• Title/Summary/Keyword: Thermoplastic Composites

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Impact of nanocomposite material to counter injury in physical sport in the tennis racket

  • Hao Jin;Bo Zhang;Xiaojing Duan
    • Advances in nano research
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    • v.14 no.5
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    • pp.435-442
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    • 2023
  • Sports activities, including playing tennis, are popular with many people. As this industry has become more professionalized, investors and those involved in sports are sure to pay attention to any tool that improves athletes' performance Tennis requires perfect coordination between hands, eyes, and the whole body. Consequently, to perform long-term sports, athletes must have enough muscle strength, flexibility, and endurance. Tennis rackets with new frames were manufactured because tennis players' performance depends on their rackets. These rackets are distinguished by their lighter weight. Composite rackets are available in many types, most of which are made from the latest composite materials. During physical exercise with a tennis racket, nanocomposite materials have a significant effect on reducing injuries. Materials as strong as graphite and thermoplastic can be used to produce these composites that include both fiber and filament. Polyamide is a thermoplastic typically used in composites as a matrix. In today's manufacturing process, materials are made more flexible, structurally more vital, and lighter. This paper discusses the production, testing, and structural analysis of a new polyamide/Multi-walled carbon nanotube nanocomposite. This polyamide can be a suitable substitute for other composite materials in the tennis racket frame. By compression polymerization, polyamide was synthesized. The functionalization of Multi-walled carbon nanotube (MWCNT) was achieved using sulfuric acid and nitric acid, followed by ultrasonic preparation of nanocomposite materials with weight percentages of 5, 10, and 15. Fourier transform infrared (FTIR) and Nuclear magnetic resonance (NMR) confirmed a synthesized nanocomposite structure. Nanocomposites were tested for thermal resistance using the simultaneous thermal analysis (DTA-TG) method. scanning electron microscopy (SEM) analysis was used to determine pores' size, structure, and surface area. An X-ray diffraction analysis (XRD) analysis was used to determine their amorphous nature.

Preparation and Dielectric Properties of Ceramic(BNT)-Polymer(LCP) Composite (세라믹(BNT)-폴리머(LCP) 복합체 제조 및 유전특성)

  • Park, Myoung-Sung;Chun, Myoung-Pyo;Cho, Jung-Ho;Nam, Joong-Hee;Choi, Byung-Hyun;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.11
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    • pp.935-940
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    • 2009
  • In this research, the composites (100-x)LCP-xBNT (x = 0, 10, 20, 30, 40 vol.%) were fabricated with thermoplastic LCP(Liquid Crystal Polymer) and BNT($BaNd_2Ti_4O_{12}$) which is a high frequency dielectric material. Their dielectric properties, mechanical strength and microstructure were investigated by Impedance analyser, Instron and SEM. In order to fabricate LCP-BNT composites, LCP resin was put into the twin screw type mixer($310^{\circ}C$), melted by keeping for 10 min. After that, BNT filler was dispersed with melted LCP resin for 15 min. in the mixer. For measuring the dielectric properties and mechanical strength, Composite specimens were made by pressing composite granule (LCP-BNT) with 7 ton in the mold at $310^{\circ}C$. With increasing the BNT content (0~40 vol.%) of the composite, Its dielectric constant increased, dielectric loss and flexural strength decreased. The dielectric constant and flexural strength of composites with 20~30 vol.% of BNT filler are 4.1~6.0 and 35~55 MPa respectively. BNT/LCP composite is the potential substrate material for the high frequency application.

Polybenzimidazole (PBI) Coated CFRP Composite as a Front Bumper Shield for Hypervelocity Impact Resistance in Low Earth Orbit (LEO) Environment

  • Kumar, Sarath Kumar Sathish;Ankem, Venkat Akhil;Kim, YunHo;Choi, Chunghyeon;Kim, Chun-Gon
    • Composites Research
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    • v.31 no.3
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    • pp.83-87
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    • 2018
  • An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

Preparation and Sound Insulation Properties of Thermoplastic Elastomer Composites with CaCO3 Filler (탄산칼슘 분말을 충진시킨 열가소성 탄성체 복합재의 제조 및 차음 특성)

  • Choi, Jung-Woo;Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.467-471
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    • 2010
  • Composites of ceramic powders and an elastomer-based matrix were prepared by mixing $CaCO_3$ powders with polyethylene and polypropylene elastomers, and their mechanical and sound insulation properties were measured. $CaCO_3$ powders with 0.7 ${\mu}m$ and 35 ${\mu}m$ particle size were added to elastomers up to 80 wt%. Scanning electron microscopy photographs showed uniform distribution of the $CaCO_3$ powders in the matrix. While density and surface hardness increased, melt index, tensile strength and elongation of the composites decreased as the amount of added $CaCO_3$ powders increased. As more $CaCO_3$ powders were added sound transmission loss of the composites increased owing to the increase of density. Addition of 0.7 ${\mu}m$ sized $CaCO_3$ powders resulted in a slightly higher transmission loss than the addition of 35 ${\mu}m$ sized powders because of the increased interface area between the elastomer matrix and the $CaCO_3$ powders. Composites with a polyethylene matrix showed higher transmission loss than those with a polypropylene matrix because the tensile strength and hardness of the polyethylene-based composites were low and their elongation was high.

Fracture Toughness of the Thermoplastic Vulcanizates from EPDM/PP/Ionomer Ternary Blends (EPDM/PP/Ionomer 삼원 블렌드로 된 열가소성 가황체의 파괴 인성)

  • Kim, K.;Cho, W.J.;Ha, C.S.;Go, J.H.
    • Elastomers and Composites
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    • v.31 no.5
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    • pp.341-346
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    • 1996
  • The fracture mechanics investigation of the thermoplastic vulcanizates(TPV) from EPDM and PP/Ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. The TPV from ternary blends consisting of EPDM, PP and ionomer were prepared in a laboratory integral mixer by blending and vulcanizing simultaneously. Vulcanization was performed with dicumyl peroxide (DCP) and the composition of EPDM and PP was fixed at 50/50 by weight. Two kinds of poly(ethylene-co-methacrylic acid) (EMA) lonomers were used. The J-integral values at crack initiation, Jc, of the dynamically vulcanized EPDM and PP/EMA Ionomer ternary blends were affected by the cation types $(Na^+\;or\;Zn^{2+})$ and contents(5-20wt%) of the added EMA Ionomers. The ternary blend containing 20wt% zinc-neutralized EMA Ionomer and 1.0phr DCP showed the highest Jc values of the blends.

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Thermoplastic Polyurethane (TPU)/Ethylene-Propylene-Diene Monomer Rubber (EPDM) and TPU/Polybutadiene Rubber (BR) Blends for the Application of Footwear Outsole Materials (신발겉창 재료용 열가소성 폴리우레탄 (TPU)/에틸렌-프로필렌-디엔 고무와 TPU/부타디엔 고무 블렌드)

  • Kim, Ji-Hoo;Kim, Gue-Hyun
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.195-200
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    • 2013
  • The main objective of this study is to improve abrasion resistance and wet slip resistance of thermoplastic polyurethane (TPU) by blending with ethylene-propylene-diene monomer rubber (EPDM) or polybutadiene rubber (BR) for the application of the footwear outsole materials. With addition of 10 wt% of EPDM or BR, TPU/EPDM and TPU/BR blends exhibited higher NBS abrasion resistance, tensile properties and wet slip resistance than TPU. However, with further increasing content of EPDM and BR, abrasion resistance and tensile properties of the blends decreased. Improvement in abrasion resistance and tensile properties with 10 wt% of addition of EPDM or BR may be due to better microphase separation of TPU.

Development and Properties of Rubber Sheet using Thermoplastic Elastomer (열가소성 고무를 사용한 RUBBER SHEET의 제조 및 물성)

  • Chun, Seung-Han;Han, Min-Hyeon;Mun, Il-Sik
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.122-127
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    • 2003
  • Compounding, using such thermoplastic elastomer as styrene-ethylene-butadiene-styrene (SEBS) blended with polypropylene(PP), oil, and other ingredients, was studied to develop a new material with excellent impact resistance and resilience for the replacement of environmentally toxic PVC sheet. Hardness decreased linearly with oil content in the SEBS/oil blend, and the tensile strength increased with PP content whereas elongation showed no effects over 50 phr of PP in SEBS/oil/PP blend. In the practical SEBS composition, proposed to replace the PVC sheet material, tensile and tear strength, as well as hardness, increased proportionally with PP content, while melt index decreased.

Compression Molding Analysis of LFT-D System for Vehicle Trailing Arm (트레일링 암 생산용 LFT-D 시스템에서의 압축성형 해석)

  • Park, Bo-Gyu;Jung, Jin Woo;Jung, Han-Kyu;Park, Si-Woo;Ha, Dong Soo;Choi, Hyen Yel
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.6
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    • pp.133-138
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    • 2017
  • Recently, CFRP composites are widely used as lightweight materials have with excellent mechanical properties and can beare widely used in various fields. In general, thermosetting resins are used for CFRP. However, in recent years, studies have been carried out using thermoplastic resins have been actively carried out to overcome the disadvantages of thermosetting resins. The LFT-D system is a molding method in which a fiber is directly cut to a the desired length while being impregnated with a thermoplastic resin to produce a compound and that is then press-molding molded to form the product. In this paper, before the production of the trailing arm, the compression molding analysis was carried out in order to grasp the problems that may occur during production. Through cCompression molding analysis was applied to calculate of the minimum press pressure and to compare and analysis analyze the molding conditions characteristic required to formfor forming the trailing arm.

A Study on Thermoplastic Elastomer Blend Using Waste Rubber Powder(I): Screw Configurations, Morphologies and Mechanical Properties (폐고무 분말을 이용한 TPE 블렌드에 관한 연구(I) : 스크류 조합, 모폴로지, 기계적 물성)

  • Lee, Sung-Hyo;Hwang, Sung-Hyuk;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.86-93
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    • 2001
  • For solving the environmental problem of the waste EPDM and for new TPE blend materials, we developed a new kind of TPE material using a co-rotating twin screw extruder. To improve the mechanical properties of TPE material such as tensile strength, elongation at break, and modulus of the blend, PP and waste EPDM powder were blended with different screw configurations. The mechanical properties of the blends and morphology of the TPE were investigated. As the number of kneading disc and left-handed screw element increased, dynamic vulcanization of the material was increased because the shear stress and residence time of blends increased.

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Computer Simulation of Deformation in a Rubber Boots for Translation and Rotation of CV-joint for Automobile

  • Lee, Min-A;Lyu, Min-Young
    • Elastomers and Composites
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    • v.55 no.2
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    • pp.88-94
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    • 2020
  • Automobile industry, along with the automobile steering system, is rapidly changing and developing. The constant velocity joint transmits power to the wheels of vehicles without changing their angular velocity based on the movement of the steering wheel. Moreover, it controls their movement to act as a buffer. In order to prevent the excessive increase in temperature caused by the movement of vehicles, boots are attached to the constant velocity joint and lubricant is injected into the boots. The boots maintain the lubrication and protect the constant velocity joint from sand, water, and so on. As the wheels of the vehicle rotate, the boots are acted upon by forces such as bending, compression, and tension. Additionally, self-contact occurs to boots. Therefore, their durability deteriorates over time. To prevent this problem, polychloroprene rubber was initially used however, it was replaced by thermoplastic polyester elastomers due to their excellent fatigue durability. In this study, the structural analysis of boots was conducted. The results showed the deformation patterns of the boots based on the translation and rotation of the constant velocity joint. Moreover, it confirmed the location that was vulnerable to deformation. This study can be used to potentially design high-quality constant velocity joint boots.