• Transactions of the Korean Society of Automotive Engineers
• /
• v.14 no.1
• /
• pp.8-16
• /
• 2006

The research was conducted to characterize of Rh-Pd-Pt TWC with a double-layer washcoat for gasoline vehicle. The physical characteristics on surface of catalyst were inspected by BET, SEM and TEM. The characteristics of catalytic reaction were examined by the TPD/TPR and CO-pulse chemisorption. The catalyst $6Hx(0.35\times11\times3)$ showed superior conversion performance after hydrothermal aging process, which was due to small difference of the surface area between. the fresh and the aged catalyst. The CO-chemisorption and surface area were superior in the 600 cpsi catalyst than other catalysts, this catalyst also shown the higher conversion efficiency of the exhaust emissions. From the TPR test, the conversion performance of the aged catalyst was decreased by the agglomeration and sintering of the PM and metal oxides. From the TPD result, it was found that the NO chemisorption was happed on the bottom-layer washcoat with Pd, and the NO chemisorption was re-happened on the upper-layer washcoat with Pt and Rh in the desorption process.

• Journal of Korean Society for Atmospheric Environment
• /
• v.15 no.5
• /
• pp.667-676
• /
• 1999

The roles of ceria on three-way catalyst is to improve the noble metal dispersion and thermal stability of support ${\gamma}$-$Al_2O_3$. And, ceria has a oxygen storage capacity(OSC) under fuel rich/lean conditions to improve the operating windows of NOx, THC and CO conversion. However, ceria has weak thermal stability under high temperature due to the crystallite growth. So that, the OSC of ceria is decreased, and then the conversions of NOx, THC and CO is decreased. One way of enhancing the thermal stability and NOx, THC and CO conversion Pd-only catalyst is to improve as well as its thermal stability and oxygen storage capacity of the ceria. Especially, the appropriate mixing ratios of bulk and stabilized ceria are very important for designing principles of Pd-only three-way catalysts. In this paper, we discussed the thermal properties of stabilizedand unstabilized (bulk) ceria, and the oxygen storage capacity (OSC) of catalysts, and found the correlation between activity and the OSC of Pd-only catalysts with various different mixing ratios of bulk and stabilized ceria. Finally, we propose the design principles to improve the thermal stability of washcoated Pd-only catalysts.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.14 no.12
• /
• pp.6106-6113
• /
• 2013

Automotive three-way catalyst substrate has a cordierite ceramic honeycomb structure. The substrate in the high engine speed range doesn't satisfy the design fatigue life due to the low mechanical properties of cordierite ceramic. SiC ceramic has higher mechanical properties than cordierite ceramic. If the automotive three-way catalyst substrate is made from the SiC ceramic honeycomb structure, the substrate can be prevented from premature failure. In this study, the mechanical properties of SiC ceramic honeycomb substrate were estimated by FEA. The FEA results indicated that the MOR and elastic modulus for the SiC ceramic honeycomb substrate was much higher than those for the cordierite ceramic honeycomb substrate.

• Journal of ILASS-Korea
• /
• v.24 no.4
• /
• pp.163-170
• /
• 2019

In this study, feedback logic using dual O₂ sensor values were developed to increase the purification capability of a three-way catalyst (TWC) in a compressed natural gas (CNG) engine. A heavy-duty inline 6-cylinder engine was used and the CNG was supplied to the engine through a mixer. This study consists of two main parts, namely, the proportional integral (PI) control with a front O₂ sensor and the feedback control with dual O₂ sensors. In the PI control experiment, effects of various parameters, such as P gain, I gain, and lean delay, on the TWC capability were identified. Based on the results of the PI control experiment, the feedback logic using dual O₂ sensor values were developed. In both cases, the nitrogen oxides (NO_X) emissions were nearly zero. However, the carbon monoxide (CO) emissions were reduced significant in the feedback logic with dual O₂ sensors than in the PI control with the front O₂ sensor.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.19 no.3
• /
• pp.90-98
• /
• 2011

Noises from diesel engine are the major issues for noise pollution as well as affect customers' purchasing needs to vehicles powered by diesel engine. This study investigates to screen-out main factors that contribute to noises from diesel engine using VGT 2000cc engine developed recently. Changes of fuel temperature, intake temperature and the presence of three way catalyst don't affect the 'Engine Radiation Noise' and the solely three way catalyst influence on the 'Tail Pipe Noise'. Especially, there are no effects of the presence of three way catalyst on torque, which is main subject that should be considered in secondary study.

• Journal of the Korean Institute of Gas
• /
• v.20 no.6
• /
• pp.23-30
• /
• 2016

The conventional natural gas engine realized lean combustion for the improved efficiency. However, in order to cope with exhaust gas regulations enforced gradually, the interest has shifted at the stoichiometric mixture combustion system. The stoichiometric mixture combustion method has the advantage of a three-way catalyst utilization whose purification efficiency is high, but the problem of thermal durability and the fuel economy remains as a challenge. Hydrogen-natural gas blend fuel (HCNG) can increase the rate of exhaust gas recirculation (EGR) because the hydrogen increases burning speed and lean flammability limit. The increase in the EGR rate can have a positive impact on heat resistance of the engine due to the decreased combustion temperature, and further can increase the compression ratio for efficient combustion. In this study, to minimize the exhaust emission developed HCNG engine with stoichiometric combustion method, developed three-way catalyst was applied to evaluate the conversion characteristics. The tests were carried out during the steady state and transient operating conditions, and the results were compared for both the conventional and proto-three-way catalyst of HCNG engine for city buses.

• Journal of Biosystems Engineering
• /
• v.24 no.6
• /
• pp.465-472
• /
• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

• Clean Technology
• /
• v.15 no.3
• /
• pp.147-153
• /
• 2009

Waste three-way catalysts were remanufactured by ultrasonic wave treatment followed by active component re-impregnation and the catalytic activities and surface properties of remanufactured catalysts were measured at various remanufacturing conditions. In case of the catalyst prepared by ultrasonic wave cleaning, the optimal period for elimination of surface contaminants from the waste catalyst was found to be about 5 minutes. The proper re-impregnation amounts of the active components for the best catalytic performance were investigated and the catalytic performance tests were also carried out with various temperature for the total hydrocarbon (THC), carbon monoxide (CO) and nitrogen oxides (NOx) conversions. The experimental results showed that the catalytic performances of the remanufactured catalysts were recovered almost the same level as those of the fresh catalyst except those of the NOx conversion.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.8 no.1
• /
• pp.92-100
• /
• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.11 no.3
• /
• pp.65-70
• /
• 2003

In this paper, an adapted TWC model and its application to the monitoring algorithm are proposed. As TWCs have the different characteristics, the model has to be corrected to diagnose more accurately. In the TWC model oxygen storage and release rate model are adapted to the installed TWC to whose characteristics related. The model learns from the downstream $O_2$ sensor output during the vehicle's operation. From the results, the model is adapted to the Installed TWC's characteristics. using this model, the monitoring algorithm can diagnose the no more accurately. Finally the algorithm is validated with simulations using the data logged from a retail car.