• Title/Summary/Keyword: Thixotropic

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The Influences of Fatty Alcohol and Fatty Acid on Rheological Properties of O/W Emulsion (고급알코올과 고급지방산이 O/W에멀젼의 유동특성에 미치는 영향)

  • Zhoh, Choon-Koo;Lee, Kang-Yen;Kim, Dong-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.35 no.2
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    • pp.103-110
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    • 2009
  • The objective of this study is to analyze the influences of fatty alcohols and fatty acids on rheological properties of oil in water (O/W) emulsions using viscosity and rheograms. As the chain length of fatty alcohols and fatty acids lengthened, the viscosity of emulsions was increased. The influence of fatty alcohols on viscosity enhancement was stronger than that of fatty acids. Both stearyl alcohol and cetearyl alcohol, which have carbon chain length similar to lipophilic portion of surfactant used in emulsion preparation, had showed the best increase in viscosity of O/W emulsions. O/W emulsions prepared with fatty alcohols and fatty acids were pseudo-plastic fluid and they showed shear thinning behaviour like as the common cosmetic emulsions. O/W emulsions prepared with cetyl alcohol, cetearyl alcohol and stearyl alcohol were thixotropic fluids and thixotropy increased with an increase in the concentration of fatty alcohols and fatty acids. Also O/W emulsions prepared with fatty alcohols were more thixotropic than those prepared with fatty acids. For the sake of viscosity increase related to O/W emulsions stability and spreadability enhancement related to payoff, it is thought that fatty alcohols are more useful than fatty acids in the O/W emulsions as the emulsion stabilizer.

Development of transparent dielectric paste for PDP (플라즈마 디스플레이용 투명 유전체 페이스트의 개발)

  • Kim, Hyung-Jong;Chung, Yong-Sun;Joo, Kyoung;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.50-54
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    • 1999
  • Plasma display panel is a potential candidate for HDTV, due to the fact that the screen size can easily be increased by a thick film technology. In this study, transparent dielectric materials which satisfied the requirements of dielectrics for PDP was developed using lead alumina borosilicate glasses. The Paste which had thixotropic behavior suitable for screen printing was made of this glass composition. the paste became more thixotropic as the particle size decreased. After firing, the cross sectional area of the thick film was analyzed by SEM. The voids in the thick film were removed using bimodal particle system. The dielectric thick film showed good adhesion characteristics.

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Development of Thixoextrusion Process for Light Alloys - Part 1. Microstructural Control of Light Alloys for Thixoextrusion (경량합금 반용융 압출 기술 개발 - Part 1. 반융용 압출을 위한 조직제어)

  • Kim, Shae-K.;Yoon, Young-Ok;Jang, Dong-In;Jo, Hyung-Ho
    • Journal of Korea Foundry Society
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    • v.26 no.5
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    • pp.211-216
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    • 2006
  • The study for thixoextrusion process of 7075, 7003 Al wrought alloys and AZ31 Mg wrought alloy was carried out with respect to reheating rate, isothermal holding temperature and time with an emphasis to the effect of homogenization on thixotropic micro-structures during the partial remelting, especially in the low liquid fraction ($f_L<0.2$). The liquid fraction and average grain size with respect to reheating profile such as reheating rate, isothermal holding temperature and time were almost uniform. It is considered very useful for thixoextrusion in terms of process control such as billet temperature control and actual extrusion time. Micro-structural controls of 7075, 7003 Al wrought alloys and AZ31 Mg wrought alloy before and after homogenization were available and thixotropic microstructures were obtained in both specimens.

Transient rheological probing of PIB/hectorite-nanocomposites

  • Sung, Jun-Hee;Mewis, Jan;Moldenaers, Paula
    • Korea-Australia Rheology Journal
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    • v.20 no.1
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    • pp.27-34
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    • 2008
  • Clay suspensions in liquid polymers exhibit a time-dependent behaviour that includes viscoelastic as well as thixotropic features. Because of the presence of interacting clay platelets, particulate networks can develop, which are broken down during flow and rebuild upon cessation of the flow. Here, the use of thixotropic techniques in probing flow-induced structures in nanocomposites is explored with data on a hectorite-poly(isobutylene) model system. By means of fast stress jump measurements the hydrodynamic contributions to the steady state stresses are determined as well as those caused by the stretching of the clay floes. Flow reversal measurements do not provide a clear indication of flow-induced anisotropy in the present case. The recovery of the clay microstructure upon cessation of flow is followed by means of overshoot and dynamic measurements. The development of a particulate network is detected by the appearance and growth of a low frequency plateau of the storage moduli. The modulus-frequency curves after various rest times collapse onto universal master curves, regardless of the pre-shear history or temperature. The scaling factors for this master curve are the crossover parameters. The crossover moduli are nearly a linear function of the crossover frequency, the relation being identical for recovery after shearing at different shear rates. This function depends, however, on temperature.

The Non Newtonian Flow Mechanism and Rheological Properties of Polyurethane Melts (용융 폴리우레탄의 비 뉴톤 유동 메카니즘과 유변학적인 성질)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.423-428
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    • 2009
  • The non-Newtonian flow curves of polyurethane melts were obtained by using a Physica cone-plate rheometer at various temperatures. The rheological parameters were obtained by applying non-Newtonian flow equation to the flow curves for polyurethane samples. When the polyurethane samples are under increasing-decreasing shear rate modes, the hysteresis loop and thixotropic behavior were shown. Polyurethane melts behave as strong gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, its shear stress remains smaller than the values measured in the increasing shear rate mode, because of broken of its structure.

PRODUCTION OF THIXOTROPLC ALUMINIUM ALLOY BILLETS

  • Pluchon, C.;Loue, W.;Garat, M.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.06a
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    • pp.80-122
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    • 1997
  • The linear electromagnetic stirring process used for the production of aluminium alloy thixotropic billets is described. The influence of the stirring conditions on the structure and rheology of an alloy similar to 319 is presented. Finally, the main characteristics of the SMM process, their impact on the properties of the parts and the major fields of application in the automobile industry are discussed.

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Preparation and Solution Properties of Hydrophobically Modified PVA (소수성기로 개질된 PVA의 제조와 용액의 성질)

  • 이광화;조창기
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.165-166
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    • 2003
  • 완전히 가수분해 된 폴리비닐알콜(PVA)은 에멜전 안정화와 계면활성이 약하다. $^{1)}$ 하지만 hydrophobically modified PVA는 높은 계면활성을 가지고 있을뿐더러 수용액에서 micelle을 형성할 수 있고 게다가 그의 수용액은 높은 viscosity, shear thinning, thixotropic, less salt sensitive 성질을 가지고 있어 enhanced oil recovery operations, drag reduction, flocculation, super absorbency, latex paints, hydraulic fluids, surface coatings등에 사용될 수 있다. $^{2.3)}$ (중략)

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Preparation of Polycrystalline Mullite Fiber Using the Sol-Gel Technique (졸-겔법에 의한 다결정 물라이트 섬유의 제조)

  • 김경용;김윤호;이수원;정형진;김구대
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.795-801
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    • 1989
  • The polycrystalline mullite fiber was synthesized from various combination of starting materials including metal alkoxides and colloidal sol by the sol-gel process. The best spinnability was observed in the sol which showed shear thinning and hysteresis (i.e., thixotropic flow), indicating that the network structure was broken down as the shear rate increased. The mullite fiber was polycrystalline after firing and characterized by thermal analysis, XRD, FT-IR spectroscopy, rheological measurements, and SEM.

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Non-Newtonian Flow Mechanism for Thixotropic and Dilatant Flow Units of Sodium bis-(2-ethylhexyl)sulfosuccinate-water Micelles (Sodium bis-(2-ethylhexyl)sulfosuccinate-water 미셀의 틱소트로 피와 다일레턴시 유동단위에 대한 비뉴톤 유동메카니즘)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.540-548
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    • 2016
  • The non-Newtonian flow curves of sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for AOT-water lamellar liquid crystal samples, the rheological parameters were obtained. Particular attention is given to the hysteresis loop detected when the liquid crystal samples are shear under increasing-decreasing shear stress modes which result in thixotropic and dilatant behavior. Sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals behave as weak gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, the dispersion still preserves much of its structure and consequently its shear stress remains higher than the values measured in the increasing shear rate mode.

Studies on Rheological Characteristics of Red Pepper Pastes (고추장의 유동(流動) 특성(特性)에 관(關한) 연구(硏究))

  • Pyun, Yu-Ryang;Lee, Shin-Young;Lee, Sang-Kyo;Yu, Ju-Hyun;Kwon, Yoon-Jung
    • Korean Journal of Food Science and Technology
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    • v.12 no.1
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    • pp.18-23
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    • 1980
  • Rheological behaviors of red pepper paste acre investigated with rotational viscometer at $25{\sim}55^{\circ}C$ and the following results were obtained. 1. At shear rate of $0.323{\sim}1.653\;sec^{-1}$, red pepper paste was found to be a thixotropic food product which showed pseudoplastic proper ties and also exhibited a yield stress and time dependent characteristics. 2. At a shear rate of 0.978 $sec^{-1}$, flow behavior index, consistency index and yield stress were 0.597, 192.3 dyne $sec^s/cm^{2}$, and 91 dyne/$cm^{2}$ respectively. 3. Variation of consistency of red pepper paste with time was found to be decayed by a second order kinetic equation and thereafter nearly time independent. 4. Variation of consistency of red pepper paste with temperature was found to follow Andrade's equation and the activation energy as calculated on the basis of this equation was $1.03\;kcal/g{\cdot}mole$.

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