• Title/Summary/Keyword: Thick Oxidation

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Effect of V on High Temperature Oxidation of TiAl Alloy (TiAl합금의 고온산화에 미치는 V효과)

  • ;Morihiko Nakamura
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.329-333
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    • 2003
  • The high-temperature oxidation behavior of Ti39Al-10V alloy that consisted primarily of $\beta$-Ti, ${\gamma}$-TiAl, and $\alpha_2$ $-Ti_3$Al phases was studied. The relatively thick and porous oxide scales formed consisted primarily of an outermost, thin TiO$_2$ layer, and an outer, thin $Al_2$$O_3$-rich layer, and an inner, very thick (TiO$_2$, $Al_2$$O_3$) mixed layer. Vanadium was present uniformly throughout the oxide scale. The formation and subsequent evaporation of V-oxides such as VO, $VO_2$, and $V_2$O$_{5}$ deteriorated oxidation resistance and scale adherence of the TiAl alloy significantly.y.

Tunneling Magnetoresistance in Si/$SiO_2$/NiFe/$Al_2$$O_3$/Co Thin Films (Si/$SiO_2$/NiFe/$Al_2$$O_3$/Co 박막의 투과자기저항 특성 연구)

  • 현준원;백주열
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.11
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    • pp.934-940
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    • 2001
  • Magnetic properties were investigated for Si/SiO$_2$/NiFe(300 )/A1$_2$O$_3$(t)/Co(200 ) junction related with the parameters of $Al_2$O$_3$. Insulating $Al_2$O$_3$ layer was formed by depositing a 5~40 thick Al layer, followed by a 90~120s RF plasma oxidation in an $O_2$ atmosphere. Magnetoresistance was not observed for tunnel junction with 5~10 thick Al layer, but magnetoresistance was observed large for tunnel junction with 15~40 thick Al layer. Oxidation time did not largely influence magnetoresistance. Tunnel magnetoresistance effect depended on magnetization behavior of two ferromagnetic layers. Tunneling junction was confirmed through nonlinear I-V curve. In this work, tunneling magnetoresistance(TMR) up to 30 % was observed. This apparent TMR is an artifact of the nonuniform current flow over the junction in the cross geometry of the electrodes.

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High Temperature Oxidation Behavior of Ni-W Coatings Electrodeposited on Steel (강기판 위에 코팅된 Ni-W의 고온산화거동)

  • 고재황;권식철;장도연;이동복
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.430-436
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    • 2003
  • The nanoocrystalline Ni-l5W(at.%) coating electrodeposited on the high carbon steel was oxidized at 700 and $800^{\circ}C$ in air, and the resultant oxidation properties were investigated using XRD, EPMA, TGA and TEM. The oxidation resistance of the coating was not so good that most of the coating was oxidized after oxidation at $800^{\circ}C$ for 5 hrs. The oxidation led to the formation of the outer, thin NiO oxide scale and the inner, porous, rather thick ($NiWO_4$+NiO) mixed layer containing a bit of $WO_2$. During oxidation, substrate elements such as Fe and Cr diffused outwardly toward the coating, according to the concentration gradient.

Impedance Analysis of Resistance Anomaly of $BaTiO_3$ based PTC thermistor

  • Chun, Myoung-Pyo;Myoung, Seong-Jae;Nam, Joong-Hee;Cho, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.182-182
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    • 2009
  • The effect of Re-oxidation on the PTCR properties of Sm-doped barium titanate ceramics was investigated by means of impedance spectroscopy. Electrical properties such as resistance vs. temperature, I-V curve were measured and microstructure was observed with SEM photography. Sample was fabricated with thick film process such as tape casting of green sheet, screen printing of electrode pattern, stacking, firing in reduced atmosphere and re-oxidation, etc. As the temperature of re-oxidation increases, resistance jump as a function of temperature enhances but resistance at room temperature increases. These behavior of resistance as a function of temperature, dependent on the re-oxidation condition, is analyzed with Cole-Cole impedance plot and is shown to be related with the degree of oxidation of grain boundary regardless of grain core during re-oxidation process of sample.

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The Oxidation of TiB$_2$ Ceramics (TiB$_2$ 세라믹스의 산화)

  • 이동복;이영찬
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.25-32
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    • 2001
  • $TiB_2$ ceramics were oxidized at 800, 900 and $1000^{\circ}C$ in air for 40 hr, and their oxidation property was investigated using TGA, XRD, SEM and EPMA. The oxidation resistance decreased with an increase in oxidation temperature. The scale was essentially composed of $TiO_2$ only. $B_2$$O_3$ formed during oxidation escaped from the $TiO_2$ oxide scale owing to its high vapor pressure. This made the oxide scale highly porous and thick. The oxidation reaction was mainly governed by the inward transport of oxygen.$ TiO_2$ existing at the outermost scale grew into peculiarly shaped blades, as the reaction progressed.

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High-temperature Oxidation of the TiAlCrSiN Film Deposited on the Cemented Hard Carbide

  • Lee, Dong Bok
    • Journal of the Korean institute of surface engineering
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    • v.47 no.5
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    • pp.252-256
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    • 2014
  • The TiAlCrSiN film was deposited on the WC-20%TiC-10%Co carbide, and its oxidation behavior was examined at $700-1000^{\circ}C$. It displayed relatively good oxidation resistance owing to the formation of $TiO_2$, $Al_2O_3$, $Cr_2O_3$, and $SiO_2$ up to $900^{\circ}C$. However, at $1000^{\circ}C$, the fast oxidation rate and partial oxidation of WC in the substrate led to the formation of the thick, fragile oxide scale.

High-temperature Oxidation of Ni-based Inconel 713 Alloys at 800-1100℃ in Air (니켈기 인코넬 713합금의 800-1100℃에서의 대기중 고온산화)

  • Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.196-200
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    • 2011
  • The Ni-based superalloy, Inconel 713, was oxidized at $800{\sim}1100^{\circ}C$ for 50 and 100 hours in air. It displayed excellent oxidation resistance, forming a few micrometer-thick scales. The major scale was ${\alpha}-Al_2O_3$. Other scales formed were $TiO_2$, $NiAl_2O_4$ and $Cr_2O_3$. Generally, uniform oxidation occurred over the alloy surface, resulting in the formation of ${\alpha}-Al_2O_3$ with and without $Cr_2O_3$. Other oxides such as $TiO_2$ and $NiAl_2O_4$ sometimes also formed. Locally, nodular oxidation occurred at the nodules that consisted of diverse alloying elements. The scales were adherent at $800^{\circ}C$. However, they spalled a little at $900{\sim}1100^{\circ}C$.

The oxidation of Fe-(21.8, 24.1, 27.2)%Al intermetallics (Fe-(21.8, 24.1, 27.2)%Al 금속간 화합물의 고온 산화)

  • 김기영;이동복
    • Journal of the Korean institute of surface engineering
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    • v.33 no.5
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    • pp.365-372
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    • 2000
  • Pure $Fe_3$Al alloys with three different compositions of Fe-21.8%Al, Fe-24.1%Al and Fe-27.2%Al were prepared by vacuum induction melting followed by homogenization and hot forging. The long-time oxidation behavior of the prepared alloys was studied at 1073, 1273 and 1473k in air. The oxidation resistance greatly increased with an increase in Al contents. Thin and uniform oxide scales were always formed on Fe-27.2%Al, while thick and fragile oxide scales were formed on Fe-(21.8, 24.1%)Al. Internal oxidation was observed in Fe-(21.8, 24.1%)Al, when oxidized above 1273K. The major oxidation product of all the oxidized alloys was always $\alpha$-$Al_2$$O_3$.

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IMPROVEMENT IN HIGH FREQUENCY MAGNETIC PROPERTIES OF THIN AMORPHOUS RIBBONS BY SURFACE OXIDATION

  • Ooae, K.;Fukunaga, H.;Kakehashi, H.;Ogasawara, H.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.597-600
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    • 1995
  • The effects of surface oxidation on magnetic properties were investigated at high frequencies (10k-100MHz) for $7-18\mu\textrm{m}$ thick $Co_{70}Fe_{5}Si_{15}B_{10}$ amorphous ribbons with controlled domain structure. Oxidation was accelerated by acid-treatment or anodic oxidation treatment, and the insulation layers were prepared on the surfaces of the ribbons. The acid-treatment was effective in improving permeability and magnetic loss. Although the anodic oxidation treatment was effective in both making oxide layer and thinning, the magnetic properties were not improved compared with the case of the acid-treatment.

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