• Title/Summary/Keyword: Thermoplastic composites

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A Study on Properties of the Glass Fiber Reinforced PPS Composites for Automotive Headlight Source Module (자동차 전조등 광원 모듈용 유리섬유강화 PPS 복합재료 특성 연구)

  • Heo, Kwang-Yeol;Park, Sung-Min;Lee, Eun-Soo;Kim, Myung-Soon;Sim, Ji-Hyun;Bae, Jin-Seok
    • Composites Research
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    • v.29 no.5
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    • pp.293-298
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    • 2016
  • In this paper, Glass Fiber Reinforced Thermoplastic (GFRTP) for automotive headlight source module was fabricated by compounding and injection molding using PPS (Poly Phenylene Sulfide) resin with glass fiber which has three cross section (round type, cocoon type, flat type). Tensile, flexural, impact properties were investigated on effect of cross section, glass fiber contents. And it was observed flatness, dimensional stability, fluidity depending on glass fiber cross section. As a result, flat glass fiber reinforced thermoplastic's mechanical properties were most excellent. Also, dimensional stability and flatness showed better results when using flat glass fiber.

A Study on Crystallization of Thermoplastic Aromatic Polymer (열가소성 방향족 폴리머의 결정화 특성에 대한 연구)

  • Park, Dong-Cheol;Park, Chang-Wook;Shin, Do-Hoon;Kim, Yun-Hae
    • Composites Research
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    • v.31 no.2
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    • pp.63-68
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    • 2018
  • Thermoplastic composite has been limitedly used in high performance aerospace industry due to relatively low mechanical properties even though it has various advantages. But, thermoplastic aromatic polymer composite has recently been researched and utilized much. In this study, PEEK and PPS neat resin film as representative thermoplastic aromatic polymer were processed through continuous heating, cooling and reheating cycle. Property change such as glass transition temperature and melting temperature were identified and crystallinity variation by different cooling rate were evaluated. In the first (heating) run, polymer specimens were kept for 5 minutes at higher temperature than melting point to remove previous thermal history, and crystallization reaction was controlled by adjusting cooling rate to 2, 5, 10, 20 and $40^{\circ}C/minute$ in the second (cooling) run. In the third (heating) run, specimen crystallinity were verified by measuring the melting enthalpy. The initial specimens containing high portion of amorphous structure exhibited cold crystallization and clear glass transition in the first run whereas they did not show in the third run due to the increase of crystalline structure portion. As cooling rate decreases through the second cooling run, the crystallinity of the specimen increased. PEEK polymer had 21.9~39.3% crystallinity depending on cooling rate change whereas PPS polymer showed 29.1~31.2%.

Evaluation of Stamp Forming Process Parameters for CF/PEKK Thermoplastic Composite Using Finite Element Method (고속 열 성형 유한요소해석을 활용한 CF/PEKK 열가소성 복합재 구조물 제작 공정 예측 및 검증)

  • Lee, Keung-In;Choe, Hyeon-Seok;Kwak, June-Woo;Lee, Jun-Sung;Ju, Hyun-Woo;Kweon, Jin-Hwe;Nam, Young-Woo
    • Composites Research
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    • v.34 no.5
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    • pp.296-304
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    • 2021
  • This study presented the evaluation of the stamp forming process for L-shape CF/PEKK thermoplastic composite using the finite element model. The formability of three different trimming allowances has been examined for representative product geometry. The results showed that those manufactured by high trimming allowance showed more excellent formability in those areas. Moreover, the effects of the trimming allowances on the stress, thickness, wrinkle distributions of thermoplastic composites fabricated with the stamp forming process were evaluated. The comparison of the simulation and experimental results for the thickness and wrinkle distributions proved the accuracy of the stamp forming model. The crystallinity of the composite was performed by differential scanning calorimetry (DSC). The void content of the composite was evaluated by matrix digestion. Then, the fabricated structure was characterized and achieved high quality in crystallinity and void content. Consequently, the presented FEM modeling shows excellent potential for application in the aircraft product design process. This pragmatic approach could efficiently offer a valuable solution for the thermoplastic composite manufacturing field.

A Study on the Compression Moldablity for Continuous Fiber-Reinforced Polymeric Composites ―Part 1 : The Mechanical Propertis and the Cup-type Compression Moldability for Numbers of Needling― (연속섬유강화 플라스틱 복합재료의 압축성형에 관한 연구 -제I보 : 니들펀칭횟수에 따른 물성치 및 컵형 압축성형성-)

  • 오영준;김형철;김이곤
    • Composites Research
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    • v.12 no.5
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    • pp.31-39
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    • 1999
  • Glass-fiber reinforced polymeric composites provide the desitable properties of high stiffness and strength as well as specific weight. Hence, they have become some of the most important materials in several industries. These composites can be grouped into thermoplastic and thermoset composites, with thermoplastic composites having several advantages over thermoset composites in mechanical properties and processing. As a result, the study of the material behavior and forming techniques of such composites has attracted considerable attention in recent years. When the continuous fiber-reinforced polymeric composites are molded by flow molding, the molded parts leads to be nonhomogeneity and anisotropic because of the separation and orientation of fibers. As the characteristics of the products are greatly dependent on the separation, it is very important to clarify the separation in relarion to molding conditions, fiber mat structures and mold geometry. In this study, the effects of the mold geometry and the fiber mat structure on the compression moldability are studied using the cup-type molding.

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Effects of Fiber Surface-Treatment and Sizing on the Dynamic Mechanical and Interfacial Properties of Carbon/Nylon 6 Composites

  • Cho, Dong-Hwan;Yun, Suk-Hyang;Kim, Jun-Kyung;Lim, Soon-Ho;Park, Min;Lee, Geon-Woong;Lee, Sang-Soo
    • Carbon letters
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    • v.5 no.1
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    • pp.1-5
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    • 2004
  • The effects of fiber surface-treatment and sizing on the dynamic mechanical properties of unidirectional and 2-directional carbon fiber/nylon 6 composites by means of dynamic mechanical analysis have been investigated in the present study. The interlaminar shear strengths of 2-directional carbon/nylon 6 composites sized with various thermosetting and thermoplastic resins are also measured using a short-beam shear test method. The result suggests that different surface-treatment levels onto carbon fibers may influence the storage modulus and tan ${\delta}$ behavior of carbon/nylon 6 composites, reflecting somewhat change of the stiffness and the interfacial adhesion of the composites. Dynamic mechanical analysis and short-beam shear test results indicate that appropriate use of a sizing material upon carbon fiber composite processing may contribute to enhancing the interfacial and/or interlaminar properties of woven carbon fabric/nylon 6 composites, depending on their resin characteristics and processing temperature.

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The Change of Mechanical Properties with Forming Conditions of Thermoplastic Composite in Compression Molding (열가소성 복합재료의 압축성형조건에 따른 기계적 특성 변화)

  • Lee, Jung-Hui;Lee, Ho-Eon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.9
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    • pp.1416-1422
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    • 2001
  • The objective of this work was to characterize mechanical properties of thermoplastic composites with various forming conditions in compression molding. Randomly oriented long glass fiber reinforced polypropylene(PP) was used in this work. The composite materials contained 20%, 30%, and 40% glass fiber by weight. Compression molding was conducted at various mold temperatures and charge sizes. The temperatures on the mold surface and at the material in the mid-plain were monitored during the molding. Differential Scanning Calorimeter was used to measure crystallinity at both in-side and out-side of the sheet material. Crystallinity at each temperature was also measured by X-ray diffractometer. Dimensional stability was studied at various conditions with the spring forward angle. Among the processing parameters, the crystallization time at the temperature above 130$^{\circ}C$, was found to be the most effective. Spring-forward angle was reduced and the tensile modulus was increased as the mold temperature increased.

Morphology of EPDM-based Thermoplastic Vulcanizates (EPDM계 열가소성 가황체의 형태학적 연구)

  • Lee, Sang-Jin;Kim, Young-Kyoo;Park, Seong-Soo;Cho, Won-Jei;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.32 no.3
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    • pp.157-165
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    • 1997
  • The morphology of the thermoplastic vulcanizates prepared from ethylene-propylene-diene terpolymer, polypropylene and high density polyethylene(HDPE) or ethylene based ionomer were studied. Blends were prepared in a laboratory internal mixer where EPDM was cured in the presence of PP and HDPE or ionomer under shear with dicumyl peroxide(DCP). The effects of DCP concentration and rubber/plastics composition were studied. In the morphological analysis by scanning electron microscopy (SEM), a small amount of EPDM acted as a compatibilizer to HDPE and PP. It was also revealed that the dynamic vulcanization process could reduce the domain size of the crosslinked EPDM phase. When ionomer was added to EPDM/PP blend, the thermoplastic vulcanizate showed typical ductile fracture topology and the trend was more clearly observed when DCP contents and ionomer contents are higher.

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Studies on Slip and Mechanical Properties of Thermoplastic Polyurethane Elastomer Containing Sulfuric Acid (Sulfuric acid를 도입한 열가소성 폴리우레탄 탄성체의 슬립특성 및 기계적 물성에 관한 연구)

  • Mok, Dong Youb;Shin, Hyun Deung;Kim, Dong Ho;Kim, Gu Ni;Kim, In-Soo
    • Elastomers and Composites
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    • v.48 no.4
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    • pp.256-262
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    • 2013
  • We synthesized thermoplastic polyurethane elastomer (TPU) with different contents of sulfuric acid group, and characterized their physical properties such as mechanical, thermal and grip properties. And the results were compared with carboxylic acid-introduced TPU. Wet slip, tensile strength and abrasion properties were increased by the introduction of acid group. Mechanical properties increased with increasing the acid content up to 0.3 wt%. However, wet slip was continually increased as the acid content increased due to increase of hydrophilicity of TPU.

A Study on Manufacturing of the Long Fiber-reinforced Thermoplastic (LFT) Automotive Under Cover Using the In-line Compounding (ILC) Technology (인라인 컴파운딩 기술을 이용한 장섬유강화 플라스틱 자동차 언더커버의 제조에 관한 연구)

  • Lee, Kyu-Se;Lee, Kyung-Sick
    • Composites Research
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    • v.30 no.6
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    • pp.399-405
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    • 2017
  • We manufactured the long fiber-reinforced thermoplastic prototype of under cover using in-line compounding technology, and investigated the formability, mechanical properties and durability of the prototype of under cover. We manufactured the injection mold for the prototype through injection molding analysis and consideration of weight reduction. We investigated the formability of the prototype by evaluating the residual length and dispersion of fiber, and also tested the mechanical properties such as flexural strength, stiffness and impact strength. We investigated the durability of the prototype by the Key-Life Test(KLT) method which is generally used for the automotive interior parts.

Studies on Slip and Mechanical Properties of Thermoplastic Polyurethane Elastomer with Carboxylic acid and Nano zinc oxide (Carboxylic acid와 nano zinc oxide를 도입한 열가소성 폴리우레탄 탄성체의 슬립특성 및 기계적 물성에 관한 연구)

  • Shin, Hyun Deung;Kim, Dong Ho;Kim, Gu Ni
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.191-198
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    • 2014
  • We synthesized thermoplastic polyurethane elastomer(TPU) with acid group and nano zinc oxide, and characterized their mechanical properties, thermal properties, contact angle and grip property. The effects of the zinc oxide content and size on the physical property of TPU were investigated. When the nano zinc oxide was introduced in TPU with acid group, it had excellent mechanical properties and grip by formation of hydrogen and ionic bonding. The wet slip of TPU with zinc oxide was increased continuously as ionization rate increased due to increase of hydrophilicity and ionic interaction, and mechanical properties were increased with increasing ionization rate up to 50%.