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Activation of persulfate by UV and Fe2+ for the defluorination of perfluorooctanoic acid

  • Song, Zhou;Tang, Heqing;Wang, Nan;Wang, Xiaobo;Zhu, Lihua
    • Advances in environmental research
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    • v.3 no.3
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    • pp.185-197
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    • 2014
  • Efficient defluorination of perfluorooctanoic acid (PFOA) was achieved by integrating UV irradiation and $Fe^{2+}$ activation of persulfate ($S_2O{_8}^{2-}$). It was found that the UV-$Fe^{2+}$, $Fe^{2+}-S_2O{_8}^{2-}$, and UV-$S_2O{_8}^{2-}$ processes caused defluorination efficiency of 6.4%, 1.6% and 23.2% for PFOA at pH 5.0 within 5 h, respectively, but a combined system of UV-$Fe^{2+}-S_2O{_8}^{2-}$ dramatically promoted the defluorination efficiency up to 63.3%. The beneficial synergistic behavior between $Fe^{2+}-S_2O{_8}^{2-}$ and UV-$S_2O{_8}^{2-}$ was demonstrated to be dependent on $Fe^{2+}$ dosage, initial $S_2O{_8}^{2-}$ concentration, and solution pH. The decomposition of PFOA resulted in generation of shorter-chain perfluorinated carboxylic acids (PFCAs), formic acid and fluoride ions. The generated PFCAs intermediates could be further defluorinated by adding supplementary $Fe^{2+}$ and, $S_2O{_8}^{2-}$ and re-adjusting solution pH in later reaction stage. The much enhanced PFOA defluorination in the UV-$Fe^{2+}-S_2O{_8}^{2-}$ system was attributed to the fact that the simultaneous employment of UV light and $Fe^{2+}$ not only greatly enhanced the activation of $S_2O{_8}^{2-}$ to form strong oxidizing sulfate radicals ($SO{_4}^{\cdot-}$), but also provided an additional decarboxylation pathway caused by electron transfer from PFOA to in situ generated $Fe^{3+}$.

A Study on the Engineering Properties of Alluvial clay in the Daebul Reclaimed Tideland (대불간척지 충적점토의 공학적 특성에 관한 연구)

  • 김홍일;진병익;유기송
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.26 no.1
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    • pp.29-37
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    • 1984
  • This study was made to find several significant relations among various physical and mechanical properties including cone penetration resistance. The alluvial clay samples were taken at the Daebul Reclaimed Tideland in Samhomyeon, Yeongamgun, Jeonranamdo. The results of the study are summarized as follows; 1.Most samples belong to medium or high plastic, inorganic, silty clay(clay contents;32-64%, silt contents; 36-68%, sand contents; 0-3%). The specific gravities range from 2.70 to 2.73, the unit weights from 1.45 to 1. 75g/cm$^3$, the natural moisture contents from 45 to 77%, the liquid limits from 32 to 56%. It is certain that the foundation is weak because the natural moisture contents are much higher than the liquid limits. 2.It is known from the shear tests that the unconfined compression strenghs vary from 0.09 to 0. 38kg/cm2, the cohesions from 0.05 to 0. 21kg/cm2, the internal friction angles from 0 to 3˚. 3.The consolidation tests show that the initial void ratios range from 1.25 to 2.28, the compression indeices from 0.43 to 0.84, the preconsolidation loads from 0.21 to 0.74kg/cm$^2$. 4.Cone penetration resistances are usually less than 5kg/cm$^2$ from ground surface to the depth of about 8m, and from S to l0kg/cm$^2$ in the layer below about 8m to hard layer. 5.The cohesion and cone penetration resistance are in proportion to the depth of soil layer. 6.The correlations between various physical and mechanical properties including cone penetration resistance for the alluvial clay samples are as follows; a) Wn=0.944C+ l2.733 (r=0.829) b) LL=0. 728Cy+6. 991 (r=0. 873) c) PI=0.659Cy-8.168 (r=0.860) d) rt=0. 0077(272-Wn) =2.092-0. 0077Wn (r=0. 859) e) 60=0. 035wn-0 447 (r=0. 893) f) C=0.380qw+0.031 (r=0.816) g) qu=0.0707qc+0.029 (r=0.810) h) C=0.018Z+0.055 (r=O.802) I) qc=0. 415Z+1, 438 (r=0. 943)

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Ratio of fat to energy intake independently associated with the duration of diabetes and total cholesterol levels in type 2 diabetes

  • Yim, Jung-Eun;Kim, Young-Seol;Cho, Mi-Ran;Choue, Ryo-Won
    • Nutrition Research and Practice
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    • v.5 no.2
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    • pp.157-162
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    • 2011
  • The importance of dietary intake in the treatment of type 2 diabetes was emphasized. This study was performed to investigate the dietary intakes of Korean type 2 diabetes patients according to the treatment and duration of diabetes and to examine the relationships between their diet and serum lipid profiles. The subjects were 111 type 2 diabetic patients who were treated by medical nutrition therapy only, oral hypoglycemic agents (OHA), or insulin with medical nutrition therapy. Dietary intake was assessed by a registered dietitian using semi-quantitative food frequency questionnaires Comparisons according to treatment type were made using covariance analyses. General linear models identified the independent effects of the different treatments after covarying for age, duration of diabetes, and 2-way interactions. There were no significant differences in age and BMI but was in duration of diabetes according to treatment type in these subjects. Carbohydrate to energy ratio was higher in the OHA group (P < 0.05), whereas the fat to energy ratio was higher in the insulin group for males (P < 0.05). Carbohydrate ($R^2$ = 0.24, P = 0.005) and fat ($R^2$ = 0.26, P = 0.02) to energy ratios were independently associated with the duration of diabetes after covarying for age, sex, treatment, and 2-way interactions. The levels of triglyceride (TG; $R^2$ = 0.32, P = 0.02) and total cholesterol (TC) were associated independently with energy intake and the carbohydrate ($R^2$ = 0.15, P = 0.02) and fat ($R^2$ = 0.15, P = 0.01) to energy ratios, respectively. The concern that the independent association of dietary intake with either duration of diabetes or dietary factors affects blood lipid levels could suggest that specific dietary recommendations may work better for identifiable groups of diabetes patients.

Effects of Air Pressure on the Fabrication of Nano-Sized Tin Oxide Powder by Spray Pyrolysis Process (분무열분해 공정에 의한 주석산화물 나노분체 제조에 미치공기압력의 영향)

  • Yu, Jae-Keun;Kim, Dong-Hee
    • Korean Journal of Materials Research
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    • v.21 no.12
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    • pp.690-696
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    • 2011
  • In this study, nano-sized tin oxide powder with an average particle size of below 50 nm is prepared by the spray pyrolysis process. The influence of air pressure on the properties of the generated powder is examined. Along with the rise of air pressure from $0.1kg/cm^2$ to $3kg/cm^2$, the average size of the droplet-shaped particles decreases, while the particle size distribution becomes more regular. When the air pressure increases from $0.1kg/cm^2$ to $1kg/cm^2$, the average size of the dropletshaped particles, which is around 30-50 nm, shows hardly any change. When the air pressure increases up to $3kg/cm^2$, the average size of the droplet-shaped particles decreases to 30 nm. For the independent generated particles, when the air pressure is at $0.1kg/cm^2$, the average particle size is approximately 100 nm; when the air pressure increases up to $0.5kg/m^2$, the average particle size becomes more than 100 nm, and the surface structure becomes more compact; when the air pressure increases up to $1kg/cm^2$, the surface structure is almost the same as in the case of $0.5kg/cm^2$, and the average particle size is around 80- 100 nm; when the air pressure increases up to $3kg/cm^2$, the surface structure becomes incompact compared to the cases of other air pressures, and the average particle size is around 80-100 nm. Along with the rise of air pressure from $0.1kg/cm^2$ to $0.5kg/cm^2$, the XRD peak intensity slightly decreases, and the specific surface area increases. When the air pressure increases up to $1kg/cm^2$ and $3kg/cm^2$, the XRD peak intensity increases, while the specific surface area also increases.

Low-intensity Oral Anticoagulation Versus High-intensity Oral Anticoagulation in Patients with Mechanical Bileaflet Prosthetic Heart Valves (이엽성 기게 심장판막 환자에 대한 낮은 강도의 항응고제 요법의 결과에 대한 임상분석)

  • Jeong, Seong-Cheol;Kim, Mi-Jung;Song, Chang-Min;Kim, Woo-Shik;Shin, Yong-Chul;Kim, Byung-Yul
    • Journal of Chest Surgery
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    • v.41 no.4
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    • pp.430-438
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    • 2008
  • Background: All the patients with mechanical valves require warfarin therapy in order to prevent them from developing thromboembolic complications. According to the ACC/AHA practice guidelines, after AVR with bileaflet mechanical prostheses in patients with no risk factors, warfarin is indicated to achieve an INR of 2.0 to 3.0. After MVR with any mechanical valve, warfarin is indicated to achieve an INR of 2.5 to 3.5. But in our clinical experience, bleeding complications (epistaxis, hematuria, uterine bleeding, intracerebral hemorrhage etc.) frequently developed in patients who maintained their INR within this value. So, we retrospectively reviewed the patients with bileaflet mechanical heart valve prosthesis and we determined the optimal anticoagulation value. Material and Method: From January 1984 to February 2007, 311 patients have been followed up at a national medical center. We classified the AVR patients (n=60) into three groups as follows: an INR from 1.5 to 2.0 in Group I, an INR from 2.0 to 2.5 in Group II and an INR from 2.5 to 3.0 in Group III. We classified the MVR (n=171) and DVR (n=80) patients into four groups as follows: an INR from 1.5 to 2.0 in Group I, an INR from 2.0 to 2.5 in Group II, an INR from 2.5 to 3.0 in Group III and an INR from 3.0 to 3.5 in Group III. We compared the groups for their thromboembolic and bleeding complications by means of the Kaplan Meier method. Result: In the AVR patients, 2 thromboembolic complications and 4 bleeding complications occurred and the log rank test failed to identify any statistical significance between the groups for thethromboembolic complication rate, but groups I and II had lower bleeding complication rates than did group III. Thirteen thromboembolic complication and 15 bleeding complication occurred in the MVR and DVR patients, and the log rank test also failed to identify statistical significance between the groups for the thromboembolic complication rate, but groups I and II had lower bleeding complication rates that did groups III and IV. Conclusion: The thromboembolic complication rate was not statistically different between groups I and II and groups III and IV, but the bleeding complication rates of groups I and II were lower than those of groups III and IV. So this outcome encouraged us to continue using our low intensive anticoagulation regime, that is, an INR of 1.5 to 2.5.

Mechanical Properties of the Ceramics of the System Al2O3-ZrO2-Y2O3 Prepared by the Precipitation Method (침전법에 의한 Al2O3-ZrO2-Y2O3계 세라믹스의 기계적 특성)

  • 김준태;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.364-372
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    • 1988
  • The mechanical properties and microstructure of ceramics of the system Al2O3-ZrO2-Y2O3 sintered at 1$650^{\circ}C$ for 2h after powder preparation by the precipitation method from Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were investigated. The Al2O3-ZrO2-Y2O3 ceramics sintered at 1$650^{\circ}C$ for 2h after mixing alpha-Al2O3 and ZrO2-Y2O3 powders, both were separately precipitated and calcined, were found to have the relative density higher than 97.5% so that the strengthening and toughening mechanisms could be explained mainly as the stress-induced phase transformation. On the other hand, the sintered bodies prepared by co-precipitating the three starting materials were measured to have the relative density lower than 85% so that the degradation of strength were observed above 15 vol% ZrO2 contents due to the high porosity by which the effect of stress-induced phase transformation was assumed to be depressed.

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A Study on Location-based Routing Technique for Improving the Performance of P2P in MANET (MANET에서 P2P 성능 향상을 위한 위치기반 라우팅 기법에 관한 연구)

  • Yang, Hwanseok
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.11 no.2
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    • pp.37-45
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    • 2015
  • The technology development of MANET and dissemination of P2P services has been made very widely. In particular, the development of many application services for the integration of P2P services in MANET has been made actively. P2P networks are commonly used because of the advantages of efficient use of network bandwidth and rapid information exchange. In P2P network, the infrastructure managing each node in the middle does not exist and each node is a structure playing a role as the sender and receiver. Such a structure is very similar to the structure of the MANET. However, it is difficult to provide reliable P2P service due to the high mobility of mobile nodes. In this paper, we propose location-based routing technique in order to provide efficient file sharing and management between nodes. GMN managing the group is elected after network is configured to the area of a certain size. Each node is assigned an identifier of 12 bit dynamically to provide routing which uses location information to the identifier. ZGT is managed in the GMN in order to provide management of group nodes and distributed cache information. The distributed cache technique is applied to provide a rapid retrieval of the sharing files in the each node. The excellent performance of the proposed technique was confirmed through experiments.

Neural Network Tuning of the 2-DOF PID Controller With a Combined 2-DOF Parameter For a Gas Turbine Generating Plant

  • Kim, Dong-Hwa
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.1 no.1
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    • pp.95-103
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    • 2001
  • The purpose of Introducing a combined cycle with gas turbine in power plants is to reduce losses of energy, by effectively using exhaust gases from the gas turbine to produce additional electricity or process. The efficiency of a combined power plant with the gas turbine increases, exceeding 50%, while the efficiency of traditional steam turbine plants is approximately 35% to 40%. Up to the present time, the PID controller has been used to operate this system. However, it is very difficult to achieve an optimal PID gain without any experience, since the gain of the PID controller has to be manually tuned by trial and error procedures. This paper focuses on the neural network tuning of the 2-DOF PID controller with a combined 2-DOF parameter (NN-Tuning 2-DOF PID controller), for optimal control of the Gun-san gas turbine generating plant in Seoul, Korea. In order to attain optimal control, transfer function and operating data from start-up, running, and stop procedures of the Gun-san gas turbine have been acquired and a designed controller has been applied to this system. The results of the NN-Tuning 2-DOF PID are compared with the PID controller and the conventional 2-DOF PID controller tuned by the Ziegler-Nichols method through experimentation. The experimental results of the NN-Tuning 2-DOF PID controller represent a more satisfactory response than those of the previously-mentioned two controllers.

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Influence of KOH Solution on the Passivation of Al2O3 Grown by Atomic Layer Depostion on Silicon Solar Cell

  • Jo, Yeong-Jun;Jang, Hyo-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.299.2-299.2
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    • 2013
  • We investigated the potassium remaining on a crystalline silicon solar cell after potassium hydroxide (KOH) etching and its effect on the lifetime of the solar cell. KOH etching is generally used to remove the saw damage caused by cutting a Si ingot; it can also be used to etch the rear side of a textured crystalline silicon solar cell before atomic layer-deposited Al2O3 growth. However, the potassium remaining after KOH etching is known to be detrimental to the efficiency of Si solar cells. In this study, we etched a crystalline silicon solar cell in three ways in order to determine the effect of the potassium remnant on the efficiency of Si solar cells. After KOH etching, KOH and tetramethylammonium hydroxide (TMAH) were used to etch the rear side of a crystalline silicon solar cell. To passivate the rear side, an Al2O3 layer was deposited by atomic layer deposition (ALD). After ALD Al2O3 growth on the KOH-etched Si surface, we measured the lifetime of the solar cell by quasi steady-state photoconductance (QSSPC, Sinton WCT-120) to analyze how effectively the Al2O3 layer passivated the interface of the Al2O3 layer and the Si surface. Secondary ion mass spectroscopy (SIMS) was also used to measure how much potassium remained on the surface of the Si wafer and at the interface of the Al2O3 layer and the Si surface after KOH etching and wet cleaning.

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Development of GHG Reduction Technology by Collecting Greenhouse Gas (CO2) in Livestock Facilities and Supply of Facility House (축산시설 내 온실가스(CO2) 포집 및 시설하우스 공급을 통한 온실가스 저감기술 개발)

  • Nah, Gyu Dong;Cho, Man Su
    • Journal of Environmental Health Sciences
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    • v.44 no.6
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    • pp.599-607
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    • 2018
  • Objectives: Carbon dioxide ($CO_2$) may be one of the biggest causes of climate change. The purposes of this study were to reduce greenhouse gases and to increase strawberry production by developing the supply devices in livestock facilities using the membrane technology Methods: Carbon dioxide was collected from beside to livestock facilities. The injection of $CO_2$ was stopped when it reached 1,000 ppm in the facility house. Case group with injection of $CO_2$ was compared to control group with normal environment. The experiments were conducted for 8 days from December 11, 2017. Results: Total strawberry production was found to be 1,317 kg in the case group and 1,176 kg in the control group. The correlation between $CO_2$ and crop yields has led to some statistical evidence that carbon dioxide helps to grow (${\beta}=0.832$, p<0.05). Conclusions: This study identified the potential for efforts to reduce the $CO_2$ in farming households. Increased concentrations of $CO_2$ have shown that strawberries have a better growth condition. In addition, it can be explained that the plants need wide leaves to quickly absorb much $CO_2$.