• KCI Concrete Journal
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• 제13권2호
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• pp.58-66
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• 2001

Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top coat with thin thickness, typically 5~15mm. The purpose of this study is to evaluate basic properties of self-leveling materials using polymer dispersions as kinds of SBR, PAE, St/BA with thin coat (under 3mm). Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as to facilitate the workability required. The self-leveling materials using four types of polymer dispersion are prepared with polymer-cement ratio which respectively range from 50% and 75%, and tested for basic characteristics such as unit weight, air content, flow, consistency change and adhesion in tension. From the test results, the self-leveling materials using PAE emulsion at curing age of 28days are almost equal to those of conventional floor using urethane and epoxy resin. The adhesion in tension of self-leveling mortars using SBR latex and PAE emulsion at curing age of 3days is over 17 kgf/cm$^2$(1.67MPa). Consistency change is strongly dependent on the type of polymer dispersion. It is concluded that the self-leveling materials using polymer dispersions can be used in the same manner as conventional floor using thermosetting resin in practical applications, in the selection of polymer dispersions.

• Composites Research
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• 제28권3호
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• pp.99-103
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• 2015

본 논문에서는 복합재료 제조공정 중 온도에 따른 경화 반응을 이해하고 열분석을 수행하였으며, 이 결과를 바탕으로 온도에 따른 수지의 경화도 및 비열의 변화를 수식화하였다. 온도에 따른 경화도와 비열은 DSC와 MDSC (Modulated DSC)를 활용하여 측정하였다. DSC와 MDSC 분석은 Isothermal과 Dynamic 조건으로 수행하여 Cure Kinetics, 유리전이온도 및 비열을 측정하고, 회기 분석 방법을 이용하여 물성거동을 수학적으로 모델링하였다.

• 전기학회논문지
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• 제67권12호
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• pp.1633-1640
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• 2018

Epoxy resin is a polar thermosetting polymer that is widely employed in different branches of industry and everyday life, due to their stable physical and chemical properties. Of all the polymer materials currently being used in the electrical insulation industry, epoxy resin is the most widely used kind, chosen as the base polymer material in the present study. Composites were prepared according to the mixing ratio (MS: MA, 1: 9, 3: 7, 5: 5, 7: 3, 9: 1)of mixture for Heterogeneous Minerals(Micro Silica:MS, Micro Alumina:MA) (MS+MA). We have investigated for AC electrical insulation breakdown characteristics and the dielectric properties (permittivity, dielectric loss, and conductivity) with frequency changes. The electrical AC insulation breakdown performance was improved with the increase of the mixing ratio of MS according to heterogeneous mineral material mixture(MS+MA). As Dielectric properties, the dielectric constant and dielectric loss increased with decreasing frequency and decreased with increasing MS content ratio of heterogeneous mineral mixture. Tensile strength and flexural strength according to the mixing ratio (MS + MA) of epoxy / heterogeneous mineral mixture were studied by mechanical properties. The performance of mechanical tensile and flexural strength was significantly improved as the fill contents ratio of MS increased.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.380-380
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• 2013

본 논문에서는 외기 환경 요인 중에서 H2O와 O2의 영향으로 성능이 저하되는 유기박막트랜지스터(OTFT)의 수명시간 향상을 위하여 필요한 passivation layer의 효과에 대하여 알아 보았다. OTFT에 기존의 액상 공정이나 증착 공정으로 단일 passivation layer또는 다층 passivation layer를 형성하는 방식과는 다르게 향후에 산업 전반에 적용이 기대되는 것을 고려하여 제작 공정의 간편성을 위하여 film 형태로 되어 있는 열경화성 epoxy resin film으로 passivation layer를 구현하는 방법을 사용하여 OTFT의 storage stability를 평가하였다. passivation layer가 없는 OTFT와 열경화성 epoxy resin film으로 passivation된 OTFT의 전기적 특성이 서로 비교 평가되었으며 또한 30일 동안 온도 $25^{\circ}C$ 상대습도 40%의 환경을 갖는 Desicator 안에서 소자를 보관하여 시간에 따른 전기적 특성 변화를 검증하여 epoxy resin film의 passivation layer으로의 적용가능성을 검증하였다. 결과적으로 30일 후의 passivation layer가 없는 OTFT의 전기적 특성은 매우 낮게 떨어진 반면에 epoxy resin film으로 passivation layer가 구현된 OTFT의 mobility는 $0.060cm^2$/Vs, VT는 -0.18 V, on/off ratio는 $3.7{\times}10^3$으로 초기의 소자 특성이 잘 유지되는 결과를 얻었다. OTFT는 Flexible한 polyethersulfone (PES)기판에 게이트 전극이 하부에 있는 Bottom gate 구조로 제작되었고 채널 형성을 위한 유기반도체 재료로 6,13-bis (triisopropylsilylethynyl) (TIPS) pentacene이 사용되었고 spin coating된 Poly-4-vinylphenol (PVP)가 게이트 절연체로 사용되었다. 이때 Au전극은 Shadow mask를 이용하여 증착하였다. 또한 OTFT의 채널 길이 $100{\mu}m$, 채널 폭 $300{\mu}m$의 영역에 Drop casting법을 사용하여 채널을 형성하였다. 물리적 특성은 scanning electron microscopy (SEM), scanning probe microscopy (SPM), x-ray diffraction (XRD)를 사용하여 분석하였고, 전기적 특성은 Keithley-4200을 사용하여 추출하였다.

• 대한치과교정학회지
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• 제20권1호
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• pp.103-110
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• 1990

Metal brackets were recycled by variable methods for economic reason. Such recycling methods had a great effect on bracket slot width and bonding strength. Therefore, the recycling methods that don't change the properties of original bracket were suggested. In this study, debonded brackets were recycled with 30 kinds of solvents and bracket surfaces were examined by S.E.M. (Super IIIA, ISI International Scientific Instruments, Japan) and Stero Microscope (Sz-Tr, Olympus Tokyo, Japan) methods. The following results were obtained. 1. Thermosetting resin adhesives (eq. $Monolok^{(R)}$, $Concise^{(R)}$) were swelled most in sulfuric acid (assays 95%) and slightly in alcohol groups. 2. The solvent was exchanged every 24 hours during the brackets were recycled with sulfuric acid (assays 95%). As the passage of time, the adhesives were removed more clearly, and after 72 hours adhesives were nearly detached from bracket base. 3. Chemical recycled metal bracket surface showed no irregular structure by S.E.M. method.

• 한국세라믹학회지
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• 제26권5호
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• pp.617-624
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• 1989

Piezoelectric composites of O-3 connectivity were prepared by thermosetting barium titanate-phenolic resin composite under various cruing pressure. Among three kinds of pore in O-3 type ceramic-polymer composite, such as matrix pores, particle pores, and ceramic-polymer interface pores, the effect of interface porosity on the dielectric and piezoelectric constant was investigated. In pure barium titanate ceramics, the porosity factor of dielectric and piezoelectric constants were 5.7 and 5.0, respectively. However, in BaTiO3-polymer composite, the interface porosity factor of the piezoelectric constant was greater than that of the dielectric constant, interface porosity factor b in d33 was 9.8 and in r 4.6. On the other, piezoelectric voltage constant g33 was independent of the porosity of barium titanate ceramics. But in composite system, the piezoelectric voltage constant g33 was decreased with interface porosity.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 추계학술대회 논문집
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• pp.1386-1391
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• 2007

The ballast gravels are often contaminated by various pollutants, like diesel fuel, lubricants, and heavy metals. Especially, the gravels near the switching are apt to be polluted by the lubricant. Because this lubricant can pollute the soil of track, the contaminated ballast gravels should be cleaned immediately. In this study, a physical desorption method was used to remove the oil contaminants from the surface of the ballast gravels. Thermosetting resin was used as a media for physical remediation of ballast gravels. The total petroleum hydrocarbon of the gravels was monitored over time. In addition, scanning electron microscopic images were obtained to observe the removal of the oily pollutants from the surface of the gravels.

• 대한기계학회논문집
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• 제19권9호
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• pp.2154-2164
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• 1995

In this study, a dielectric cure monitoring system which consists of an electric circuit, a sensor and a personal computer was developed to on-line monitor the dielectric properties of carbon fiber epoxy composite materials. Also, the kinetic model of carbon fiber epoxy composite materials was developed by curve fitting of differential scanning calorimetry data. The start and end points of cure and the relationship between the dissipation factor and the degree of cure were obtained by comparing the dissipation factor from the dielectric properties with the degree of cure from the DSC data. The relationship between the dissipation factor and the degree of cure was tested under various temperature profiles.

• Steel and Composite Structures
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• 제33권2호
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• pp.299-306
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• 2019

The natural fibre composites are termed as bio-composites. They have shown a promising replacement to the current carbon/glass fibre reinforced composites as environmental friendly materials in specific applications. Natural fibre reinforced composites are potential materials for various engineering applications in automobile, railways, building and Aerospace industry. The natural fibre selected to fabricate the composite material is plant-based fibre e.g., sisal fibre. Sisal fibre is a suitable reinforcement for use in composites on account of its low density, high specific strength, and high hardness. Epoxy is a thermosetting polymer which is used as a resin in natural fibre reinforced composites. Hand lay-up technique was used to fabricate the composites by reinforcing sisal fibres into the epoxy matrix. Composites were prepared with the unidirectional alignment of sisal fibres. Test specimens with different fibre orientations were prepared. The fabricated composites were tested for mechanical properties. Impact test, tensile test, flexural test, hardness test, compression test, and thermal test of composites had been conducted to assess its suitability in industrial applications. Scanning electron microscopy (SEM) test revealed the microstructural information of the fractured surface of composites.

• 한국철도학회논문집
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• 제12권6호
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• pp.1059-1066
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• 2009

근래에 와서 강화 플라스틱 복합재료의 생산과 함께 열경화성 수지 폐기물들의 양이 급격하게 증가하여 심각한 환경문제를 야기하고 있다. 우수한 기계적 물성을 지닌 유용한 열경화성 수지의 하나인 에폭시 수지는 열가소성 수지처럼 용융되거나 재 성형되지 않는다. 본 연구에서는 철도 차량용 탄소섬유 강화 에폭시 수지 복합재로부터 에폭시 수지를 분해하여 탄소섬유를 회수하는 일련의 실험을 수행하였다. 여러 분해공정들을 실험적으로 조사하여, 분해 효율과 회수되는 탄소섬유의 기계적 물성을 비교 검토하였다. 회수되는 탄소섬유가 서로 엉키는 것을 방지하기 위해서 각 복합재료 시편은 테플론 지지대로 고정시키고, 기계적인 교반을 가하지 않았다. 분해 생성물은 전자현미경(SEM), 기체 크로마토그라피 질량분석기(GC-MS) 및 만능재료시험기를 사용하여 분석하였다. 질산 수용액을 사용하는 분해 공정과 액상 및 기상 열분해 공정에서는 탄소섬유가 완전하게 회수되었다. 회수된 탄소섬유의 인장강도 감소율은 4% 미만으로 미미하였다.