• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.4
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• pp.27-37
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• 2008

It is most serious problem which is various occurs from the agricultural concrete structure and off shore concrete structure the problem which it comes to think is deterioration of the concrete which is caused with the corrosion of the reinforcing steel which is caused by with permeation of the water and the sea water. Specially the off shore concrete structure has been deteriorated by the steel reinforcement corrosion. The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. This study were accomplished to the estimate the diffusion coefficient of LMC, and the time dependent constants of diffusion. The average chloride diffusion coefficient was estimated. Also, the average chloride diffusion coefficient was compared with diffusion coefficient test results of 28 curing days. The test results indicated that the average chloride diffusion coefficient could closely estimate the test results of the diffusion coefficient test results of 28 curing days.

• Proceedings of the KSR Conference
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• 2008.11b
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• pp.1096-1101
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• 2008

Concrete is shown the time dependent behavior after placing. The time dependent behavior of normal strength concrete that is used usually in present, were already examined closely lots of parameters by several investigators. however, high strength concrete is that the material characteristics are not definite and the experimental data are lacking. So, The goal of this study is to propose the material characteristics models, and to develop the routine of the time dependent behavior above 60 MPa. The thermal conductivity, the specific heat, the moisture diffusion coefficient, and the surface coefficient are proposed the suitable models through the parametric study. The structural element is used the 8-node solid element. The matrix equation is developed considering the transient heat transfer and moisture diffusion theory. The application of the time dependent behavior is used the finite differential method.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.6
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• pp.49-60
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• 2008

This study were predicted the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC) which were applied the agricultural hydraulic concrete structures. Accelerated testing was accomplished to the evaluate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, the average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC were effected on the mix proportion factor including cement contents, latex content, and water-cement ratio. Especially, the average chloride diffusion coefficient, the corrosion threshold reached at reinforcement in LMC were affected by the all mix proportion factor.

• Honam Mathematical Journal
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• v.43 no.4
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• pp.667-678
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• 2021

Blow-up phenomena for a nonlocal reaction-diffusion system with time-dependent coefficients are investigated under null Dirichlet boundary conditions. Using Kaplan's method with the comparison principle, we establish new blow-up criteria and obtain the upper bounds for the blow-up time of the solution under suitable measure sense in the whole-dimensional space.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.259-268
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• 2016

The service life evaluation in RC(Reinforced Concrete) structure exposed to chloride attack can be classified into deterministic and probabilistic method, and it significantly varies with design parameters. The present work derives PDF (Probability of Durability Failure) and the related service life considering time-dependent diffusion coefficient and internal parameters such as reference diffusion coefficient, critical chloride content, and time-exponent. When critical chloride content increases to 133.3%, the changing ratios of service life are 134.0~145.4% for deterministic method and 149.2%~152.5% for probabilistic method, respectively. In the case of increasing time-exponent to 200%, they increase to 323.8% for deterministic method and 346.0% for probabilistic method. Through adopting time-diffusion coefficient for probabilistic method, reasonable service life evaluation can be achieved, and it is also verified that increasing time-exponent through mineral admixture is very effective to extension of service life in RC structure.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.5
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• pp.83-91
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• 2015

With varying conditions of concrete surface, induced chloride contents are changed and this is a key parameter for steel corrosion and service life in RC (Reinforced Concrete) structures. Many surface enhancement techniques using impregnation have been developed, however the evaluation techniques for chloride behavior through doubly layered media and time-dependent diffusion are rarely proposed. This paper presents an analysis technique considering double-layer concrete and time-dependent diffusion behavior, and the results are compared with those from the previous test results through reverse analysis. The chloride profiles from the surface-impregnated concrete exposed to atmospheric, tidal, submerged zone for 2 years are adopted. Furthermore surface chloride contents and diffusion coefficients are obtained, and are compared with those from Life365. Through consideration of time effect, the relative error decreases from 0.28 to 0.20 in atmospheric, 0.29 to 0.11 in tidal, and 0.54 to 0.40 in submerged zone, respectively, which shows more reasonable results. Utilizing the diffusion coefficients from Life365, relative errors increases and it needs deeper penetration depth (e) and lower diffusion coefficient ratio ($D_1/D_2$) due to higher diffusion coefficient.

• Journal of the Korea Concrete Institute
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• v.24 no.6
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• pp.715-726
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• 2012

Since strength and diffusion coefficient of concrete, representative concrete properties that in change with age, the time effect must be considered in the analysis of chloride penetration. In this study, an evaluation of correlation between accelerated diffusion coefficient, apparent diffusion coefficient, and compressive strength in high performance concrete with various mineral admixtures such as ground granulated blast furnace slag, fly ash, and silica fume was performed. For this work, thirty mix proportions were prepared. Accelerated diffusion coefficients at the age of 28, 91, 180, and 270 days were evaluated. For apparent diffusion coefficient, submerging test for 6 months was performed. For evaluation of compressive strength with ages, the compressive strength test was carried out at an age of 7, 28, 91, 180 days. The results of accelerated diffusion coefficient, apparent diffusion coefficient, and strength were compared, and the correlation was analyzed considering time dependency. From this study, linear relationship between accelerated diffusion and apparent diffusion coefficient were obtained regardless of concrete age. The linear relations were also observed in strength-accelerated diffusion coefficient and strength-apparent diffusion coefficient regardless of concrete age.

• Bulletin of the Korean Chemical Society
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• v.13 no.4
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• pp.398-404
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• 1992

We have investigated the kinetics of diffusion-influenced bimolecular reactions in which one reactant has an internal mode, called the gating mode, that activates or deactivates its reactivity intermittently. The rate law and an expression for the time-dependent rate coefficient have been obtained from the general formalism based on the hierarchy of kinetic equations involving reactant distribution functions. The analytic expression obtained for the steady-state reaction rate constant coincides with the one obtained by Szabo et al., who derived the expression by employing the conventional concentration-gradient approach. For the time-dependent reaction rate coefficient, we obtained for the first time an exact analytic expression in the Laplace domain which was then inverted numerically to give the time-domain results.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.145-153
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• 2013

Recently, accelerated chloride diffusion coefficients are used for an evaluation of chloride behavior. Similar as apparent diffusion coefficients, accelerated diffusion coefficients decrease with time. In this study, decrease in diffusion coefficient with time is simulated with porosity. Utilizing DUCOM-program, porosities from 15 mix proportions are obtained and diffusion coefficients are modelled with regression analysis of porosity for 270 days. Considering non-linear binding capacity which means the relation between free and bound chloride ion, chloride behavior in high performance concrete is evaluated. Through utilizing the previous test results for concrete under chlorides for 180 days, the applicability of the proposed technique is verified. The proposed technique is evaluated to reasonably predict the chloride behavior in concrete with various w/c (water to cement) ratios and mineral admixtures (GGBFS and FA). It is also shown that decrease in chloride diffusion should be considered for chloride prediction in concrete with mineral admixture since it has very clear decrease in diffusivity with time.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.4
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• pp.141-148
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• 2005

The nonlinear humidity distribution occurs due to the moisture diffusion when a concrete is exposed to an ambient air. This nonlinear humidity distribution induces shrinkage cracks on surfaces of the concrete. Because shrinkage cracks largely affect the durability and serviceability of concrete structures, the moisture diffusion in concrete must be investigated. The purpose of this paper is to propose a model of the moisture diffusion coefficient that governs moisture diffusion within concrete structures. To propose the model, numerical analysis was performed with several experiments. Because the moisture diffusion coefficient is changed with aging, especially at early ages, the proposed model includes aging effect by terms of the porosity as well as the humidity of concrete.