• 공업화학
• /
• 제26권4호
• /
• pp.439-444
• /
• 2015

본 연구에서는 차선도료로 MMA (methyl metacrylate) 수지계 열경화성 수지를 선정하여 차선의 내구성능과 재귀반사성능을 개선할 수 있는 최적의 열경화성 차선도료를 설계하고자 하였다. 특히 현장 적용성을 향상시키기 위하여 차선도료의 경화시간을 8 min으로 단축하기 위해 주재의 구성요소를 설계하였다. 실험 결과 MMA 모노머($Tg=105^{\circ}C$) 15.6 wt%에 PMMA (ploymethyl metacrylate, MW = 70,000, $Tg=60^{\circ}C$) 6.0 wt%와 TMPTA (trimethylolpropane triacrylate, MW = 338, $Tg=27^{\circ}C$) 1.2 wt%를 배합한 TSRM-6가 부착강도 등 도료물성이 우수하여 최적 배합비율로 결정하였다. 열경화성 차선도료의 도장조건은 분사 전 반드시 균일한 혼합이 이루어져야 하며 최적 설계된 TSRM-6에 우천용 유리알을 사용한 경우 마모시험 횟수 20만 회에서 야간재귀반사성능계수는 $431mcd{\cdot}m^{-2}{\cdot}lux^{-1}$ (건조 조건), $354mcd{\cdot}m^{-2}{\cdot}lux^{-1}$ (젖은 조건), $172mcd{\cdot}m^{-2}{\cdot}lux^{-1}$ (비오는 조건)으로 우수한 성능을 나타내었다.

• Design & Manufacturing
• /
• 제16권3호
• /
• pp.9-15
• /
• 2022

In order to reduce the manufacturing costs of the glass lens, it is necessary to manufacture a lens using a UV curable resin or a thermosetting resin, which is a curable material, in order to replace a glass lens. In the case of forming a lens using a thermosetting material, it is necessary to form several lenses at once using the wafer-level lens manufacturing technologies due to the long curing time of the material. When a lens is manufactured using a curable material, an error in the shape of the lens due to the shrinkage of the material during the curing process is an important cause of defects. The major factors for these shape errors and deformations are the shrinkage and the change of mechanical properties in the process of changing from a liquid material during curing to a solid state after complete curing. Therefore, it is necessary to understand the curing process of the material and to examine the shrinkage rate and change of physical properties according to the degree cure. In addition, it is necessary to proceed with CAE for lens molding using these and to review problems in lens manufacturing in advance. In this study, the viscoelastic properties of the material were measured during the curing process using a rheometer. Using the results, Rheological investigation of cure kinetics was performed. At the same time, The shrinkage of the material was measured and simple mathematical models were created. And using the results, the molding process of a single lens was analyzed using Comsol, a commercial S/W. In addition, the experiment was conducted to compare and verify the CAE results. As a result, it was confirmed that the shrinkage rate of the material had a great influence on the shape precision of the final product.

• 비파괴검사학회지
• /
• 제23권5호
• /
• pp.409-417
• /
• 2003

열경화성 수지 복합재료의 제조과정에서 제품의 품질과 생산성 향상에 필수적인 경화 모니터링 기술을 개발하였다 경화도를 분석하기 위해, 동일한 경화조건에서 유전기법에 의한 소산계수 측정결과와 시차 주사 열분석 방법에 의한 발열량 계측 결과를 비교하였으며, 계측 감도의 향상을 위해 센서부분과 계측선의 영향을 적절히 분리하는 방법을 사용하였다. 유리섬유/폴리에스터 복합재료와 유리섬유/에폭시 복합재료에 대하여 경화과정에서의 경화도 분석을 위한 새로운 경화 모니터링 방법으로 소산계수와 온도를 동시에 고려하였다. 이 때, 소산계수의 변화 경향은 수지 점도의 변화 양상과 비교하여 분석하였다 개발된 경화 모니터링 방법은 다양한 종류의 열경화성 복합재료 경화 모니터링에 사용될 수 있다.

• 한국응용과학기술학회지
• /
• 제28권3호
• /
• pp.351-358
• /
• 2011

It was researched to be alternative of TGIC type hardener with human hazard element as PT 910 mix powder paint with hardener. Generally PT 910 was compared with TGIC & Epoxy resin of hardener to be used at thermosetting powder paint. We inquired a property of matter for paint through Gel time, glass transition temperature, melting point and a property of matter for film through a property of adhesion, a property of tolerance, softness, gloss, acid-resistant, alkali-resistant, salt water spray-resistant, facilitation climatic. When PT 910 is used of hardener, it was shown the excellent results in gel time, softness, salt water spray-resistant, fracilitation climatic and the similar results in melting point, a property of tolerance, a property of adhesion, gloss, acid-resistant, alkali-resistant, as compared with the powder paint used by TGIC hardener. The glass transition temperature was little low. But there was slightly different results. After the study results, we reached the conclusion that thermosetting powder used by PT 910 is alterative to by TGIC hardener.

• Carbon letters
• /
• 제14권2호
• /
• pp.76-88
• /
• 2013

Carbon fibers (CFs) have high service temperature, strength, and stiffness, and low weight. They are widely used as reinforcing materials in advanced polymer composites. The role of the polymer matrix in the composites is to provide bulk to the composite laminate and transfer load between the fibers. The interface between the CF and the resin matrix plays a critical role in controlling the overall properties of the composites. This paper aims to review the synthesis, properties, and applications of polymer matrices, such as thermosetting and thermoplastic resins.

• 융복합기술연구소 논문집
• /
• 제3권1호
• /
• pp.45-49
• /
• 2013

Spherical active carbon materials have been used for the removal of pollutants in the area of food processing, water treatment, air purification, oral administration. Moreover, they are now expected to make an epoch in the areas of electronics, life science, environmental technology, and so on due to their superior physical properties. Carbon particles should be requested for the edgeless spherical shapes in order to minimize the loss due to the abrasion during the process and/or practical use, but the carbon particles manufactured from petroleum-based pitch do not meet these needs. Nowadays, thus, the spherical active carbon particles carbonized from various spherical polymer beads are studied with thermoplastic and/or thermosetting polymers. In this paper, the synthesis of spherical phenolic beads and furan beads, which are thermosetting polymers, and their carbonization techniques are examined.

• Bulletin of the Korean Chemical Society
• /
• 제31권8호
• /
• pp.2272-2278
• /
• 2010

A new hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) is prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with Epichlorohydrin by using benzyltrimethylammonium chloride as a catalyst. The resulting compound possesses both the oxirane ring and maleimide group. The curing reaction of these maleimidophenyl glycidylether epoxy compound (N-MPGE) with amines as curing agents such as ethylendiamine (EDA), diethylentriamine (DETA) and triethylenetetramine (TETA), aminoethylpiperazine (AEP) and isophoronediamine, IPDA), are studied. Incorporation of maleimide groups in the epichlorohydrin provides cyclic imide structure and high cross-linking density to the cured resins. The cured samples exhibited good thermal stability, excellent chemical (acid/alkali/solvent) and water absorption resistance. Morphological studies by the SEM technique further confirmed the phase homogeneity net work of the cured systems.

• 연구논문집
• /
• 통권29호
• /
• pp.151-162
• /
• 1999

In general, manufacturing processes of thermosetting composites consist of mold filling and resin cure. The important parameters used in modeling and designing mold filling are the permeability of the fibrous preform and the viscosity of the resin. To consolidate a composite, resin cure or chemical reaction plays an essential role. Cure kinetics. Therefore, is necessary to quantify the extent of chemical reaction or degree of cure. It is also important to predict resin viscosity which can change due to chemical reaction during mold filling. There exists a heat transfer between the mold and the composite during mold filling and resin cure. Cure kinetics is also used to predict a temperature profile inside composite. In this study, a new scheme which can determine cure kinetics from dynamic temperature scaning was proposed. The method was applied to epoxy resin system and was verified by comparing measurements and predictions.

• 대한기계학회논문집
• /
• 제19권2호
• /
• pp.527-536
• /
• 1995

Analysis of pultrusion process for the thermosetting composites containing volatiles was performed. Degree of cure, amount of volatile evolved and pulling force were calculated for the processing variables such as die temperature and pulling speed. Cure kinetics was modeled from the data obtained by DSC(Differential Scanning Calorimeter). The volatile evolution kinetics was modeled from the data by DSC as well as TGA(Thermo Gravimetric Analyzer). The cure kinetics and volatile evolution kinetics models were incorporated into the energy equation. The resulting governing equation was solved using finite element method. Pulling force was calculated through the analysis of pressure developed inside the pultrusion die. Experiments were performed and the data were compared with the calculated results. Good agreements were observed.

• Journal of Forest and Environmental Science
• /
• 제31권4호
• /
• pp.297-302
• /
• 2015

With the intention to solve environmental problems caused by synthetic plastics from petroleum resources, biodegradable polyurethane foams and thermosetting moldings were prepared from biomass, such as wood and wheat bran by liquefaction method. Biodegradability of these biomass-based polymeric materials was investigated. In activated sludge, polyurethane foams from liquefied wheat bran and thermosetting molding from phenolated wood were decomposed approximately 14% and 29% for 20 days, respectively. One of the wood fungi, Coriolus versicolor was able to grow without supplemental nutrition, only with distilled water and polyurethane foam as a nutrition source. Risk assessments were also conducted and results showed that estrogenicity, mutagenicity, and carcinogenicity were not observed in the extractives of biomass- based polymeric materials.