• 제목/요약/키워드: TiC content

검색결과 453건 처리시간 0.036초

V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) 금속수소화물전극에 관한 연구 (A Study on the V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) Metal Hydride Electrodes)

  • 김정선;조원일;조병원;윤경석;김상주
    • 한국수소및신에너지학회논문집
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    • 제5권1호
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    • pp.1-8
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    • 1994
  • Lattice structure, hydrogen absorption characteristics, discharge capacity and cycle life of $V_{22}Ti_{16}Zr_{16}Ni_{39}X_7$(X= Cr, Co, Fe, Mn, Al) alloys were investigated. The matrix phases of these alloys were the C14 Laves phase. Chromium-containing alloy had a vanadium-rich phase in addition to the Laves phase. The chromium, maganese, or aluminum-containing alloys had lower hydrogen equilibrium pressure and larger hydrogen absorption content than the cobalt or iron-containing alloys. The discharge capacities of these alloys were 270~330mAh/g. The discharge capacity according to the alloying element X decreased in the order of Mn>Cr>Co, Al)Fe. The charge/discharge cycle lives of the chromium, cobalt or iron-containing alloys were longer than those of maganese or aluminum-containing alloys due to the lower vanadium dissolution rate.

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Dielectric Properties of Zr-doped (Ba,Sr,Ca)TiO3 Thick Films for Microwave Phase Shifters

  • Lee, Sung-Gap;Lee, Sang-Heon
    • Transactions on Electrical and Electronic Materials
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    • 제4권2호
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    • pp.24-28
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    • 2003
  • (Ba,Sr,Ca)TiO$_3$ powders, prepared by the sol-gel method, were mixed with organic binder and the BSCT thick films were fabricated by the screen printing techniques on alumina substrates. All the BSCT thick films, sintered at 1420$^{\circ}C$, showed the typical XRD patterns of a perovskite polycrystalline structure. The average grain sizes decreased with increasing amounts of ZrO$_2$, and the BSCT(40/40/20) thick films doped with 2wt% MnO$_2$ showed a value of 8$\mu\textrm{m}$. The thickness of thick films by four-cycle on printing/drying was approximately 951$\mu\textrm{m}$. The relative dielectric constant decreased with increasing Ca content and MnO$_2$ doping amount. The relative dielectric constant, dielectric loss and tunability of the BSCT(50/40/10) thick films doped with 2.0wt% ZrO$_2$ were 772, 0.184% and 15.62%, respectively.

비휘발성 메모리 소자응용을 위한 Eu 첨가량에 따른 BET 박막의 강유전 특성 (Ferroelectric Properties of Bi3.25La0.75Ti3O12 Thin Films with Eu Contents for Non-volatile Memory Device Application)

  • 김경태;김종규;우종창;김관하;김창일
    • 한국전기전자재료학회논문지
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    • 제20권3호
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    • pp.223-227
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    • 2007
  • The effect of Eu contents on the ferroelectric properties of $Bi_{4-x}Eu_xTi_3 O_{12}$ (BET) thin films has been investigated. Bismuth Europium titanate thin films with a Eu contents were prepared on the $Pt/Ti/SiO_2/Si$ substrate by metal-organic decomposition technique. The structure and the morphology of the films were analyzed using X-ray diffraction (XRD) and field emission scanning microscopy (FE-SEM), respectively. From the XRD analysis, it was found that BET thin films have polycrystalline structure, and the layered-perovskite phase is obtained when the Eu contents exceeds 0.2 (x > 0.2). Also, the ferroelectric characteristics of the BET thin films were found to be dependent on the Eu content. Particularly, the BET films doped with x = 0.75 show better ferroelectric properties (remanent polarization 2Pr = 60.99 C/$cm^2$ and only a little polarization fatigue up to $3.5{\times}10^9$ bipolar switching cycling) than those doped with other Eu contents.

자동차 배기계 플랜지용 16~19 wt.% 페라이트 주조용 스테인리스강 개발 (Development of a (16~19)Cr Ferritic Cast Stainless Steel for a Flange Material of Automotive Exhaust Parts)

  • 장희진;범원진;박찬진
    • 한국표면공학회지
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    • 제42권2호
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    • pp.79-85
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    • 2009
  • We aimed to develop a Fe-($16{\sim}19$)Cr-($0.1{\sim}0.6$)Ti-($0.1{\sim}0.6$)Nb stainless steel for automotive exhaust parts with high corrosion resistance. The alloys with high Cr content showed high resistance to general corrosion and also localized corrosion. The increase of Ti and Nb contents resulted in a linear increase in the general corrosion resistance, while the pitting potential was improved by addition of these elements up to about 0.4 wt.%. The low-carbon Fe-17Cr-0.4Ti-0.4Nb alloy annealed at $850^{\circ}C$ and air-cooled was considered to be the optimum alloy for our purpose with the critical anodic current density of $247{\mu}A/cm^2$ in 0.05 M $H_2SO_4$ solution and the pitting potential of 310 mVSCE in 0.2 M NaCl solution.

$Pb(Mg_{1/2}W_{1/2})O_3-Pb(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3$계 세라믹스의 유전 및 압전 특성 (Dielectric and Piezoelectric Characteristics of Ceramics in the $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3$ system)

  • 김우현;윤광희;윤현상;박용욱;박창엽
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 추계학술대회 논문집 학회본부
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    • pp.193-195
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    • 1994
  • In this study, the structural, dielectric and piezoelectrical properties of $xPb(Mg_{1/2}W_{1/2})O_3-(1-x)[0.41Pb(Ni_{1/3}Nb_{2/3})O_3-0.36PbTiO_3-0.23P Zr)_3]$ (x=0, 0.01, 0.02, 0.03, 0.04, 0.05) system ceramics were investigated. The dielectric constant ${\varepsilon_{33}}^{\tau}$ at loon temperature increased up to 3mol% PMW and decreased with further PMW content. The specimen with 1mol% $Pb(Mg_{1/2}W_{1/2})O_3$, which has the ${\varepsilon_{33}}^{\tau}=5509$, kp=59[%] and $d_{33}=758{\times}10^{-12}[C/N]$, exhibits good characteristics.

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Sol-gel법으로 제조된 Tb-doped PZT(60/40) 박막의 강유전 특성 (Ferroelectric properties of sol-gel derived Tb-doped PZT thin films)

  • 손영훈;김경태;김창일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.51-54
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    • 2003
  • Tb-doped lead zirconate titanate($Pb_{1.1}(Zr_{0.6}Ti_{0.4})O_3$; PZT) thin films on $Pt(111)/Ti/SiO_2/Si(100)$ substrates prepared by a sol-gel method. Films have a Zr/Ti ratio of 60:40 and perovskite phase structure. The effect on the structural and electrical properties of films measured according to Tb content. Dielectric and ferroelectric properties of PZT thin films were altered significantly by Tb-doping. The PZT thin film with higher dielectric constant and improved leakage current characteristic was obtained by adding 0.3 mol% Tb. At 100 kHz, the dielectric constant and the dielectric loss of the 0.3 mol% Tb-doped PZT thin film were 1611 and 0.24, respectively The remanent polarization(2Pr) of the 0.3 mol% Tb-doped PZT thin film was $61.4\;{\mu}C/cm^2$ and the coercive field was 61.9 kV/cm. Tb-doped PZT thin films showed improved fatigue characteristics comparing to the undoped PZT thin film.

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구리를 포함하는 ${\gamma}$-$Al_2O_3$$TiO_2$에서의 금속-담체 상호작용 (Metal-Support Interaction in Cu /${\gamma}$-$Al_2O_3 and Cu / TiO_2$ Systems)

  • 주미경;한종수;조민수;이계수
    • 대한화학회지
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    • 제32권6호
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    • pp.543-548
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    • 1988
  • 1∼5wt%의 구리가 얹혀진 ${\gamma}$-알루미나 또는 티타니아에서 금속-지지체 상호작용을 승온환원과 상자성 공명으로 연구하였다. $500^{\circ}C에서 시료를 산소로 처리했을 때 티타니아계에서는 구리 함량이 증가함에 따라 고온쪽으로 승온환원 피이크가 증가했으나 알루미나 계에서는 저온쪽의 승온 환원 피이크가 커졌다. $300^{\circ}C 처리 경우에는 알루미나계에서는 $300^{\circ}C에서 티타니아계는 120 과 $300^{\circ}C에서 각각 환원피이크를 보여주었다. ${\gamma}$-알루미나에서는 $Cu^{2+}$의 전형적인 상자성 신호가 나타났으나 티타니아에서는 넓고 작은 신호만 관찰되었다. 이들 결과들로부터 금속-지지체 상호작용은 실리카 < 티타니아 < ${\gamma}$-알루미나의 순으로 커지며 산화구리는 지지체에 따라 서로 다른 담지특성을 가짐을 알 수 있었다.

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조미훈연 오징어의 가공중 품질변화 (Changes in Quality of Seasoned and Smoked Squid During Processing)

  • 류흥수;문숙임;이강호
    • 한국수산과학회지
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    • 제25권5호
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    • pp.406-412
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    • 1992
  • 조미훈연 오징어(Neon flying squid, Qmmastrephes bartrannii)의 적절한 가공조건을 찾기 위하여 일반성분변화 및 단백질 품질변화를 측정하였다. 수분, 조단백질함량은 매우 감소하였으나(p<0.05) 지방, 회분함량은 그다지 증가하지 않았다. 조미, 훈연은 TBA가의 증가를 초래하였다. 여러 가지 가공단계들은 TI함량을 크게 증가시키지는 않았다. 오징어 가공전단계를 통해 측정된 TI함량은 같은 가공단계에서의 TBA가와 서로 관련이 없었다. Steak용으로 가공한 것을 제외한 모든 가공품들의 경우, 소화율과 C-PER, DC-PER이 증가하였다. 생시료의 경우, 북태평양산 빨강오징어(몸통, 다리 양쪽 모두)의 효소 소화율은 다른 오징어종에 비해 상당히 낮았다.

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저온 소결 유전체에 관한 연구 (A Study on the Low-Firing Dielectric Material)

  • 이종규;김왕섭;김경용
    • 한국재료학회지
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    • 제2권4호
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    • pp.263-269
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    • 1992
  • 본 실험에서는 낮은 음의 온도계수를 갖는 저온 소결 유전체에 대해 연구하였다. 새로 개발된 재료의 조성은 Ti$O_2$(100-X) CuOx(X=1~5wt%)에 미량의 Mn$O_2$를 첨가 하였다. CuO를 첨가하지 않은 경우에는 저온 (90$0^{\circ}C$) 에서 소결이 진행되지 않았다. CuO 함량이 증가할수록 저온에서 소결이 가능하였으나, 유전율이 낮아지고 유전손실은 증가 하였다. Mn$O_2$를 0.6wt% 첨가한 경우 유전율과 Q값이 가장 높게 나타났다.

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투광성 전기 광학용 소자의 제조에 관한 연구 (Studies on Fabrication of Translucent Eletrooptic Ceramics)

  • 김재육;이태근;임응극
    • 한국세라믹학회지
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    • 제22권6호
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    • pp.71-79
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    • 1985
  • In order to fabricate the translucent electrooptic ceramics which are comparable to PLZT, $PNZT^*$ has been prepared from aqueous solutions of their itrate and chlorides. In the quarternary $Pb^{1-x} Nd_x(Zr_{0.63} Ti_{0.37})^{1-\frac{x}{4}O_3$, (PNZT) $(0.02\le x\ge 0.12)$ system cold-pressed PNZT slugs were sintered in $O_2$ in pt-crucible for 45 min. at 118$0^{\circ}C$ and were then heat-treated in air for 60 hrs. at 120$0^{\circ}C$ in Al2O3 crucibles containing $PbZrO_3$ powder to control the atmosphere. Mean particle size of calcined PNZT powders was 0.1~0.15${\mu}{\textrm}{m}$. It was found that the maximum value of optical transmission has been revealed at 6~8 at. % $Nd_2O_3$ added body and that their dielectric constant has been decreased as the frequency increased. Curic temperature has been varied inversely with $Nd^{3+}$ ion content up to 8 at. % and become constant above this value. $^*Pb_{1-x}Nd_x(Zr_{0.63} Ti_{0.37})_{1-2/4}O_3$

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