• Journal of Nuclear Fuel Cycle and Waste Technology
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• 제1권1호
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• pp.65-73
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• 2013

Temperature-dependent hydrolysis behaviors of aqueous U(VI) species were investigated with time-resolved laser fluorescence spectroscopy (TRLFS) in the temperature range from 15 to $75^{\circ}C$. The formation of four different U(VI) hydrolysis species was measured at pHs from 1 to 7. The predominant presence of $UO{_2}^{2+}$, $(UO_2)_2(OH){_2}^{2+}$, $(UO_2)_3(OH){_5}^+$, and $(UO_2)_3(OH){_7}^-$ species were identified based on the spectroscopic properties such as fluorescence wavelengths and fluorescence lifetimes. With an increasing temperature, a remarkable decrement in the fluorescence lifetime for all U(VI) hydrolysis species was observed, representing the dynamic quenching behavior. Furthermore, the increase in the fluorescence intensity of the further hydrolyzed U(VI) species was clearly observed at an elevated temperature, showing stronger hydrolysis reactions with increasing temperatures. The formation constants of the U(VI) hydrolysis species were calculated to be $log\;K{^0}_{2,2}=-4.0{\pm}0.6$ for $(UO_2)_2(OH){_2}^{2+}$, $log\;K{^0}_{3,5}=-15.0{\pm}0.3$ for $(UO_2)_3(OH){_5}^+$, and $log\;K{^0}_{3,7}=-27.7{\pm}0.7$ for $(UO_2)_3(OH){_7}^-$ at $25^{\circ}C$ and I = 0 M. The specific ion interaction theory (SIT) was applied for the extrapolation of the formation constants to infinitely diluted solution. The results of temperature-dependent hydrolysis behavior in terms of the U(VI) fluorescence were compared and validated with those obtained using computational methods (DQUANT and constant enthalpy equation). Both results matched well with each other. The reaction enthalpies and entropies that are vital for the computational methods were determined by a combination of the van't Hoff equation and the Gibbs free energy equation. The temperature-dependent hydrolysis reaction of the U(VI) species indicates the transition of a major U(VI) species by means of geothermal gradient and decay heat from the radioactive isotopes, representing the necessity of deeper consideration in the safety assessment of geologic repository.

• 폴리머
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• 제32권1호
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• pp.1-6
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• 2008

Acrylonitrile butadiene rubber(NBR)의 접착력 및 가공성을 향상시키기 위한 연구를 하였다. 최상의 조건을 선별하기 위해서 NBR의 acrylonitrile(ACN) 함량에 따른 접착물성 및 가공성을 관찰하였다. 무늬 점도, 충전제, 가소제 및 가교제가 접착력에 미치는 영향도 조사하였다. NBR의 ACN 함량은 NBR sealing에서 접착거동 및 가공성에 큰 영향을 미침을 알 수가 있었다. 최상의 혼합 조건을 알기 위해서 분산도를 조사하였다. 분산도는 혼합순서, 시간 및 온도 등의 많은 인자들에 의해 영향을 받는 것이 확인되었다. 가교시스템은 황 가교시스템, 과산화물 가교시스템, 가교밀도 및 구조 등의 관찰로 연구하였다. 접착제의 변화는 건조 상태와 hexamine 함량 등과 같은 것으로부터 NBR과 접착제 사이의 관계를 연구하였다. 이 결과 접착 물성과 가공성은 ACN 함량 및 가교시스템에 따라 차이를 보였다.

• 비교문화연구
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• 제27권
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• pp.471-496
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• 2012

Since Takeo Toi's discussion in The Anatomy of Dependence (1973), the concept of amae has generated considerable interest in the fields of psychology, anthropology, communication and other fields. However, there have been few agreements on the definition and functions of amae (Behrens, 2004). Furthermore, it has rarely drawn interest from linguists in general and has rarely been discussed in the context of social interaction. This study aims to examine the concept of amae in Japanese and the corresponding phenomena in Korean, and attempts to explore the similarities and differences between them. The prototype of the amae relationship is the mother-infant relationship (Doi,1973). Even an adult can assume the role of a baby, showing his or her need for dependence on others and expecting to be accepted. It turns out that amae-like phenomena frequently occur in everyday life in Korea as well (Lee, 1982). There is no single term for the concept, but it can be translated in many different ways in Korean, for example, aykyo, ayang, ungsek, erikwang, etc. It can have either positive or negative connotations depending on the situation. It seems that the psychological system that causes dependent behaviors such as ungsek in Korea is cheong, one of the key terms characterizing the Korean culture. Cheong, like amae, starts in the mother-infant relationship extending to familial and to other relationships. A corpus-based analysis shows that cheong is conceptualized as gluing people together, growing over time, and also potentially fatal because it assumes illogical, uncalculated, and personal relationships. In conclusion, unlike some Japanese scholars' claim that amae is the Japanese concept that exists only in Japan, it seems that similar phenomena do exist in Korea as well, but that Korean has no single term corresponding to amae in Japanese. It seems that cheong can be posited in Korean as the inner emotional system that makes amae-like behaviors possible, and that there is not single term, but many, designating the behaviors, possibly because the behaviors have a negative connotation and are not encouraged in Korean society.

• Biomolecules & Therapeutics
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• 제16권4호
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• pp.328-335
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• 2008

This study was undertaken to investigate whether honokiol could enhance the pentobarbitalinduced sleeping behaviors through $\gamma$-aminobutyric acid (GABA) receptor $Cl^-$ channel activation. Thirty minutes after the oral administration of honokiol, mice were received sodium pentobarbital (42 mg/kg, i.p.). The time elapsed from pentobarbital injection to the loss of the righting reflex was taken as sleeping latency. The time elapsed between the loss and voluntary recovery of the righting reflex was considered as the total sleeping time. Western blot technique and $Cl^-$ sensitive fluorescence probe were used to detect the expression of $GABA_A$ receptor subunits and $Cl^-$ influx in the primary cultured cerebellar granule cells. Honokiol (0.1 and 0.2 mg/kg) prolonged the sleeping time induced by pentobarbital (42 mg/kg) in a dosage-dependent manner. Honokiol (20 and 50 ${\mu}M$) increased $Cl^-$ influx in primary cultured cerebellar granule cells, and selectively increased the $GABA_A$ receptor $\alpha$-subunit expression, but had no effect on the abundance of $\beta$ or $\gamma$-subunits. Chronic treatment with 20 ${\mu}M$ honokiol in primary cultured cerebellar neurons did not affect the abundance of GAD65/67. The results suggested that honokiol could potentiate pentobarbital-induced sleeping through $GABA_A$ receptor $Cl^-$ channel activation.

• Corrosion Science and Technology
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• 제4권4호
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• pp.147-154
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• 2005

The creep resistance of geogrids is one of the most significant long-term safety characteristics used as the reinforcement in slopes and embankments. The failure of geogrids is defined as creep strain greater than 10%. In this study, the accelerated creep tests were applied to polyester geogrids at various loading levels of 30, 50% of the yield strengths and temperatures using newly designed test equipment. Also, the new test equipment permitted the creep testing at or above glass transition temperature($T_g$) of 75, 80, $85^{\circ}C$. The time-dependent creep behaviors were observed at various temperatures and loading levels. And then the creep curves were shifted and superposed in the time axis by applying time-temperature supposition principles. The shifting factors(AFs) were obtained using WLF equation. In predicting the lifetimes of geogrids, the underlying distribution for failure times were determined based on identification of the failure mechanism. The results confirmed that the failure distribution of geogrids followed Weibull distribution with increasing failure rate and the lifetimes of geogrids were close to 100 years which was required service life in the field with 1.75 of reduction factor of safety. Using the newly designed equipment, the creep test of geogrids was found to be highly accelerated. Furthermore, the time-temperature superposition with the newly designed test equipment was shown to be effective in predicting the lifetimes of geogrids with shorter test times and can be applied to the other geosynthetics.

• 콘크리트학회논문집
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• 제28권2호
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• pp.149-156
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• 2016

염해에 노출된 콘크리트의 내구수명은 매우 중요한데, 주로 Fick's 2법칙에 근거한 결정론적인 방법과 확률론에 근거한 방법이 사용되고 있다. 본 연구에서는 시간의존적 확산계수와 표면염화물량을 고려하여 내구적 파괴확률과 이에 따른 내구수명의 변화를 평가하였다. 이를 위해 3.5~4.5년, 비교적 짧은 기간 염해에 노출된 RC 교각에 대하여 해상부(9.0 m)와 간만대(6.0 m) 구분하여 실태조사를 수행하였다. 피복두께, 표명염화물량, 염화물 확산계수에 대한 확률변수를 도출하였으며, MCS을 이용하여 내구적 파괴확률과 내구수명을 평가하였다. Life365를 이용한 결정론적 방법과 다르게, 시간의존성을 고려한 확률해석에서는 내구수명의 변동이 크게 발생하였으며, 표면염화물량이 낮은 조건에서는 초기에 빠른 내구수명의 감소가 평가되었다. 실태조사 결과를 이용하여 확률론적인 내구성 평가를 할 경우, 장기간 염해에 노출되어 $10.0kg/m^3$ 이상의 높은 표면염화물량이 필요함을 알 수 있으며, 확산계수의 시간의존성에 따른 감소를 고려하면 합리적인 내구수명을 평가할 수 있다.

• Smart Structures and Systems
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• 제15권2호
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• pp.469-488
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• 2015

Thermal loads, especially thermal gradients, have a considerable effect on the behaviors of large-scale bridges throughout their lifecycles. Bridge design specifications provide minimal guidance regarding thermal gradients for simple bridge girders and do not consider transversal thermal gradients in wide girder cross-sections. This paper investigates the three-dimensional thermal gradients of arch bridge girders by integrating long-term field monitoring data recorded by a structural health monitoring system, with emphasis on the vertical and transversal thermal gradients of wide concrete-steel composite girders. Based on field monitoring data for one year, the time-dependent characteristics of temperature and three-dimensional thermal gradients in girder cross-sections are explored. A statistical analysis of thermal gradients is conducted, and the probability density functions of transversal and vertical thermal gradients are estimated. The extreme thermal gradients are predicted with a specific return period by employing an extreme value analysis, and the profiles of the vertical thermal gradient are established for bridge design. The transversal and vertical thermal gradients are developed to help engineers understand the thermal behaviors of concrete-steel composite girders during their service periods.

• Tribology and Lubricants
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• 제27권2호
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• pp.101-108
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• 2011

In this paper, a study on the frictional losses and dynamic behaviors of a reciprocating compression mechanism used in small refrigeration compressor is performed. In the problem formulation of the compressor dynamics, the viscous frictional force between piston and cylinder wall is considered in order to determine the coupled dynamic behaviors of piston and crankshaft supported on a thrust ball bearing. The solutions of the equations of motion of the reciprocating mechanism along with the time dependent Reynolds equations for the lubricating film between piston and cylinder wall and lubricant films of the journal bearings are obtained simultaneously. The hydrodynamic forces of journal bearings are calculated using finite bearing model and G$\hat{u}$m-bel boundary condition. And, a Newton-Raphson procedure was employed in solving the nonlinear equations of piston and crankshaft with a thrust ball bearing. The results explored the effects of design parameters on the frictional losses and dynamic stability of the compression mechanism.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.1341-1344
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• 2003

Studies on impact damage of composite laminate shells were fewer compared with those on impact behaviors to analyze time-load, displacement-load and impact energy - energy absorption. Up to date the studies were not enough to demonstrate suitability of their results because they were dependent on theories and numerical analyses. In particular, it is a well-known fact that there was a correlation between initial peak load and damage resistance of composite material flat plates imposed with low-speed impact, but studies on composite material shells with curvature were also very few. Actually structures such as wings or moving bodies of airplanes, motor cases and pressure containers of rockets are circular. And as low-speed impact load is imposed for optimal design of take-off and landing, and containers of airplanes, it is very important to analyze evaluation of behaviors and damaged areas. Therefore, in this paper to evaluate the impact characteristics of the CFRP laminate shell according to size of curvature quantitatively, it was to identify energy absorption and impact damage instruments according to change of impact speed.

• 한국태양에너지학회 논문집
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• 제34권1호
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• pp.48-57
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• 2014

The transient and synchronization behaviors of a TA (thermo acoustic) laser pair were investigated experimentally for various crossing angles and different separation distances between the laser openings. Sound waves generated by the lasers were measured and analyzed at or near the focusing point by means of microphones, SPL meters, and a commercial software called Signal-Express. The two TA lasers were acoustically coupled through the air mass between their openings, and the only mode-locking operation that could be achieved was the one that was nearly $180^{\circ}C$ out of phase. The time to achieve synchronization was found to be dependent upon the initial mistuning of the frequencies and the crossing angle between the laser axes. The synchronization process could also be accelerated by turning on the laser with the lower power input first.