• Title/Summary/Keyword: Three component reaction

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Identification of Synthesized Pitch Derived from Pyrolyzed Fuel Oil (PFO) by Pressure (석유계 잔사유(PFO)의 피치 합성 시 압력조건에 따른 피치 특성 변화)

  • Seo, Sang Wan;Kim, Ji Hong;Lee, Young-Seak;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.652-656
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    • 2018
  • In this study, effects of the reaction pressure were studied for petroleum-based pitch synthesis. A two-stage reaction process was performed based on different reaction pressure conditions. Each stage experiments for the two-stage reaction were consecutively carried out. The first stage was consisted of three different pressure conditions; high (10 bar), normal and low (0.1 bar). And the second stage was carried out at the normal and low (0.1 bar) pressure. The pitch synthesis was realized at $400^{\circ}C$ for 2 h. Thermal properties and molecular weight distributions of each samples were investigated by analyzing the softening point and MALDI-TOF data. Volatilized components during the pith synthesis were measured by GC-SIMDIS. In case of the first-step reaction with the high pressure condition, the low molecular weight component participated to the pitch formation more effectively and the pitch with the low softening point was obtained. However, for the case of the first-step with the low pressure, the low molecular weight component was vent outside and the partial coke formation occurred. Eventually, pitch properties such as the softening point and yield were controlled effectively by changing the pressure in the pitch synthesis reaction.

Computer Simulation of an Automotive Engine Cooling System (자동차 엔진 냉각시스템의 컴퓨터 시뮬레이션)

  • 원성필;윤종갑
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.4
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    • pp.58-67
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    • 2003
  • An automotive engine cooling system is closely related with overall engine performances, such as reduction of fuel consumption, decrease of air pollution, and increase of engine life. Because of complex reaction between each component, the direct experiment, using a vehicle, takes high cost, long time, and slow response to the system change. Therefore, a computer simulation would provide the designer with an inexpensive and effective tool for design, development, and optimization of the engine cooling system over a wide range of operating conditions. In this work, it has been predicted the thermal performance of the engine cooling system in cases of stationary mode, constant speed mode, and city-drive mode by mathematical modelling of each component and numerical analysis. The components are engine, radiator, heater, thermostat, water pump, and cooling fans. Since the engine model is the most important, that is divided into eight sub-sections. The volume mean temperature of eight sub-sections are simultaneously calculated at a time. For detail calculation, the radiator and heater are also divided into many sub-sections like control volumes in finite difference method. Each sub-section is assumed to consist of three parts, coolant, tube with fin, and air. Hence it has been developed the simulation program that can be used in case of design and system configuration changes. The overall performance results obtained by the program were desirable and the time-traced tendencies of the results agreed fairly well with those of actual situations.

Analysis of Varietal Variation in Alkali Digestion of Milled Rice at Several Levels of Alkali Concentration (쌀의 KOH 농도별 붕괴양상에 따른 품종변이 해석)

  • 최해춘;손영희
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.1
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    • pp.31-37
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    • 1993
  • To analyze and classify the varietal variation of alkali digestibility in detail, which is closely connected with the gelatinization temperature and physical characteristics of cooked rice, the patterns of alkali decomposition changed along the alkali concentration were investigated for thirty three Korean leading rice cultivars and new breeding lines(japonica : 25, Tongil-type:8) including five glutinous rice. Principal component analysis was used to condense the information and to classify rice materials according to decomposed reaction pattern at several levels of potassium hydroxide(KOH) concentration. Thirty three rice varieties were classified largely into four groups by the distribution on the plane of upper two principal component scores which contained above 92% of total informations. Group I was consisted of one variety, Dobongbyeo, which owned almost same strong resistance to alkali digestion at the range of 0.8% to 1.6% KOH solutions. Group II included three japonica and Tongil-type glutinous rice varieties, which revealed medium alkali digestion value(ADV) at 1.4% KOH solution and intermediate change in ADV from 0.8% to 1.6% KOH solutions. Most of Tongil-type and early-maturity japonica rice, which exhibited medium-high ADV at 1.4% of KOH concentration and large ADV difference between low and high alkali solutions, were contained in Group III. Group N included most of medium or medium-late-maturity japonica, which showed high ADV at 1.4% KOH and medium or intermediate-high ADV change between low and high alkali solutions. The 1st principal component indicated the average index of ADV through 0.8-1.6% KOH solutions and the 2nd principal component pointed out the factor related with ADV difference between low and high alkali solutions or regression coefficients of ADV change along with the KOH concentrations.

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A Method for Analyzing and Evaluating the Golf Swing Using the Force Platform Data (지면반력분석기를 이용한 골프 스윙의 분석 평가 방법)

  • Sung, Rak-Joon
    • Korean Journal of Applied Biomechanics
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    • v.20 no.2
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    • pp.213-219
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    • 2010
  • The purpose of this study is developing a method to analyze and evaluate a golf swing motion using the ground reaction force (GRF) data. Proper weight shifting is essential for a successful shot in golf swing and this could be evaluated by means of the forces between the feet and ground. GRF during the swing were measured from 15 low-handicapped male golfers including professionals. Four clubs(driver, iron 3, iron 5, and iron 7) were selected to analyze the differences due to different characteristics of club. Swings of each subject were taken using a high speed video camera and GRF data were taken simultaneously by two AMTI force platforms. To simplify the GRF data, forces of the three major component of GRF(vertical, lateral, anterior-posterior force) at 10 predefined temporal events for each trial were selected and the mean of each event were calculated and evaluated. Analyzed vertical GRF (VGRF) data could be divided into two different styles, one-legged and two legged. One-legged style shows good weight transfer to the target leg and most of the previous study shows this style as a typical pattern of good players. Therefore the data from the iron 5 swing obtained from 10 one-legged style golfers are provided as criteria for the evaluation of a swing.

Effects of MgO content of Spinel on the Reaction of Spinel with CaO-Al$_2$O$_3$-SiO$_2$ Slag (CaO-Al$_2$O$_3$-SiO$_2$계 슬래그와 스피넬의 반응에 미치는 스피넬중의 MgO함유량의 영향)

  • 조문규;홍기곤
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.410-416
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    • 1999
  • The reactivity of three kinds of spinels which CaO-Al2O3-SiO2 slag was investigated in terms of mineral phases and microstructures. New crystal products were not formed by reaction of 12CaO.7Al2O3 in the slag with spinels and free MgO components was preferenctially dissolved into slag for MgO-rich spinel and stoichiometric spinel. Meanwhile mineral phase was changed from 12CaO.7Al2O3 to CaO.Al2O3 to CaO.2Al2O3 finally to CaO.6Al2O3 having high melting point for Al2O3 -rich spinel. The Fe-oxide component of the slag was taken up by only stoichiometric spinel grains within the spinel clinker and the trapped amount of Fe-oxide was independent of MgO content of MgO in spinel clinker the more th resistance to slag corrosion but the less resistance to slag penetration.

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A new approach on soil-structure interaction.

  • Gilbert, C.
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.101-110
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    • 2002
  • This article summarises the traditional method of soil-structure interaction based on the modulus of subgrade reaction and shows its weakness. In order to avoid these weakness, a new soil-structure interaction model is proposed. This model considers the soil as a set of connected springs which enables interaction between springs. Its use is as simple as the traditional model but allows to define the soil properties independently from the structural properties and the loading conditions. Thus, the definition of the modulus of subgrade reaction is unnecessary as each component is defined by its own modulii (Young's modulus and shear modulus). The non-linear soil behaviour for the shear stress versus distortion is also incorporated in the model. This feature allows to pinpoint the arching effect in the ground and shows how the stresses concentrate on stiff materials. Based on these principles, three dimensional program has been developed in order to solve the difficult problem of soil improvement by inclusions (stiff or soft). Also the possibility to take into account a flexible mat and/or a subgrade layer has been implemented. Equations used in the model are developed and a parametric study of the necessary data used in the program is presented. In particular, the Westergaard modulus notion and the arching effect are analysed.

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Evaluating the Reaction Force of Office Chair Backrest for Different Joint Structures (사무용 의자의 조인트 구조에 따른 등판 반발력 분석)

  • Hyeong, Joon Ho;Kim, Sa Yup;Roh, Jong Ryun;Park, Seong Bin;Chung, Kyung Ryul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.535-540
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    • 2015
  • The location of the pivot between the backrest and seat pan of a reclining chair should be identical to the hip joint center to prevent unpleasant user experiences during tilting motion. However, mechanical friction occurs in the pin-in-slot joints that are installed under the seat pan as an alternative to the hinge joint. This reduces the reaction force between the backrest and the occupant's back when reclining and returning to an upright position, which causes the occupant's discomfort. In this study, bearings, rollers, and sliders were suggested as alternatives for the pin component, and the percentage of the reaction force on the backrest was measured while reclining the backrest and subsequently returning it to an upright position. The results show when bearings, rollers, and sliders were used for the pin-in-slot joint, the percentages of the reaction force were $59.7{\pm}10.3$, $47.2{\pm}13.6$, and $30.3{\pm}18.1$, respectively, indicating that the friction of the bearing was the lowest among the three pin components. Because the three alternatives have different manufacturing costs, synthetic judgment requires the consideration of not only mechanical friction but also user experience.

Uncertainty reaction force model of ship stern bearing based on random theory and improved transition matrix method

  • Zhang, Sheng dong;Liu, Zheng lin
    • Ocean Systems Engineering
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    • v.6 no.2
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    • pp.191-201
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    • 2016
  • Stern bearing is a key component of marine propulsion plant. Its environment is diverse, working condition changeable, and condition severe, so that stern bearing load is of strong time variability, which directly affects the safety and reliability of the system and the normal navigation of ships. In this paper, three affecting factors of the stern bearing load such as hull deformation, propeller hydrodynamic vertical force and bearing wear are calculated and characterized by random theory. The uncertainty mathematical model of stern bearing load is established to research the relationships between factors and uncertainty load of stern bearing. The validity of calculation mathematical model and results is verified by examples and experiment yet. Therefore, the research on the uncertainty load of stern bearing has important theoretical significance and engineering practical value.

Assessment of the Changes in the Microbial Community in Alkaline Soils using Biolog Ecoplate and DGGE (Biolog Ecoplate와 DGGE 방법을 이용한 알칼리화 토양의 미생물군집 변화 평가)

  • Lee, Eun Young;Hong, Sun Hwa
    • KSBB Journal
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    • v.28 no.5
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    • pp.275-281
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    • 2013
  • Soil microbial community analysis of farmland soil sprayed with lye in order to use fertilizer in Nigeria was performed. As a control, two kinds of soils not sprayed with lye, located in Eungo and Lagos with general practice in agriculture was selected. Soil sprayed with lye was pH 8.25 through alkalization reaction, while the other soil samples were pH 6.22 and 5.94. Substrate utilization and species diversity index of soil sprayed with lye were low than that of the other soils with the analysis of Biolog ecoplate. As a result of principal component analysis, the relationship between three samples was low. Microbial community analysis was performed by DGGE and most of them were soil uncultured bacterium. Especially, Uncultured Acidobacteria and Uncultured Methylocystis sp., which had been isolated from the rhizosphere of soybean grown in that site were discovered in the soil sprayed with lye.

TAMAM RWA Micro-Vibration Test and Analysis (TAMAM 반작용휠의 미소진동 측정 및 분석)

  • 오시환;이승우;최홍택;이선호;용기력
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.836-839
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    • 2003
  • In this paper, we briefly introduce the test bench and test method of RWA micro-vibration. TAMAM RWA (Reaction Wheel Assembly) micro-vibration was measured on a KISTLER dynamic plate which can measure time signals of three orthogonal forces and torques simultaneously up to 400Hz, and test data was analyzed. Measured data were evaluated with respect to the wheel spin rate and the static/dynamic unbalances were estimated from the extracted first harmonic component. The estimated static and dynamic unbalances were 0.79gㆍcm and 17.4gㆍ$\textrm{cm}^2$ respectively. The resonance mode and two rocking modes were observed as a results of its frequency analysis. Several higher order harmonic components were observed, which comes from its rotor shape as well as the wheel bearing.

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