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Tin Oxide-modulated to Cu(OH)2 Nanowires for Efficient Electrochemical Reduction of CO2 to HCOOH and CO (SnO2/Cu(OH)2 Nanowires 전극을 이용한 전기화학적 이산화탄소 환원 특성)

  • Chaewon Seong;Hyojung Bae;Sea Cho;Jiwon Heo;Eun Mi Han;Jun-Seok Ha
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.91-97
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    • 2023
  • Electrochemical (EC) CO2 reduction is a promising method to convert CO2 into valuable hydrocarbon fuels and chemicals ecofriendly. Here, we report on a facile method to synthesize surface-controlled SnO2/Cu(OH)2 nanowires (NWs) and its EC reduction of CO2 to HCOOH and CO. The SnO2/Cu(OH)2 NWs (-16 mA/cm2) showed superior electrochemical performance compared to Cu(OH)2 NWs (-6 mA/cm2) at -1.0 V (vs. RHE). SnO2/Cu(OH)2 NWs showed the maximum Faradaic efficiency for conversion to HCOOH (58.01 %) and CO (29.72 %). The optimized catalyst exhibits a high C1 Faradaic efficiency stable electrolysis for 2 h in a KHCO3 electrolyte. This study facilitates the potential for the EC reduction of CO2 to chemical fuels.

The Oxidation of Kovar in Humidified $N_2$/H$_2$ Atmosphere (가습된 $N_2$/H$_2$혼합가스 분위기에서의 Kovar 산화 거동)

  • 김병수;김민호;김상우;최덕균;손용배
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.2
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    • pp.1-7
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    • 2001
  • In order to form a uniform oxidation layer of spinel phase on Kovar which helps the strong bonding in Kovar-to-glass sealing, the humidified $N_2/H_2$ was used as an oxidation atmosphere. The oxidation of Kovar was controlled by diffusion mechanism and the activation energy was 31.61 kacl/mol at 500~$800^{\circ}C$. After oxidation at $600^{\circ}C$, the external oxidation layer was below 0.5 $\mu \textrm{m}$ thick. According to TEM analysis, oxidized Kovar was spinel its lattice parameter of 7.9 $\AA$. Oxidation of under $600^{\circ}C$ and in a humidified $N_2/H_2$ atmosphere, Kovar was found to be appropriate for the Kovar-to-glass sealing.

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Joint Buying P2P System for User Convenient Social Network (사용자 편의적 소셜 네트워크 공동구매 P2P 시스템)

  • Kim, Boon-Hee
    • The Journal of the Korea institute of electronic communication sciences
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    • v.6 no.6
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    • pp.915-920
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    • 2011
  • P2P technology is the concept to share resources efficiently in distributed environments that a lot of research is underway. a lot. In these P2P systems, the server to support the contents-information have less overloads than the composed system as the server to have resources generally. In this paper, we suggest a P2P system to support conveniences to choice time for users that were connected with the information of joint-buying based on social network. Social networks based on co-purchasing information and price alerts using the P2P system is provided by the peer, this relay information is provided by the P2P server.

Fabrication of SnO2-TiO2-based Thick Films for Hydrocarbon Gas Sensors (탄화수소계 가스센서를 위한 SnO2-TiO2계 후막의 제조)

  • 정완영;박정은;강봉휘;이덕동
    • Journal of the Korean Ceramic Society
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    • v.28 no.9
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    • pp.721-729
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    • 1991
  • SnO2-TiO2(Pt or Pd), as raw material for hydrocarbon gas sensors, was prepared by a coprecipitation method. The SnO2-TiO2-based thick film gas sensors were made by screen printing technique. The titanium dioxide synthesized was shown to be anatase structure from XRD peaks and was transformed to rutile structure between 700$^{\circ}C$ and 1000$^{\circ}C$. Titanium dioxide in SnO2-TiO2 thick films devices plays a very important role in the enhancement of the sensitivity to CH4 and C4H10. In the case of SnO2-TiO2(Pt) sensors, titanium dioxide that was rutile structure enhanced the sensitivity of the thick film to CH4. Platinum added to the raw powder at coprecipitation (as chloroplatinic acid VI hydrate) improved the gas sensitivity to hydrocarbon gases. Therefore, it is expected that the SnO2-TiO2(Pt) thick film sensors fabricated in this experiment could be put into practical use as LPG (primary component : C4H10 and C3H8) and LNG (primary component : CH4) sensors.

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The Effect of Photocatalysis using $TiO_2$ and UV for COD Degradation of Wastewater in Linerboard Mill

  • Kang, Kwang-Ho;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.5
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    • pp.53-59
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    • 2008
  • This study was carried out to investigate the effect of photocatalysis using $TiO_2$ and UV applied for the COD reduction of wastewater in linerboard mill. Trials were done to obtain the optimum addition amounts of $TiO_2$ and $H_2O_2$ to the wastewater and find an appropriate pH condition for photocatalysis on $TiO_2$ for degrading COD. The photocatalytic reaction was applied to the wastewater collected after secondary activated sludge treatment in WWTP of linerboard mill. The optimum application of photocatalysis reaction was obtained under the addition conditions of 2 g/L of $TiO_2$ and 200 mg/L of $H_2O_2$ at pH 3.0, respectively. The removal efficiency of $SCOD_{Cr}$ by photocatalytic treatment was 86.4 % and higher than Fenton treatment in which removal efficiency was 67.4 %. It was concluded that the photocatalytic process using $TiO_2$ and UV could be applied to the wastewater treatment in linerboard mill and also to the dramatic drop-off in NBDCOD load from wastewater of tertiary treatment in WWTP.

Analysis on Properties of $TiO_2-Nb_2O_5$ Sol ($TiO_2-Nb_2O_5$ 솔의 물성에 대한 분석)

  • You, Do-Hyun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.349-353
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    • 2006
  • [ $TiO_2-Nb_2O_5$ ] sol was prepared using sol-gel method. Crystalline properties of gel powder changed from rutile phase to anatase phase with increasing $Nb_2O_5$ additives at $800^{\circ}C$, while they retained rutile phase regardless of $Nb_2O_5$ additives at $900^{\circ}C,\;1,000^{\circ}C$. They retained amorphous phase from $50^{\circ}C\;to\;400^{\circ}C$, retained anatase phase from $500^{\circ}C\;to\;600^{\circ}C$ and had rutile phase over $700^{\circ}C$ at 1mole% $Nb_2O_5$ additive. After $TiO_2-Nb_2O_5$ sol retained low viscosity with normal chain structure for a long time, its viscosity increased fast with network structure. DTA properties of gel powder had endothermic reaction due to evaporation of propanol and water about $78^{\circ}C$, had exothermic reaction due to propanol combustion about $290^{\circ}C$ and had exothermic reaction due to changing of $TiO_2$ phase about $640^{\circ}C$.

P2P System for Simultaneous Support of Menu and Social Network Joint Buying Information (메뉴와 소셜 네트워크 공동구매 정보 동시제공 P2P 시스템)

  • Kim, Boon-Hee
    • The Journal of the Korea institute of electronic communication sciences
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    • v.6 no.3
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    • pp.445-449
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    • 2011
  • A P2P technique is the concept to share sources efficiently in distributed environment that is studying a lot. In these P2P systems, the server to support the contents-information have less overloads than the composed system as the server to have resources generally. In this paper, we suggest a P2P system to support conveniences for users that were connected with the information of joint-buying based on social network. The joint-buying information based on social network is supported by peers using a p2p system and these information to intermediate are supported by a P2P server.

The Development of BIM Library for Building Life Cycle CO2 Assessment (건축물 전과정 $CO_2$ 평가를 위한 BIM 라이브러리 개발)

  • Lee, Byeong-Ho;Hong, Soung-Wook;Shin, Sung-Woo
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.2
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    • pp.67-76
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    • 2012
  • BIM and its quantity take-off widely apply to the construction projects and LCCO2 Assessment using the BIM's quantity take-off function can be tried recently. Because BIM modeling programs such as Revit and ArchiCAD do not provide adequate library for LCCO2 Assessment, quantity take-off data should be conversed and applied to Carbon Emission Coefficient using Excel program or manual work. Therefore, the purpose of this research is 1) to propose the Unit Conversion Systems for Carbon Emission Coefficient, 2) to provide basic library sets for BIM based LCCO2 Assessment method, and 3) to apply 11 material library sets on a apartment unit plan modeling to pursue the CO2 emission evaluation of the material production in the process of LCCO2 Assessment. Research results showed CO2 emission amount of 458.64kgCO2/m2 from the apartment unit plan modeling.

A Study of the Development of CVD Precursors III-Synthesis and Properties of New Lead $\beta$-diketonate Derivatives

  • 임종태;이중철;이완인;이익모
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.355-361
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    • 1999
  • To improve the volatility and stability of lead complexes, the principle of stabilization by saturating the metal coordination sphere by intramolecular coordination through a β-diketonates with an ethereal group has was tested. Several new lead complexes with alkoxyalkyl-substituted β-diketonates, Pb(R1C(O)CHC(O)(CH2)3OR2)2(Rl=t-Bu, Me, OMe, i-Pr, R2=Me, Et), or carboxylate, Pb(OC(O)(CH2)3OEt)2, were prepared by the reaction between Pb(OAc)2 and corresponding alkoxyalkyl-substituted β-diketonates, and they were found to have a viscous liquid phase. The nature of the head (β-diketonate or carboxylate) or tails and substituents of β-diketonates appeared not to be important for the formation of the liquid phase. It is worth mentioning that Pb(OAc)2, which has limited use due to its low solubility, was successfully adopted as a starting material for the preparation of new lead complexes. Easy hydrolysis, reaction with HCl, and 13C NMR spectra indicated that tail portions were not coordinated to the metal as a copper derivative, Cu(t-BuC(O)CHC(O)(CH2)3OMe)2. All these complexes were not volatile enough for the MOCVD experiments, but a methyl derivative, Pb(MeC(O)CHC(O)(CH2)3OEt)2, showed some sublimation. The methoxy derivative, Pb(MeOC(O)CHC(O)(CH2)3OEt)2, was thermally unstable due to possible equilibrium between species coordinating with a keto oxygen atom and an ethereal atom of a methoxy group, which was confirmed by IR and 13C NMR spectra.

Characterization of hrp2 + Gene Related to SNF2 Family in Schizosaccharomyces pombe (Schizosaccharomyces pombe에서 SNF2에 속하는 hrp2+ 유전자의 특성 연구)

  • Park, In-Soon
    • Environmental Mutagens and Carcinogens
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    • v.22 no.3
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    • pp.137-141
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    • 2002
  • The SNF2/SW12 family comprises proteins from a variety of species with in vivo functions, such as transcriptional regulation, maintenance of chromosome stability during mitosis, and various types of DNA repair. This study was shown the characterization of hrp2+ gene which was isolated by PCR amplification using the conserved domain of SNF2 motifs. Sequence analysis of hrp2+ gene showed striking evolutionary conservation among the SNF2 family of proteins. The transcript of hrp2+ gene was found to be a 4.7 kb as identified by Northern hybridization. In addition, to determine the transcription initiation site of hrp2+ gene, primer extension analysis was performed. This result showed the band of 64 bp. The transcriptional start point was mapped to a position of 47 base pair from the first ATG codon of translational initiation codon. In order to investigate the inducibility of hrp2+ gene, transcript levels were examined after treating the cells to various DNA damaging agents. The transcripts of hrp2+ were induced by UV-irradiation. But the transcripts were not induced by treatment of 0.25% Methylmethane sulfonate (MMS). These results implied that the effects of damaging agents are complex and different regulatory pathways exist for the induction of this gene.

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