• Title/Summary/Keyword: Three-way Catalyst

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An Estimation of Thermal fatigue in Three-way catalyst (삼원촉매장치의 열 피로 평가)

  • Cho, Seok-Swoo;Lee, Hyun-Chang;Park, Woo-Chul;Choi, Hyun-Jin
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.163-166
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    • 2009
  • 현재 자동차 검사 또는 정비 현장에서는 특정 삼원촉매변환기가 요구 내구 수명을 제대로 만족시키지 못하여 파손되는 사례가 발생되고 있다. 이러한 삼원촉매장치의 경우 배기가스 변환 효율이나 압력강하 등은 엔진 효율 측면에서 만족되지만 열적 내구성은 만족되지 못한다. 본 연구에서는 열유동 해석 및 구조 해석을 통하여 국내 승용차용 삼원촉매 변환기의 대한 열적 안전성에 대하여 검토하였다.

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A study on Screening Test Methods of Three-Way Catalyst for Automobile Emission Control (자동차 배기정화용 3원촉매 성능평가 시험방법에 대한 고찰)

  • 박경석;정석진
    • Journal of the korean Society of Automotive Engineers
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    • v.9 no.2
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    • pp.5-11
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    • 1987
  • 선진국에서 사용되고 있는 자동차 배기정화 장치의 성능평가 시험방법은(CVS테스트, 유럽테스트, 일본테스트법 등)배기정화용 3원촉매 뿐만 아니라 그 부수장치의 성능을 포함한 포괄적인 평가방 법이므로 그 결과에 미치는 인자가 대단히 복잡하고 평가비용과 시간도 크게 드는 결점이 있어 서, 3원촉매만의 특성평가와 새로운 촉매의 연구개발의 방향을 추출하기 위하여서는 개선된 새로 운 성능 평가방법이 요구되고 있다. 이에 부응하여 모조합성 배기가스를 이용환 촉매성능측정장 치로부터 실제 엔진배기사스 측정장치에 이르까지 많은 평가시험 방법이 제안되었으나 아직 이러 한 시험방법에 의한 결과와 해석에 대하여서는 많은 관찰의 소지를 남기고 있는 것으로 보고 되 고 있다. 따라서, 본고에서는 기존상업적 3원촉매 뿐만 아니라 앞으로 연구 개발될 새로운 3원 촉매의 특성 및 성능평가에 관하여 미국, 일본 등을 포함한 선진제국의 현행 평가방법을 주로 초기단계에서 제안된 일본자동차연구소 연구보고 중심으로 하여 고찰하고자 한다.

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Precise Air-Fuel Ratio Control on Transient Conditions with the PC-ECU in SI Engine (PC-ECU를 이용한 SI 기관의 비정상상태 정밀공연비 제어)

  • Yoon, S.H.
    • Journal of ILASS-Korea
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    • v.5 no.3
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    • pp.9-16
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    • 2000
  • In a SI engine, three-way catalyst converter has the best efficiency when A/F ratio is near the stoichiometry. The feedback control using oxygen sensors in the commercial engine has limits caused by the system delays. So it is necessary to control fuel quantity in accordance with intake air amount in order to reduce exhaust emission and improve the specific fuel consumption. Precise A/F ratio control requires measurement of air amount with respect to the cylinder and injection fuel according to the air amount In this paper, we applied nonlinear fuel injection model and developed the algorithm of A/F ratio control. This algorithm includes the methods of measurement of transient air mass flowing into each cylinder, of calculation of injection pulse width for measured air mass, and the method of feedback and engine control by using lambda sensor. Also we developed control program for IBM-PC by using C++ Builder, and tested it in the commercial engine.

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Study on the Characteristics of the Design for the Community Building of Facilities for the Elderly (노인시설의 커뮤니티 증진을 위한 디자인 특성에 관한 연구)

  • Kim, Jung-Gon;Koh, Gwi-Han;Bang, Moon-Sun;Han, Chang-Hwan
    • Korean Institute of Interior Design Journal
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    • v.23 no.2
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    • pp.21-29
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    • 2014
  • This study analyzed some of nursing homes in various domestic and foreign regions in order to find solutions to reduce suicidal incidents from the loneliness. To analyze community space of nursing homes, elderly community is analyzed into three categories based on their characteristics (morphological characteristics, Social characteristics, Environmental characteristics). With those three characteristics above, architectural spaces are analyzed the relation with them. Elderly nursing homes are divided with living, nursing, management, and public spaces. The space of elderly nursing homes (classification of function)-elderly community (classification of elderly characteristics) is approached in an architectural way related to the space of elderly nursing homes and elderly characteristics. Through some case studies, specific space relation of elderly nursing homes and elderly community is analyzed. Also, with the building analysis for summary, plans, wards(hospital rooms), cafeteria, program rooms and alley, some of general information and elderly community space is understood. In this study, there will be an analysis of relation of elderly community(morphological, social, environmental characteristics) which is separated into some spaces of elderly nursing homes(living, nursing, public spaces and facilities) written above. Furthermore, if people can recognize the importance of community space for elderly facilities, there will be a new guide line for that which can have a play on catalyst.

Structure and Reactivity of Bimetallic Catalyst (이원금속 촉매의 구조와 반응성)

  • Yie, Jae-Eue
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.24-34
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    • 1992
  • Recent studies dealing with the fundamental understanding and applications of bimetallic catalysts are discussed. Bimetallic catalysts have had a major industrial impact, specifically for the reforming of petroleum naphtha, for the hydrogen reduction of carbon monoxide, and for the three way catalytic converter system. The action of the bimetallic catalysts in these reactions may be interpreted in terms of ensembles, electronic influences and surface structure. Various combinations of metal pairs have been considered in order to evaluate the role played by the added metals. For catalyst selectivity control, the possibility of surface enrichment of one element has been recognised. More generally, the influence of preparative variables on the formation of supported catalysts has been clarified, In particular by temperature programmed reduction (TPR). Information on the structure of bimetallic catalysts has been obtained with chemical probes, such as chemisorption and reaction rate measurement and physical probes, such as extended X-ray absorption fine structure (EXAFS), scanning transmission electron microscopy (STEM) and Xe-NMR.

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Catalytic Technology for NOx Abatement using Ammonia (암모니아를 환원제로 이용한 NOx 저감 촉매 기술)

  • Park, Soon Hee;Lee, Kwan-Young;Cho, Sung June
    • Clean Technology
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    • v.22 no.4
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    • pp.211-224
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    • 2016
  • Three way catalyst has been used extensively for the exhaust gas treatment for the internal combustion gasoline engine. While, numerous research efforts have been directed to develop various technologies for the abatement of exhaust gas from diesel engine. Diesel engine operating under lean condition produces large amount of NOx and the corresponding catalytic technology employing vanadium supported titania using ammonia has been commercialized for heavy duty vehicle. Recently, the Cu catalyst supported on zeolite has been investigated for NOx abatement using ammonia because of its critical importance for ultra low emission vehicle. The current review shows the recent trend in research and development for zeolite based copper catalysts, which are mainly used as catalysts for selective catalytic reduction using ammonia, are one of the aftertreatment technologies for effectively removing nitrogen oxides from diesel exhaust.

A Convergence Study on the Effects of NH3/NOx Ratio and Catalyst Type on the NOx Reduction by Urea-SCR System of Diesel Engine (디젤엔진의 Urea-SCR 시스템에 의한 NH3/NOx 비율 및 촉매 방식이 NOx 저감에 미치는 영향에 관한 융합연구)

  • Yoon, Heung-Soo;Ryu, Yeon-Seung
    • Journal of the Korea Convergence Society
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    • v.10 no.4
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    • pp.131-138
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    • 2019
  • Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

Catalytic Oxidation of Volatile Organic Compounds Over Spent Three-Way Catalysts (배기가스 정화용 폐 자동차 촉매를 이용한 휘발성 유기화합물의 제거)

  • Shim, Wang Geun;Kim, Sang Chai
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.574-581
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    • 2008
  • The optimum regeneration conditions for the regeneration of three way spent catalysts (TWCs), which were taken from automobiles with different driving conditions, were investigated to evaluate the suitability as alternative catalysts for removing VOCs. The spent catalysts were washed with five different acids ($HNO_3$, $H_2SO_4$, $C_2H_2O_4$, $C_6H_8O_7$, and $H_3PO_4$) to remove contaminants and examine the optimum conditions for recovering the catalytic activity. The physicochemical properties of spent and its regenerated TWCs were evaluated by using nitrogen adsorption-desorption isotherms, XRD, and ICP. The relative atomic ratios of contaminants and platinum group metals (PGMs) of the spent TWCs were greatly dependent on the placed positions. The main contaminants formed were lubricant oil additives and metallic components. Also, the regeneration treatment increased the PGMs ratio, BET surface area, and average pore diameter of TWCs. The catalytic activity results indicated that the spent TWCs have the possibility for removing VOCs. Moreover, the employed acid treatments greatly enhanced the catalytic activity of the spent TWCs. Especially, nitric and oxalic acids provided the most improvement in the catalytic behavior. The catalytic activities of the regenerated TWCs were significantly influenced by the containing platinum ratios rather than the removal ratios of contaminants and the changes in the structural properties offered by the acid treatments.

A/F Control of an MPI Engine on Transient Conditions with an Intergration type Ultrasonic Flow Meter (적분형 초음파 유량계를 이용한 MPI 엔진의 비정상상태 공연비 제어)

  • 김중일;장준석;고상근
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.9
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    • pp.36-47
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    • 1999
  • Three-way catalyst converter, cleaning up the exhaust gas contamination of SI engine, has the best efficiency when A/F ratio is near the stoichiometry . The feedback control using oxygen sensors in the exhaust manifold has limits caused by the system delays. So the accurate measurement of air flow rate to an engine is essential to control the fuel injection rate especially on transient condition like the rapid throttle opening and closing. To measure the rapid change of flow rates. the air flow meter for the engine requires quick response, flow reversal detection, and linearity . Tjhe proposed integration type air flow meter (IFM), composed of an ultrasonic flow meter with an integration circuit, has significantly improved the measurement accuracy of air mass inducted through the throttle body. The proposed control method estimated the air mass at the cylinder port using the measured air mass at the throttle . For the fuel dynamic model, the two constant fuel model is introduced . The control parameters from air and fuel dynamics are tuned to minimize the excursion of the air fuel ratio. As a result A/F ratio excursion can be reduced within 5% when throttle rapidly opens and closes at the various engine conditions.

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What is meaning of internet game to the University students?

  • Kim, Jung-Ae
    • International Journal of Internet, Broadcasting and Communication
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    • v.8 no.2
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    • pp.75-80
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    • 2016
  • Objectives : The objective of this study is to examine the experiences of Internet game experience targeting to University students in Korea. Research topics was "What is meaning of internet game to the University students?" Methods : Classical phenomenology underpinned this study. Seven qualitative studies of University students were conducted between 20 and 23 years old. Semi-structured interviews were conducted. Interviews were audio recorded and transcribed verbatim. Phenomenological thematic analysis of data was undertaken. Results : The findings pivot around three interconnected themes :[Expectations for the emotional needs], [Spend time in the cyberspace], [Relieve stress throughout the game], [Instead of satisfaction from virtual reality], [Internet gaming repeat and desires]. The basic need for getting into internet game was [satisfaction from virtual reality was identified]. While internet games was eliminated stress, [Expectations for the emotional needs] and [Spend time in the cyberspace] were the catalyst that makes them repeatedly getting into Internet the game. Based on the result, I suggest that Internet gaming should be recognized as a tool to relieve stress for college students, But it is not satisfied with the reality in virtual space. Therefore, the strategy must be to recognize reality accompanying. And Using a lot of time in cyberspace make them cause of internet game addiction. Therefore, it requires a systematic strategy for the Internet using time limits. Also the emotional needs met were motivated to repeat an Internet game. So another way to meet the emotional needs to college students should be sought.