermosetting resins contained in the coating agents. Compared to the non-coated specimen, the coated sample showed more higher polarization resistance and corrosion potential with lower corrosion current density.

Hot Corrosion and Thermally Grown Oxide Formation on the Coating of Used IN738LC Gas Turbine Blade (사용된 IN738LC 가스 터빈 블레이드 코팅층의 고온 부식 및 Thermally Grown Oxide 형성 거동)

  • Choe, Byung Hak;Han, Sung Hee;Kim, Dae Hyun;Ahn, Jong Kee;Lee, Jae Hyun;Choi, Kwang Su
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.200-209
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    • 2022
  • In this study, defects generated in the YSZ coating layer of the IN738LC turbine blade are investigated using an optical microscope and SEM/EDS. The blade YSZ coating layer is composed of a Y-Zr component top coat layer and a Co component bond coat layer. A large amount of Cr/Ni component that diffused from the base is also measured in the bond coat. The blade hot corrosion is concentrated on the surface of the concave part, accompanied by separation of the coating layer due to the concentration of combustion gas collisions here. In the top coating layer of the blade, cracks occur in the vertical and horizontal directions, along with pits in the top coating layer. Combustion gas components such as Na and S are contained inside the pits and cracks, so it is considered that the pits/cracks are caused by the corrosion of the combustion gases. Also, a thermally grown oxide (TGO) layer of several ㎛ thick composed of Al oxide is observed between the top coat and the bond coat, and a similar inner TGO with a thickness of several ㎛ is also observed between the bond coat and the matrix. A PFZ (precipitate free zone) deficient in γ' (Ni3Al) forms as a band around the TGO, in which the Al component is integrated. Although TGO can resist high temperature corrosion of the top coat, it should also be considered that if its shape is irregular and contains pore defects, it may degrade the blade high temperature creep properties. Compositional and microstructural analysis results for high-temperature corrosion and TGO defects in the blade coating layer used at high temperatures are expected to be applied to sound YSZ coating and blade design technology.

Growth Behavior of Thermally Grown Oxide Layer with Bond Coat Species in Thermal Barrier Coatings

  • Jung, Sung Hoon;Jeon, Soo Hyeok;Park, Hyeon-Myeong;Jung, Yeon Gil;Myoung, Sang Won;Yang, Byung Il
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.344-351
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    • 2018
  • The effects of bond coat species on the growth behavior of thermally grown oxide (TGO) layer in thermal barrier coatings (TBCs) was investigated through furnace cyclic test (FCT). Two types of feedstock powder with different particle sizes and distributions, AMDRY 962 and AMDRY 386-4, were used to prepare the bond coat, and were formed using air plasma spray (APS) process. The top coat was prepared by APS process using zirconia based powder containing 8 wt% yttria. The thicknesses of the top and bond coats were designed and controlled at 800 and $200{\mu}m$, respectively. Phase analysis was conducted for TBC specimens with and without heat treatment. FCTs were performed for TBC specimens at $1121^{\circ}C$ with a dwell time of 25 h, followed by natural air cooling for 1 h at room temperature. TBC specimens with and without heat treatment showed sound conditions for the AMDRY 962 bond coat and AMDRY 386-4 bond coat in FCTs, respectively. The growth behavior of TGO layer followed a parabolic mode as the time increased in FCTs, independent of bond coat species. The influences of bond coat species and heat treatment on the microstructural evolution, interfacial stability, and TGO growth behavior in TBCs are discussed.

A Study on Suitable the Amount of Consumption of 2K Urethane Paint (2액형 우레탄도료의 적정 소모량 연구)

  • You, Chang-Bae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.130-135
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    • 2010
  • Paint is used as top coat in Automobile Refinishing that is divided into 1K paint of base type and 2K paint of urethane type. after using 1K paint, it can be reusable. However 2K paint is not available that is mixed a certain amount of base with hardner, so 2K paint has to be used all at a time or discarded the rest. This study covered that colored Urethane paint and colorless urethane paint in top coating process of AR. Top coat urethane paint is divided into colored urethane paint and transparent urethane paint like clear coat. Colored urethane paint is used for paint that contains resin, pigment, solvent and additives. It is color such as black and white. While transparent urethane paint is used for paint that contains resin, solvent and additives. Urethane paint has a paint system that cur after several hours of mixing base and hardner. By a paint technician of a field and empirical data, we can also recognize that according to worker's paint style and experience, although he or she paint same car model and area, paint use of one's is different. There aren't guidelines workers refer to about paint use by car models and work scope because ARP works various car models that are in different color, size and area. After using urethane paint, the rest of paint has come, and there are highs and lows in paint use each time he or she works. Therefore, this study suggest a basic guideline to use paint efficiently and regularly by understanding area, the type of work, and paint use that are appropriate for each car model and regardless of workers and work scopes in AR.

An Experimental Evaluation on Performance of Surface Protector for Concrete Structures (콘크리트 구조물 표면 보호재의 성능에 대한 실험적 평가)

  • Nam, Yong-Hyuk;Chung, Young-Jun;Jang, Suk-Hwan;An, Young-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.157-163
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    • 2006
  • This study is on the evaluation of double surface protection method using water repellent primer and final top coat to protect concrete. Water repellent agent has been applied on the final top coat to protect concrete. However, to make up for the weakness to the ultraviolet of the water repellent, the work procedure of these protectors is done vice versa. This combination of protectors was compared with existing ones in this study. Even though the final top coat was applied on the water repellent primer, its adhesive strength met to KS F 4936-' 03 with other protectors used in this study. All surface protectors used in this study were excellent in protecting concrete. Especially, in case of applying with final top coat in conjunction with water repellent primer, the resistance against chloride ion penetration and neutralization by $CO_2$ was more efficient than other surface protectors used in this study under this given condition.

A Study on the Dancing & Music Various Kinds of Entertainer's Constumes of Ancient China(2-3) -Focusing on the various kinds of entertainter's costumes of han dynasty- (중국의 무악.백희연예인 복식에 관한 연구(2-3) - 한대의 백희 연예인 복식을 중심으로 -)

  • 임명미
    • Journal of the Korean Society of Costume
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    • v.49
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    • pp.5-24
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    • 1999
  • The results from the consideration of this are as follows. 1. Various kindes of entertainments were beganed by common peoples of old china. 2. From the Han dynasty Various kindes of entertainments are devided into the classic dance and music which was performed courtesy ceremonial meetings of ancient china. 3. Traditional drama dance and musics performed art by artist of old china was called collectively "Various kindes of Entertainments(百戱)" 4. After unification of Han dynasty many commercial men and artist come from western to China therefore western music dance and drama acrobatic magic flowered into the old china so "Various kindes of Entertainments(百戱)" items was abundant. "Various kindes of Entertainments(百戱)" items as follows: 1) dramas 2) horsemanships. 3) acrobatics 4) magics 5) masked dramas. 5. "Various kinds of Entertainments" artist's costumes as follows: 1)For mens: *Old-china's "Various kindes of Entertainments" artist's costumes of Han-dynasty was Chin hyun-Kwan(진현관) right handed neck collor long coat narrow trousers belt just simmillar is official's dress of Han dynasty. *Various kindes of Entertainments(百戱)" artist's costumes of Westerner's dress is high top hats, lace trimminged round-necklong coat trimminged belt narrow trousers. *Another weaterner's dress is long striped patterned knee-lengh coat narrow trousers *opened top body and wearing narrow pantaloon short skirt short trousers. 2) For females: (1) Hair style is high top hair style twin high top hair style birds hair decorated high top hair style ribbon dressed high top hair style (2) Dress is knee-lengh one-piece west0-lengh jaket and knee-lengh skirt one-piece and short trousers scarf hart sleeved jaket narrow pantallons. "Various kindes of Entertainments(百戱)" artist's costumes influenced from royal families costumes to common peoples costumes without concern of that one's social positionon peoples costumes without concern of that one's social position.

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