• Title/Summary/Keyword: Thin membrane

검색결과 524건 처리시간 0.027초

얇은 막재료의 주름해석 기법 (Analysis Methods of Wrinkle Prediction for Thin Membrane)

  • 배홍수;우경식
    • 한국항공우주학회지
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    • 제41권11호
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    • pp.865-873
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    • 2013
  • 본 논문에서는 유한요소해석에 의한 막재료의 주름 해석 기법에 관하여 연구하였다. 삼각형 세일 형상에 대해 멤브레인 요소와 쉘 요소를 사용하여 주름해석을 수행하였다. 멤브레인 요소를 이용한 기법에서는 주름을 벌칙매개변수에 의한 물성치를 수정하는 알고리즘을 상용프로그램 내 사용자 서브루틴을 통하여 구현하였다. 쉘 요소에 의한 기하학적 비선형 후좌굴 기법에서는 면외방향의 좌굴을 발생시키기 위하여 모델의 메쉬에 작은 크기의 기하학적 결함을 심는 방법을 사용하였다. 쉘 방법에서는 내연 및 외연해석 기법을 고려하였다. 요소수의 증가에 따른 수렴성과 결과의 정확도의 관점에서 멤브레인 요소법과 쉘 요소법의 효율성을 비교하였다.

Hexamethyldisiioxane의 플라즈마 중합에 의하여 제조된 복합막을 통한 공기중의 휘발성 유기물질의 분리에 관한 연구 (Separation of VOCs from Air through Composite Membranes Prepared by Plasma Polymerization of Hexamethyldisiioxane)

  • 류동현;오세중;손우익;구자경
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 추계 총회 및 학술발표회
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    • pp.63-65
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    • 1998
  • 1. Introduction : Atmospheric discharge of VOC-contaminated streams in chemical plants and air streams from chemical processes poses a serious environmental problem and entails large financial losses. Such emissions may be reduced by i) adsorption process, ii) absorption process and iii) incineration process. These processes only forbids the air pollutions. Throughout the recent decade, another technique-membrane process has emerged. The separation and recovery of organic vapors by membrane process may have great economic potential. Most of the published research works on the separation of organic vapors from air were performed using silicon rubber membranes. However, it is very difficult to fabricate very thin membranes with less than 1 $u m thickness. Plasma polymerization could be a good technique to generate a thin polymer film. The objective of this work is to find out the optimum condition of plasma polymerization for producing VOC separation membrane. For the objective, composite membranes are prepared through plasma polymerization of hexamethyldisiloxane onto porous substrates under different conditions. The membrane is then subjected to the permeation of permanent gases and VOCs to find the correlations between the physical properties of the penetrant and permeability and selectivity.

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폴리케톤(PK) 지지체를 이용한 유기용매 역삼투(OSRO) 분리막의 제조 및 특성 평가 (Preparation and Characterization of Organic Solvent Reverse Osmosis (OSRO) Membranes Using Polyketone (PK) Supports)

  • 김성우;홍승희;박희민;이용택
    • 멤브레인
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    • 제34권4호
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    • pp.205-215
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    • 2024
  • 본 연구는 폴리케톤(PK) 지지체를 이용한 유기용매 역삼투(OSRO) 분리막 제조를 목적으로 하였다. 비용매 유도상분리 방법(NIPS)을 통해 PK 지지체를 제작하였고, PK 지지체 위에 polyamide layer를 계면 중합하여 thin-film composite(TFC) 형태로 OSRO 분리막을 완성하였다. 이후 OSRO 분리막의 표면과 단면 구조 및 표면의 화학적 구조를 분석하였고 수투과도와 염 제거율은 각각 약 1.28 LMH/bar와 99.0%의 결과를 얻었다. 또한 OSRO 분리막의 polyamide layer는 유기용매침지 1일 동안 매우 안정적이었고, 단일 유기용매 투과도 경향성은 유기용매 나노여과(OSN) 분리막의 투과도 모델과 일치하였다. OSRO 분리막의 MWCO는 MeOH 상에서 240 g/mol이었다. OSRO 분리막의 MeOH-toluene 혼합용액에 대한 투과도와 separation factor는 상용 OSN 분리막보다 각각 200%와 60%의 높은 결과를 얻었다.

막재료의 난연 및 방염성능 실험에 대한 연구 (Tests of Fire and Flame Retardant Performance for Membrane Materials)

  • 김기철;최광호
    • 한국공간구조학회논문집
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    • 제16권2호
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    • pp.55-60
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    • 2016
  • The Membrane structure has a number of problems in the application of a fireproof code based on general buildings codes. Thus, the fireproof code of membrane structure is necessary to activate the construction of the membrane structure. Because it requires a systematic classification of fire retardant and flame proof performance of membrane material. Fire retardant and flame proof tests are conducted on membrane materials mostly used in current construction to propose the fire and flame retardant performance criteria of membrane materials. Fire and flame retardant tests results, PTFE membrane material with the glass fiber fabric have a limit-combustible performance. PVDF membrane material with the polyester fabric does not ensure the fire retardant performance, but this membrane material has the flame retardant performance of a thick fabric. Also, ETFE does not ensure the fire retardant performance, but this membrane material has the flame retardant of a thin fabric.

지지층 구조가 다른 복합 정삼투막의 기공구조와 분리 특성 (Pore Structure and Separation Properties of Thin Film Composite Forward Osmosis Membrane with Different Support Structures)

  • 안수현;김인철;송두현;제갈종건;권영남;이희우
    • 멤브레인
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    • 제23권3호
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    • pp.251-256
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    • 2013
  • 본 연구에서는 아세틸화된 메틸 셀룰로스를 복합박막 정삼투막의 지지층으로 사용하였다. 계면중합법을 이용하여 선택성이 우수한 폴리아미드 활성층을 다양한 지지층 위에 코팅하였다. 아세틸화된 메틸 셀룰로스 지지층 위에 코팅된 복합박막 정삼투막의 구조와 성능을 다른 지지층 위에 코팅된 복합박막 정삼투막과 비교하였다. 실험적 결과는 아세틸화된 메틸 셀룰로스 지지층 위에 코팅된 복합박막 정삼투막의 성능이 다른 정삼투막들에 비해서 우수하였으며 이것은 구조적인 특성과 염의 낮은 역확산속도 때문인 것으로 사료된다.

저온 플라즈마 공정의 복합막 제조에의 응용 (Application of Low Temperature Plasma Treatment to the Fabrication of Thin Film Composite Membrane)

  • 김현일;김성수;전배혁
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 추계 총회 및 학술발표회
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    • pp.120-122
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    • 1998
  • 현재 상업화되어있는 RO membrane으로는 크게 asymmetric membrane과 composite membrane으로 구분될 수 있다. Asymmetric membrane의 소재로는 Cellulose acetate나 Cellulose triacetate와 같은 것들이 사용되며 현재에도 많이 사용되고 있으나, 보다 더 우수한 성능을 갖는 분리막을 제조하기 위해 현재에는 주로 composite membrane 형태로 제조된다. 대부분의 composite membrane은 계면중합에 의해 제조되는데 대표적인 membranem으로는 FT-30이 있다. 이 밖에도 support의 표면을 직접 플라즈마 처리하여 복합막을 제조하는 공정이 있으며 polyactrylonitrile과 같은 membrane이 이에 속한다. 플라즈마 처리된 복합막은 처리 대상에 크게 영향을 받지 않고 support 표면에 crosslinking의 형태로 형성되기 때문에 active layer가 매우 안정하며 따라서 우수한 물리화학적 성질을 기대할 수 있다. 이밖에도 분리막 표면을 친수성 단량체로 플라즈마 처리함으로써 분리막 표면에 친수성을 부여하거나 관능기를 도입함으로써 불활성 표면을 활성화 시킬 수도 있는 등의 여러가지 장점을 가지고 있다.

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PRO 분리막 및 모듈성능에 지지체가 미치는 영향 (The effect of backing layer for pro membranes and modules)

  • 한만재;전은주;심연주;이종화
    • 상하수도학회지
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    • 제30권5호
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    • pp.553-559
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    • 2016
  • There has been increasing global interest in the environmental pollution problems produced by fossil fuel consumption and greenhouse gas emissions. In order to tackle these issues, new renewable energy such as solar, wind, bio gas, fuel cell and pressure retarded osmosis(PRO) have been developed extensively. Among these energy sources, PRO is one of the salinity gradient power generation methods. In PRO, energy is obtained by the osmotic pressure generated from the concentration difference between high and low concentration solutions separated by a semipermeable membrane. The development for high power density PRO membranes is imperative with the purpose of commercialization. This study investigates development of thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on power density was identified, and the characteristic factors of PRO membranes was determined. Different backing layers were used to improve power density. As expected, the PRO membrane with more porous backing layer showed higher power density.

CATALYTIC MEMBRANE REACTOR FOR DEYDROGENATION OF WATER VIA GAS-SHIFT

  • Tosti, Silvano;Castelli, Stefano;Violante, Vittorio
    • 한국막학회:학술대회논문집
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    • 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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    • pp.43-47
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    • 1999
  • Pd-ceramic composite membranes and catalytic membrane reactors(CMR) have been studied for hydrogen purification and recovery in th fusion reactor fuel cycle. The development of techniques for coating microporous ceramic tubes with Pd and Pd/Ag layers is described: composite membranes have been produced by electroless deposition (Pd/Ag film of 10-20${\mu}{\textrm}{m}$) and rolling of thin metal sheet (Pd and Pd/ Ag membranes of 50-70 ${\mu}{\textrm}{m}$). Experimental results on electroless membranes showed that the metallic film presented some defects and the membranes had not complete hydrogen selectivity . Then the catalytic membrane reactors with electroless membranes can be applied for some industrial processes that do not require a complete separation of the hydrogen (i.e. in the dehydrogenation of hydrocarbons). The rolled thin Pd/Ag membranes separated the hydrogen from the other gas with a complete selectivity and exhibited a slightly larger (about a factor 1.7) mass transfer resistance with respect to the electroless membranes. Experimental tests confirmed the good performances in terms of durability.

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Membrane Morphology: Phase Inversion to Electrospinning

  • Chanunpanich N.;Byun Hongsik;Kang Inn-Kyu
    • 멤브레인
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    • 제15권2호
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    • pp.85-104
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    • 2005
  • Recently, membrane can be prepared by two methods, phase inversion and electrospinning techniques. Phase inversion technique is a conventional but commercially preparation membrane. The most versatile of preparation in this technique is immersion of the cast film into nonsolvent bath, causing dense top layer with a finger-like pattern in the sub layer membrane. The membrane pore size getting from phase inversion is in the range of micro or submicrometer. As a result, it can be used as microfiltration and ultrafiltration applications. A new technique, electrospinning, is introduced for membrane preparation. Nonwoven nanofibrous mat or nanofibrous membrane is obtained. In this technique, electrostatic charge is introduced to the solution jet, causing a thin fiber with high surface area; hence it can be used in the applications where high surface area-to-volume or length-to-diameter ratios are required. Moreover, the pore size can be controlled by controlling the time of electrospinning. Hence, it can be used as a filter for filtering microparticles as well as nanoparticles.

The use of the strain approach to develop a new consistent triangular thin flat shell finite element with drilling rotation

  • Guenfoud, Hamza;Himeur, Mohamed;Ziou, Hassina;Guenfoud, Mohamed
    • Structural Engineering and Mechanics
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    • 제68권4호
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    • pp.385-398
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    • 2018
  • In the present paper, we offer a new flat shell finite element. It is the result of the combination of a membrane element and a bending element, both based on the strain-based formulation. It is known that $C^{\circ}$ plane membrane elements provide poor deflection and stress for problems where bending is dominant. In addition, they encounter continuity and compliance problems when they connect to C1 class plate elements. The reach of the present work is to surmount these problems when a membrane element is coupled with a thin plate element in order to construct a shell element. The membrane element used is a triangular element with four nodes, three nodes at the vertices of the triangle and the fourth one at its barycenter. Each node has three degrees of freedom, two translations and one rotation around the normal. The coefficients related to the degrees of freedom at the internal node are subsequently removed from the element stiffness matrix by using the static condensation technique. The interpolation functions of strain, displacements and stresses fields are developed from equilibrium conditions. The plate element used for the construction of the present shell element is a triangular four-node thin plate element based on Kirchhoff plate theory, the strain approach, the four fictitious node, the static condensation and the analytic integration. The shell element result of this combination is robust, competitive and efficient.