• Title/Summary/Keyword: Ti 확산

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Microstructures and Electrical properties of Multilayer PTCR ceramics as a function of Sintering Additives (소결첨가제에 따른 적층 PTCR 세라믹스의 미세구조와 전기적 특성)

  • Myoung, Seong-Jae;Park, Myoung-Sung;Chun, Myoung-Pyo;Cho, Jeong-Ho;Nam, Chung-Hee;Kim, Byung-Ik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.180-181
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    • 2008
  • 화학양론적 $BaTiO_3$의 소결은 고온의 에너지를 필요로 하며, 내부전극과 세라믹충의 동시소성과정에서 Ni이 세라믹층으로의 확산이 발생되어 PTC의 물성저하를 초래한다. 본 연구에서는 저온에서 액상을 형성하여 소결온도를 낮추는 것으로 알려진 산화물 및 비산화물계 소결첨가제가 적층 PTC 세라믹스의 미세구조 및 전기적 특성에 미치는 영향에 대하여 고찰하였다. 소결과정에서 분해되어 기체를 형성하는 BN, $Li_2CO_3$, LiF의 경우 기공율을 증가시켜 산소의 이동경로를 형성하였으며, 이는 입계의 재산화를 용이하게 하여 PTC 효과를 보였다.

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A Study on Development of Insert Metal for Liquid Phase Diffusion Bonding of Fe Base Heat Resistance Alloy (Fe 기내열합금의 액상확상접합용 삽입금속의 개발에 관한 연구)

  • 강정윤;김인배;이상래
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.147-156
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    • 1995
  • The change of microstructure in the bonded interlayer and tensile properties of joints were studied for liquid phase diffusion bonding using STS-310 and Incoloy-825 as base metal and base metal+B alloy as insert inetal. Main experimental results obtained in this study are as follows. 1) The optimum amount of B addition into the insert metal was found to be about 4mass%. 2) When isothermal solidification was completed, the microstructure in the bonded interlayer was the same with that of the base metal because of the grain boundary migration in the bonded interlayer. 3) All of the tensile specimen fractured at base metal and joints bonded at optimum condition exhibited tensile properties in excess of base metal requirements. 4) It was determined that fine car-borides and bordes such as M$_{23}$(C,B)$_{6}$, Cr$_{2}$B, and CrB in STS-310S and TiB in Incoloy-825 exist at the grain boundary around bonded interlayer. These precipitates almost disappeared after homogenizing treatment at 1373K for 86.4ks.s.

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Mixing Effect by Tone-Excitation In Round Jet Diffusion Flame (원형분류확산화염에서의 음파가진에 의한 혼합효과)

  • Kim, Tae Kwon;Park, Jeong;Shin, Hyun Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.795-801
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    • 1999
  • An experimental investigation has been conducted with the objective of studying the mixing mechanism near the nozzle exit in a tone-excited jet diffusion flame. The fuel jet was pulsed by means of a loudspeaker-driven cavity. The excitation frequencies were chosen for the two cases of the non-resonant and resonant frequency identified as a fuel tube resonance due to acoustic excitation. The effect of tone-excitations on mixing pattern near the nozzle exit and flame was visualized using various techniques, including schlieren photograph and laser light scattering photograph from $TiO_2$ seed particles. In order to clarify the details of the flame feature observed by visualization methods, hotwire measurements have been made. Excitation at the resonant frequency makes strong mixing near the nozzle. In this case, the fuel jet flow in the vicinity of nozzle exit breaks up into disturbed fuel parcels. This phenomena affects greatly the combustion characteristics of the tone excited jet and presumably occurs by flow separation from the wall inside the fuel nozzle. As a result, in the resonant frequency the flame length reduces greatly.

Wireless Sensor Network System Power Supply Test-bed Implementation using Wireless Power Transmission for Self-sustainability Support (자기유지지원을 위한 무선에너지전송기반 무선센서네트워크 전원공급 테스트베드 구현)

  • Lee, Sang-Shin;Song, Min-Hwan;Ryu, Min-Woo;Won, Kwang-Ho;Kim, Joong-Hwan
    • Proceedings of the KAIS Fall Conference
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    • 2011.05a
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    • pp.416-420
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    • 2011
  • 무선센서네트워크 시스템의 확산에 가장 큰 장애물인 한정된 전원으로 동작하는 특성에 따라 주기적인 배터리 교체에 소요되는 비용이다. 이러한 문제를 해결하기 위하여 원격지에서 에너지를 무선으로 공급하는 자기유지 지원 기술이 연구되고 있다. 본 논문에서는 무선에너지전송을 통해 무선센서네트워크 노드에 에너지를 전송하는 환경을 구축하고 환경에 따라 에너지 수신의 결과를 측정하는 테스트베드를 구축하였다. 구축된 테스트베드는 Powercast사의 915MHz 대역에서 3W EIRP (Equivalent Isotropic Radiated Power) 에너지 송신장치, RF (Radio Frequency) 에너지 획득 모듈 그리고 TI사의 CC2530기반의 무선센서네트워크 노드로 구성되어있다. 또한 수신된 에너지의 양을 측정하고 기록하는 LabView기반의 모니터링 시스템이 구현되었다. 구현된 테스트베드는 다양한 환경에서 RF를 기반의 무선에너지전송을 통한 자기유지(Self-sustainable) 시스템의 전원공급 상태를 모니터링에 활용될 수 있다.

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Synthesis Long Multi-Walled Carbon Nanotubes by Water-Assisted Thermal-CVD (물 첨가 열화학기상증착을 이용하여 긴 다중벽 탄소나노튜브의 합성)

  • Jeon, Hong-Jun;Kim, Young-Rae;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.220-220
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    • 2008
  • 물 첨가 열화학기상증착을 이용하여 750도에서 길고 수직 성장한 다중벽 탄소나노튜브를 합성하였다. 사용된 기판으로는 우선 실리콘 웨이퍼에 열 증착기로 확산 방지층으로 Ti 50 nm를 입히고 그 위에 Al 15 nm를 입히고 난 후 촉매 층으로 Invar 36 (63 wt% Fe, 37 wt% Ni)을 1 nm 얇게 증착하였다. 탄소나노튜브의 성장에 사용된 가스는 Ar, $C_2H_2$ 이다. Ar은 분위기 가스로 사용되었고, $C_2H_2$는 탄소나노튜브의 성장에 관여하는 가스이다. 또한, 합성중에 약간의 물을 첨가함으로 기존의 탄소나노튜브 성장 길이보다 10배 가량 더 성장 하였다. 이것은 합성 중의 물 첨가로 인해 촉매 입자들의 활동성이 기존에 비해 더 증가했다는 것을 보여준다. 합성된 탄소나노튜브의 길이와 정렬도를 보기 위해 주사전자현미경 (scanning electron microscopy, SEM)을 이용하였고, 탄소나노튜브의 지름과 벽의 개수를 파악하기 위해 투과전자현미경 (transmission electron microscopy)을 이용하였다.

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Application of Environmental Management System Model for the Local Food Industry and the Analysis (로컬푸드산업의 환경경영시스템 모델 적용 분석)

  • Cho, Chang-Duk;Park, Dea-Woo
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.11 no.2
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    • pp.233-247
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    • 2016
  • Local food industry has been spreading all over the world. Korea is also actively applying and developing local food industry. However, relatively high distribution cost in Korean agricultural market is hindering its further growth. Distribution cost has close relation with shipping distance. Raised distribution cost brings major impacts not only on quality and price of products but also on greenhouse gas(carbon dioxide) emissions. Therefore, it is necessary to find a solution for inefficient distribution system of the local food industry to reduce overall cost and greenhouse gas. In this study, we present a location selection model for local food regional center using Analytic Hierarchy Process. The location of local food regional hub center is decided based on expert opinions on five factors: accessibility, quality, population, size of area, and shipping distance. The relative importance of the five factors has been concluded as follows: quality (0.430) ${\gg}$ population (0.262) ${\gg}$ travel distance (0.201) ${\gg}$ accessibility (0.075) ${\gg}$ and area (0.033). We apply and analyze the environmental management system model for Local food industry to develop the regional hub center site selection criteria and to analyze the effects of greenhouse gas emissions in the local food industry. This study, by applying and analyzing the environmental management system of the local food industry, is believed to be a valuable asset for managing greenhouse gas emission in the local food industry. Also, the data will be used for the autonomous local food industry's direct sales stall management. Eventually, this study will contribute so greatly to the local food industry's competitiveness that even large distribution companies will give way for the local food industry.

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High Efficiency Solar Cell(I)-Fabrication and Characteristics of $N^+PP^+$ Cells (고효율 태양전지(I)-$N^+PP^+$ 전지의 제조 및 특성)

  • 강진영;안병태
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.3
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    • pp.42-51
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    • 1981
  • Boron was predeposited into p (100) Si wafer at 94$0^{\circ}C$ for 60minutes to make the back surface field. High tempreature diffusion process at 1145$^{\circ}C$ for 3 hours was immediately followed without removing boron glass to obtain high surface concentration Back boron was annealed at 110$0^{\circ}C$ for 40minutes after boron glass was removed. N+ layer was formed by predepositing with POCI3 source at 90$0^{\circ}C$ for 7~15 minutes and annealed at 80$0^{\circ}C$ for 60min1es under dry Of ambient. The triple metal layers were made by evaporating Ti, Pd, Ag in that order onto front and back of diffused wafer to form the front grid and back electrode respectively. Silver was electroplated on front and back to increase the metal thickness form 1~2$\mu$m to 3~4$\mu$m and the metal electrodes are alloyed in N2 /H2 ambient at 55$0^{\circ}C$ and followed by silicon nitride antireflection film deposition process. Under artificial illumination of 100mW/$\textrm{cm}^2$ fabricated N+PP+ cells showed typically the open circuit voltage of 0.59V and short circuit current of 103 mA with fill factor of 0.80 from the whole cell area of 3.36$\textrm{cm}^2$. These numbers can be used to get the actual total area(active area) conversion efficiency of 14.4%(16.2%) which has been improved from the provious N+P cell with 11% total area efficiency by adding P+ back.

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A Suitability Study on the Indicator Isotopes for Graphite Isotope Ratio Method (GIRM) (흑연 동위원소 비율법의 지표 동위 원소 적합성 연구)

  • Han, Jinseok;Jang, Junkyung;Lee, Hyun Chul
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.1
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    • pp.83-90
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    • 2020
  • The Graphite Isotope Ratio Method (GIRM) can verify non-proliferation of nuclear weapon by estimating the total plutonium production in a graphite-moderated reactor. Using the reactor, plutonium is generated and accumulated through the 238U neutron capture reaction, and impurities in the graphite are converted to nuclides due to the nuclear reaction. Therefore, the amount of plutonium production and concentration of the impurities are correlated. However, the plutonium production cannot be predicted using only the absolute concentration of the impurities. It can only be predicted when the initial concentration of the impurities is obtained because the concentration, at a certain time, depends on it. Nevertheless, the ratios of the isotopes in an element are known regardless of the impurity of an element in the graphite moderator. Thus, the correlation between the isotope ratio and amount of plutonium produced helps predict plutonium production in a graphite-moderated reactor. Boron, Lithium, Chlorine, Titanium, and Uranium are known as indicator elements in the GIRM. To assess whether the correlation between the indicator isotope and amount of plutonium produced is independent of the initial concentration of the impurities, four different impurity compositions of graphite were used. 10B/11B, 36Cl/35Cl, 48Ti/49Ti, and 235U/238U had a consistent correlation with the cumulative plutonium production, regardless of the initial impurity concentration of the graphite, because these isotopes were not generated through the nuclear reaction of other elements. On the other hand, the correlation between 6Li/7Li and plutonium production depended on the initial concentration of the impurities in graphite. Although 7Li can be produced through the neutron capture reaction of 6Li, the (n, α) reaction of 10B was the major source of 7Li. Therefore, the initial concentration of 10B affected the production of 7Li, making Li unsuitable as an indicator element for the GIRM.

Reversely Zoned Compositional Variations and their Origins of the Andong Pluton, Andong Batholith, Korea (안동심성암체의 역누대 초성변화와 그 성인)

  • 황상구;이보현
    • Economic and Environmental Geology
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    • v.35 no.1
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    • pp.75-95
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    • 2002
  • The Andong pluton in the Andong Batholith is composed of comagmatic plutonic rocks, in which the lithofacies comprise hornblende biotite tonalite in the central paft biotite granodiorite in the marginal paft and porphyritic biotite granite at the topside (noJthea~tern paft) of the pluton. The pluton is petrographically and petrochemically zoned, having more mafic center than margin and topside. Distribution pallern of the lithofacies represents a reverse zoning in the pluton. Modal and chemical data in the pluton show progressive and gradual compositional variations from the centrer via the margin to the topside. Quartz and K-teldspar increase toward the topside of the pluton, whereas hornblende, biotite and color index increase toward the center. The bulk composition in the pluton is also reversely zoned, with high $Si0_2$ and $K_{2}O$ in the topside facies, and high MnO, CaO, $Ti0_2$, $Fe_{2}O_{3}$t, MgO and $P_{2}O_{5}$ in the central facies. The reverse zoning is also evident in higher Cr. V, Ni, Sc and Sr of the more mafic tonalite in the interior. The reversely zoned pluton results from remobilization (resurgence) of the lower more mafic compositional zone into the upper more felsic zones of the pluton modified by thennogravitational diffusion and fractional crystallization. In the initial stages of evolution, the pluton was a petrochemical system that fonned chemical compositional zonation with mafic tonalitic magma in the lower. granodioritic one in the middle and granitic one in the upper paft of the magma chamber. Periodic influxes of more mafic magma from the ba~e resulted in mingling of liquids and redistribution of minerals, and may have triggered the remobilil.ation of the lower compositional zone into the upper more felsic zones.

Selective Catalytic Reduction (SCR) of NOx with NH3 on Sb-promoted VWTi Catalysts (Sb 첨가에 따른 VWTi 촉매의 암모니아 선택적 촉매 환원(SCR)을 통한 질소산화물 저감)

  • Kim, Su Bin;Choi, Gyeong Ryun;Shin, Jung Hun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.35-41
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    • 2021
  • VWTi, which is used as a commercial catalyst in NH3-SCR, exhibits excellent denitrification performance at 300 to 400 ℃, but there is a problem that efficiency decreases at low temperatures below 300 ℃. Research on catalysts containing promoter to increase low-temperature denitrification efficiency is steadily progressing. However, research on the cause of the improvement in low-temperature denitrification efficiency of the catalyst and the catalyst properties is insufficient. In this study, it was confirmed that by adding Sb to VWTi, denitrification performance was improved by more than 10% in NH3-SCR reaction below 300 ℃. At this time, the space velocity and the size of the catalyst particles were controlled to exclude the influence of external/internal diffusion. In addition, the catalytic properties according to the presence or absence of Sb were investigated by performing BET, TEM/EDS, O2-TPD, H2-TPR and DRIFTs analysis. It was judged that the addition of Sb increased the adsorbed oxygen species on the surface of the catalyst, thereby enhancing the redox properties of the catalyst at low temperature and exhibiting excellent denitrification performance.