• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1140-1145
• /
• 2004

Laser-induced incandescence (LII) is introduced as a valuable tool for the characterization of nanoparticles in flame environments. This technique is based on the heating of the particles by a short laser pulse and the subsequent detection of the thermal radiation. It has been applied successfully for the investigation of soot in different fields of application. The evaluation of the temporal decay of the laser-induced incandescence (LII) signal from soot particles is introduced as a technique to obtain two-dimensional distributions of particle sizes and is applied to a laminar diffusion flame. This novel approach to soot sizing exhibits several theoretical and technical advantages compared with the established combination of elastic scattering and LII, especially as it yields absolute sizes of primary particles without requiring calibration. With this technique a spatially resolved 2-D measurement of soot primary particle sizes is feasible in a combination process form the ratio of emission signals obtained at two delay times after a laser pulse, as the cooling behavior is characteristic of particle size.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1152-1157
• /
• 2004

Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to see the effects of particle size, laser fluence on soot temperature characteristics and cooling behavior. Together with this, we focus on validating our simulation code by comparing with other previous results. Results of normalized LII signals obtained from various laser fluence conditions showed a good agreement with that of Dalzell and Sarofim's. It could be found that small particles cool faster at a constant laser fluence. And it also could be observed that vaporization is dominant process of heat loss during first 100ns after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.10 s.253
• /
• pp.973-981
• /
• 2006

Recently there is an increasing interest in particulate matter emission because of new emission regulations, health awareness and environmental problems. It requires to improve particulate measurement techniques as well as to reduce soot emissions from combustion systems. As mentioned above, it is demanded that reduction techniques together with measurement techniques of exhausted particulate matters in combustion systems such as vehicles. However, measurement techniques of particulate matters should be prior to reduction techniques of that because it is able to know an increase and a decrease of exhausted particulate matters when measured particulate matters. Therefore, in this study, we report the measurement of soot primary-particle size using time-resolved laser induced incandescence (TIRE-LII) technique in laminar ethylene diffusion flame. As an optical method, laser induced incandescence is one of well known methods to get information for spatial and temporal soot volume fraction and soot primary particle size. Furthermore, TIRE-LII is able to measure soot primary particle size that is decided to solve the decay ate of signal S $(t_1)$ and S $(t_2)$ at two detection time. In laminar ethylene diffusion flame, visual flame height is 40 mm from burner tip and measurement points are height of 15, 20, 27.5, 30 mm above burner tip along radial direction. As increasing the height of the flame from burne. tip, primary particle size was increased to HAB(Height Above Burner tip)=20mm, and then decreased from HAB=27.5 mm to 30 mm. This results show the growth and oxidation processes for soot particles formed by combustion.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.7 s.262
• /
• pp.596-603
• /
• 2007

As increasing interest for soot emission. etc in combustion systems, various studies are being carried out for the reduction and measurement techniques of soot. Especially, laser induced incandescence is the useful measurement technique which has distinguished spatial and temporal resolution for primary particle size, volume fraction and aggregated particle size etc. Time resolved laser induced incandescence is the technique for measuring primary particle size that is decided to solve the signal decay rate which is related to the cooling behavior of heated particle by pulsed laser. The cooling behavior of heated particle is able to represent the heat and mass transfer model which are involved constants of soot property for surround gas temperature on the our previous work. In this study, it is applied to the time-dependence thermodynamic properties for soot temperature instead of constants of soot property for surround gas temperature and compared two different model results.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.29 no.12 s.243
• /
• pp.1335-1343
• /
• 2005

The calibration technique of Time Resolved Laser Induced Incandescence was investigated both experimentally and numerically by using standard-sized carbon black particles for the instantaneous soot measurement at exhaust tail pipe in engine. The carbon black particles (19nm, 25nm, 45nm and 58nm) used in this study are similar, though not identical, to soot particle generated from flame not only in morphology but also in micro-structure. The amount of soot loading in flow was controled by a diluted gas (nitrogen) and was measured by the gravimetric method at exhaust pipe in calibrator. The successful calibrations of primary particle size and soot mass fraction were carried out at the range from 19nm to 58nm and from $0.25mg/m^3$ to $37mg/m^3$ respectively. And based on these results the numerical simulation of LII signal was tuned and the effect of an exhaust temperature variation on the decay rate of LII signal was corrected.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.29 no.9 s.240
• /
• pp.1022-1031
• /
• 2005

Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to obtain an appropriate calibration curve for determining primary particle size by comparing the gated signal ratio and double-exponential curve fitting methods. Not only the effects of laser fluence and gas temperature on the cooling behavior but also heat transfer mechanisms of heated soot particle have been investigated. The second-order exponential curve fitting showed better agreements with the LII signals than the gated signal ratio method which was based on the lust-order exponential curve fit. And the temporal decay rate of the LII signal and primary particle size showed nearly linear relationship, which was little dependent on the laser fluence. And it also could be reconfirmed that vaporization was dominant process of heat loss during first loons after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.5
• /
• pp.78-85
• /
• 2007

Recently, diesel vehicles have been increased and their emission standards have been getting strict. The emission of diesel vehicles contains numerous dangerous compounds, especially particulate matters cause a serious environmental pollutant and affect to human health seriously. Thousands of studies have already reported that particulate matters are associated with respiratory and cardiovascular diseases, and death. Due to these, it is necessary to measure the soot concentration and soot particle size in laboratory flames or practical engines to recognize the soot formation, and develop the control strategies for soot emission. In this study, the characteristics of exhausted soot particle size and volume fraction from 2.0L CRDI diesel engine have been investigated as varying engine speed and load. Laser induced incandescence has been used to measure soot concentration. Time-resolved laser induced incandescence has been used to determine soot particle size in the engine. The soot volume fraction is increased as increasing engine load but soot volume fraction is decreased as increasing engine speed. The primary particle size is distributed about $35nm{\sim}60nm$ at each experimental conditions.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.14 no.3
• /
• pp.95-102
• /
• 2006

Recently particulate matter(PM) emission regulations are becoming more strict for diesel engines. There is increasing interest for measuring not only concentration but also size of the particles. Laser-induced incandescence (LII) has emerged as a promising technique for measuring particle volume fraction and size. In this study, the Simple Time Resolved-LII method was applied to exhaust of Ethylene diffusion flame and diesel engine exhaust for measuring soot and PM size. The particle size data from LII technique were calibrated using Field Emission Scanning Electron Microscope(FE-SEM) and Transmission Electron Microscope(TEM) photographs. In diesel engine experiments for particle size measurement, results from LII measurement are in a good agreement with those from TEM photograph, and difference between two measurements was less than 16%.

• Journal of the Korean Society of Visualization
• /
• v.2 no.1
• /
• pp.12-17
• /
• 2004

The physical characteristics of soot near the soot inception point were investigated with various measurements. In-situ measurements of particle size and volume fraction were introduced based on time resolved laser-induced incandescence (TIRE-LII) and laser-induced ion mobility (LIIM). The one has more convenience and accuracy than conventional LII technique and the other works best for particle sizes of a few nanometers at high concentrations in a uniform concentration field. A complementary ex-situ measurement of particle size is nano differential mobility analyzer (Nano-DMA), which recently developed for measuring particle sizes between 2nm and 100nm and provides high-resolution size information for early soot. Particles will be also collected on transmission electron microscope (TEM) grids using rapid thermophoretic sampling and analyzed for morphology. These measurements will allow fresh and original insight into the characterizing soot inception process. The measured physical properties of incipient soot will clarify the controlling growth mechanism combined with chemical ones, and the dominant mechanism for soot modeling can be deduced from the information.

• Journal of Mechanical Science and Technology
• /
• v.19 no.11
• /
• pp.2068-2076
• /
• 2005

The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.