• 제목/요약/키워드: Three component reaction

검색결과 117건 처리시간 0.027초

경관시뮬레이션을 이용한 아치교량의 시각적 특성평가 (Assessment of Visual Characteristics on Arch Bridge Using Landscape Simulation)

  • 정성관;박영은;박경훈;유주한;김경태;이우성
    • 한국조경학회지
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    • 제35권4호
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    • pp.48-56
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    • 2007
  • This study was to understand the component that affects the formative beauty and to present the direction of bridge design for improving the image of urban landscape to survey the visual effect and landscape Preference by the change of bridge type. The results of this study are as follows. In the results of image analysis by bridge types, the images of one-arch bridges are unique and interesting, whereas more than two successive arched bridge were harmonize, stable, consecutive and regular. In the case of the arch rib, braced-rib arch bridge was assessed that complicated, diverse and interesting more than solid-rib arch bridge. The results of factor analysis on the psychological factor were classified into three categories: orderliness, aesthetic and symbolism. In the results of analysis on psychological factors by bridge types, the orderliness and symbolism were different in the position of path, and the number of arches, too. In case of arch rib, symbolism was different. In the preference analysis, they showed a sensitive reaction in the background of building. In the results of the relativity preference and psychological factor, according to aesthetic, symbolism and orderliness, there was an effect on the background of building. And, there showed the high effect in order of aesthetic, orderliness and symbolism in the background of mountain and building. This study should be objective raw data of the arch bridge design for improving the urban landscape. In the future, aesthetic variables like colors or textures should be considered for more exact evaluation.

Modeling of Hydrodynamic Processes at a Large Leak of Water into Sodium in the Fast Reactor Coolant Circuit

  • Perevoznikov, Sergey;Shvetsov, Yuriy;Kamayev, Aleksey;Pakhomov, Ilia;Borisov, Viacheslav;Pazin, Gennadiy;Mirzeabasov, Oleg;Korzun, Olga
    • Nuclear Engineering and Technology
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    • 제48권5호
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    • pp.1162-1173
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    • 2016
  • In this paper, we describe a physicomathematical model of the processes that occur in a sodium circuit with a variable flow cross-section in the case of a water leak into sodium. The application area for this technique includes the possibility of analyzing consequences of this leak as applied to sodium-water steam generators in fast neutron reactors. Hydrodynamic processes that occur in sodium circuits in the event of a water leak are described within the framework of a one-dimensional thermally nonequilibrium three-component gas-liquid flow model (sodium-hydrogen-sodium hydroxide). Consideration is given to the results of a mathematical modeling of experiments involving steam injection into the sodium loop of a circulation test facility. That was done by means of the computer code in which the proposed model had been implemented.

Comparative and Structural Analysis of the Interaction between β-Lactoglobulin type A and B with a New Anticancer Component (2,2'-Bipyridin n-Hexyl Dithiocarbamato Pd(II) Nitrate)

  • Divsalar, A.;Saboury, A.A.;Mansoori-Torshizi, H.;Hemmatinejad, B.
    • Bulletin of the Korean Chemical Society
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    • 제27권11호
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    • pp.1801-1808
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    • 2006
  • The interaction between whey carrier protein $\beta$-lactoglobulin type A and B (BLG-A and -B) and 2,2'-bipyridin n-hexyl dithiocarbamato Pd(II) nitrate (BPHDC-Pd(II)), a new heavy metal complex designed for anticancer property, was investigated by fluorescence spectroscopy combined with chemometry and circular dichroism (CD) techniques. A strong fluorescence quenching reaction of BPHDC-Pd(II) to BLG-A and -B was observed. Hence, BPHDC-Pd(II) complex can be bound to both BLG-A and -B, and quench the fluorescence spectra of the proteins. The quenching constant was determined using the modified Stern-Volmer equation. The binding parameters were evaluated by fluorescence quenching method. The results of binding study provided evidences presence of two and three sets of binding sites on the BLG-B and -A, respectively, for BPHDC-Pd(II) complex. Using fluorescence spectroscopy and chemometry, the ability of BLG-A and -B to form an intermediate upon interaction with BPHDC-Pd(II) complex was assessed. CD studies displayed that under influence of different concentrations of BPHDC-Pd(II) complex, the regular secondary structure of BLG-B had no significant changes, whereas for BLG-A a transition from $\alpha$-helix to $\beta$-structure was appeared. The results for both of BLG-A and -B displayed that BPHDC-Pd(II) complex can induce a conformational transition from the native form to an intermediate state with a slightly opened conformation, which is detectable with chemometry analyses.

cis-Prenyltransferase interacts with a Nogo-B receptor homolog for dolichol biosynthesis in Panax ginseng Meyer

  • Nguyen, Ngoc Quy;Lee, Sang-Choon;Yang, Tae-Jin;Lee, Ok Ran
    • Journal of Ginseng Research
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    • 제41권3호
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    • pp.403-410
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    • 2017
  • Background: Prenyltransferases catalyze the sequential addition of isopentenyl diphosphate units to allylic prenyl diphosphate acceptors and are classified as either trans-prenyltransferases (TPTs) or cis-prenyltransferases (CPTs). The functions of CPTs have been well characterized in bacteria, yeast, and mammals compared to plants. The characterization of CPTs also has been less studied than TPTs. In the present study, molecular cloning and functional characterization of a CPT from a medicinal plant, Panax ginseng Mayer were addressed. Methods: Gene expression patterns of PgCPT1 were analyzed by quantitative reverse transcription polymerase chain reaction. In planta transformation was generated by floral dipping using Agrobacterium tumefaciens. Yeast transformation was performed by lithium acetate and heat-shock for $rer2{\Delta}$ complementation and yeast-two-hybrid assay. Results: The ginseng genome contains at least one family of three putative CPT genes. PgCPT1 is expressed in all organs, but more predominantly in the leaves. Overexpression of PgCPT1 did not show any plant growth defect, and its protein can complement yeast mutant $rer2{\Delta}$ via possible protein-protein interaction with PgCPTL2. Conclusion: Partial complementation of the yeast dolichol biosynthesis mutant $rer2{\Delta}$ suggested that PgCPT1 is involved in dolichol biosynthesis. Direct protein interaction between PgCPT1 and a human Nogo-B receptor homolog suggests that PgCPT1 requires an accessory component for proper function.

10kW급 건물용 고체산화물연료전지(SOFC) 시스템 모델을 이용한 운전조건 최적화 연구 (Optimization of Operating Conditions for a 10 kW SOFC System)

  • 이율호;양찬욱;양충모;박상현;박성진
    • 한국수소및신에너지학회논문집
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    • 제27권1호
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    • pp.49-62
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    • 2016
  • In this study, a solid oxide fuel cell (SOFC) system model including balance of plant (BOP) for building electric power generation is developed to study the effect of operating conditions on the system efficiency and power output. SOFC system modeled in this study consists of three heat-exchangers, an external reformer, burner, and two blowers. A detailed computational cell model including internal reforming reaction is developed for a planer SOFC stack which is operated at intermediate temperature (IT). The BOP models including an external reformer, heat-exchangers, a burner, blowers, pipes are developed to predict the gas temperature, pressure drops and flow rate at every component in the system. The SOFC stack model and BOP models are integrate to estimate the effect of operating parameters on the performance of the system. In this study, the design of experiment (DOE) is used to compare the effects of fuel flow rate, air flow rate, air temperature, current density, and recycle ratio of anode off gas on the system efficiency and power output.

수용액 중의 염료 제거를 위한 폐수처리공정의 특성(2) - 반응성염료의 오존산화 및 섬유상활성탄 흡착 처리 - (Characteristics of The Wastewater Treatment Processes for The Removal of Dyes in Aqueous Solution(2) - Ozonation or ACF Adsorption Treatment of Reactive Dyes -)

  • 한명호;허만우
    • 한국염색가공학회지
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    • 제19권3호
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    • pp.26-36
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    • 2007
  • This study was carried out to treat the aqueous solutions containing reactive dyes(RB19, RR120 and RY179) by the Ozone demand flask method and adsorption process using activated carbon fiber(ACF) which are one of the main pollutants in dye wastewater. Ozone oxidation of three kinds of the reactive dyes was examined to investigate the reactivity of dyes with ozone, competition reaction and ozone utilization on various conditions for single- and multi-solute dye solution. Concentration of dyes was decreased continuously with increasing ozone dosage in the single-solute dye solutions. Competition quotient values were calculated to investigate the preferential oxidation of individual dyes in multi-solute dye solutions. Competition quotients(CQi) and values of the overall utilization efficiency, ${\eta}O_3$, were increased at 40mg/l of ozone dosage in multi-solute dye solutions. ACF(A-15) has much larger specific surface area$(1,584m^2/g-ACF)$ in comparison with granular activated carbon adsorbent (F400, $1,125m^2/g-GAC$), which is commonly used, and most of pores were found to be micropores with pore radius of 2nm and below. It was found that RB19 was most easily adsorbed among the dyes in this study. In the case of PCP (p-chlorophenol) and sucrose, which are single component adsorbate, adsorption capacities of ACF(A-15) were in good agreement with the batch adsorption measurement, and saturation time predicted of ACF columns for these components was also well agreed with practically measured time. But in the case of reactive dyes, which have relatively high molecular weight and aggregated with multi-components, adsorption capacities or saturation time predicted were not agreed with practically measured values.

아연 결정유약의 제조 및 분산이 결정생성에 미치는 영향 (Effect of manufacturing and dispersion of zinc crystalline glaze on crystal formation)

  • 이지연
    • 한국결정성장학회지
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    • 제31권6호
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    • pp.240-246
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    • 2021
  • 도자 생산현장에서 아연결정유약을 제조하여 사용할 때 조성원료에 따라 유약의 결정생성이 불안정하고, 특히 결정이 잘 생성되는 유약도 습식제조 후 시간이 경과하면 결정생성이 급격히 저하되는 문제점이 있다. 도예가들이 주로 사용하는 산화아연(ZnO)과 하소아연(calcined ZnO), 프리트 3110, 그리고 규석을 출발 물질로 3성분계 실험을 통하여 아연결정 조성을 선택하고 선 연구된 소성 조건을 사용하였다. 유약을 제조하고 1일~24주까지 습식으로 보관하면서 침수 과정에서 아연이 아연결정유의 결정생성에 미치는 영향을 규명하고자 하였다. 원료 입도 및 침수 영향을 측정하기 위해 입도분석, XRD, Raman Spectroscopy 그리고 SEM 분석 등을 하였다. 연구결과, 산화아연은 습식으로 유약 사용 시 willemite 결정 생성 및 성장이 우수하지만 유약을 보관하는 동안 ZnO가 물과 반응하여 Zn(OH)2를 생성하고 응집되면서 유약내 ZnO량이 감소되어 willemite 생성을 저해하여 결정이 감소됨을 확인하였다.

Genetic diversity of Indonesian cattle breeds based on microsatellite markers

  • Agung, Paskah Partogi;Saputra, Ferdy;Zein, Moch Syamsul Arifin;Wulandari, Ari Sulistyo;Putra, Widya Pintaka Bayu;Said, Syahruddin;Jakaria, Jakaria
    • Asian-Australasian Journal of Animal Sciences
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    • 제32권4호
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    • pp.467-476
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    • 2019
  • Objective: This research was conducted to study the genetic diversity in several Indonesian cattle breeds using microsatellite markers to classify the Indonesian cattle breeds. Methods: A total of 229 DNA samples from of 10 cattle breeds were used in this study. The polymerase chain reaction process was conducted using 12 labeled primers. The size of allele was generated using the multiplex DNA fragment analysis. The POPGEN and CERVUS programs were used to obtain the observed number of alleles, effective number of alleles, observed heterozygosity value, expected heterozygosity value, allele frequency, genetic differentiation, the global heterozygote deficit among breeds, and the heterozygote deficit within the breed, gene flow, Hardy-Weinberg equilibrium, and polymorphism information content values. The MEGA program was used to generate a dendrogram that illustrates the relationship among cattle population. Bayesian clustering assignments were analyzed using STRUCTURE program. The GENETIX program was used to perform the correspondence factorial analysis (CFA). The GENALEX program was used to perform the principal coordinates analysis (PCoA) and analysis of molecular variance. The principal component analysis (PCA) was performed using adegenet package of R program. Results: A total of 862 alleles were detected in this study. The INRA23 allele 205 is a specific allele candidate for the Sumba Ongole cattle, while the allele 219 is a specific allele candidate for Ongole Grade. This study revealed a very close genetic relationship between the Ongole Grade and Sumba Ongole cattle and between the Madura and Pasundan cattle. The results from the CFA, PCoA, and PCA analysis in this study provide scientific evidence regarding the genetic relationship between Banteng and Bali cattle. According to the genetic relationship, the Pesisir cattle were classified as Bos indicus cattle. Conclusion: All identified alleles in this study were able to classify the cattle population into three clusters i.e. Bos taurus cluster (Simmental Purebred, Simmental Crossbred, and Holstein Friesian cattle); Bos indicus cluster (Sumba Ongole, Ongole Grade, Madura, Pasundan, and Pesisir cattle); and Bos javanicus cluster (Banteng and Bali cattle).

Methylophaga aminosulfidovorans SKI bfmo 오페론의 클로닝 및 구조 분석 (Cloning and Structural Analysis of bfmo Operon in Methylophaga aminosulfidovorans SK1)

  • 임현숙;구재환;김리현;김시욱;조은희
    • 미생물학회지
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    • 제41권1호
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    • pp.1-7
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    • 2005
  • Methylophaga aminosulfidovorans SK1 (KCTC 10323 BP)은 단일 탄소원, 질소원 그리고 에너지원으로 난분해성 화합물인 트리메틸아민을 이용할 수 있다. M. aminosulfidovorans SK1는 진핵세포의 flavin-containing monooxygenase와 유사한 유전자(bFMO)를 지니고 있으며 대장균에서 발현된 재조합 단백질은 강력한 트리메틸아민 산화활성을 보인다. 본 연구에서는 bEMO의 기능과 조절 메커니즘을 연구하기 위하여 bfmo의 상단부 및 하단부 유전자의 염기서열을 결정하였다. bfmo 상단부의 세 개의 열린해독틀은 잘 보존된 nitrate/nitrite response regulators와 methyl accepting protein 유사단백질을 암호화하였다. 하단부의 두 개의 작은 열린해독틀은 기능은 알려져 있지 않지만 진정세균계에서 잘 보존된 단백질의 일종으로 나타났다. 역전사효소 중합효소증폭반응을 통하여 여섯 개의 유전자는 세 개의 독립된 오페론으로 구성되어 있음을 확인하였다. bfmo의 상단부에 위치하는 세 개의 조절유전자는 두 개의 프로모터에서 전사되었다. 그리고 이와 독립적으로 bfmo와 두 개의 하단부 유전자가 하나의 전사단위를 이루고 있다.

SBR 컴파운드의 가황 및 기계적 성질에 미치는 카본블랙 표면의 화학적 개질의 영향 (Effects of Chemical Surface Modification of Carbon Black on Vulcanization and Mechanical Properties of Styrene-Butadiene Rubber Compound)

  • 이종문;김완두;강신영;장영욱;박수진;나창운
    • Elastomers and Composites
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    • 제36권1호
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    • pp.44-51
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    • 2001
  • 카본블랙의 화학적 표면개질에 따른 영향을 조사하기 위해 3종류 화학약품(KOH, $H_3PO_4$, 벤젠)을 이용하여 카본블랙 표면을 처리하였으며, 이를 함유한 스티렌-부타디엔 고무(SBR)의 가황특성과 기계적 특성을 조사하였다. 산(HCB)이나 염기(KCB)로 표면 처리할 경우 표면 자유에너지의 증가가 관찰된 반면, 벤젠(BCB)의 경우 미세한 증가만이 관찰되었다. London 비극성 성분은 BCB가 가장 높았다. 각 표면처리 카본블랙을 함유한 SBR 컴파운드의 가황반응의 빠르기는 KCB-SBR>BCB-SBR>VCB- SBR(무처리)>HCB-SBR의 순으로 나타났다. 일반적으로 가교도를 나타내는 가황곡선상의 최대토오크와 최소토오크의 차이는 VCB-SBR, KCB-SBR, HCB-SBR에 비해 BCB-SBR이 높은 값을 나타내었다. BCB-SBR과 KCB-SBR의 경우 인장특성과 동적기계적 특성이 증진되었다. 표면자유에너지 중 London 비극성 요소와 기계적 특성간에는 비례관계가 있음이 확인되었다.

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