• 한국환경과학회지
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• 제27권3호
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• pp.167-177
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• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.112-117
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• 2000

A numerical study on natural convection in a vertical square cavity filled with a porous medium is carried out with Brinkman-Forchheimer-extended Darcy flow model, and the validity of local thermodynamic equilibrium assumption is studied. The local thermodynamic equilibrium refers to the state in which a single temperature can be used to describe a heat transfer process in a multiphase system. With this assumption, the analysis is greatly simplified because only one equation is needed to describe the heat transfer process. But prior to using this assumption, it is necessary to know in what conditions the assumption can be used. The numerical results of this study reveal that large temperature difference between fluid phase and solid phase exists near wall region, paticularily when the convection becomes dominant over conduction. And the influence of flow parameters such as fluid Rayleigh number, fluid Prandtl number, dimensionless particle diameter and conductivity ratio are investigated.

• 대한금속재료학회지
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• 제50권2호
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• pp.116-121
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• 2012

Equilibria between Mn-Si melts and $MnO-SiO_2$ slags were studied at 1673 K and 1773 K in MnO crucibles to accurately determine the thermodynamic property of the Mn-Si melts. The Unified Interaction Parameter Formalism (UIPF) was used to describe the thermodynamic property of the Mn-Si liquid. Using the UIPF, the experimental results obtained in the present study were thermodynamically analyzed to determine the activity coefficient of Si at infinite dilution and the 1st- and 2nd-order self-interaction parameters of Si in the Mn-Si melts.

• Structural Engineering and Mechanics
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• 제33권4호
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• pp.391-406
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• 2009

Viscoelastic materials store as well as dissipate energy to the thermal domain under deformation. Two efficient modelling techniques reported in literature use coupled (thermo-mechanical) ATF (Augmenting Thermodynamic Fields) displacements and ADF (Anelastic Displacement Fields) displacements, to represent the constitutive relationship in time domain by using certain viscoelastic parameters. Viscoelastic parameters are first extracted from the storage modulus and loss factor normally reported in hand books with the help of Genetic Algorithm and then constitutive relationships are used to obtain the equations of motion of the continuum after discretizing it with finite beam elements. The equations of motion are solved to get the frequency response function and modal damping ratio. The process may be applied to study the dynamic behaviour of composite beams and rotors comprising of several viscoelastic layers. Dynamic behaviour of a composite beam, formed by concentric layers of steel and aluminium is studied as an example.

• Journal of Microbiology and Biotechnology
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• 제20권7호
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• pp.1077-1085
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• 2010

With an emphasis on its thermal behavior with different pHs and salts, the kinetic and thermodynamic parameters of the purified polygalacturonase (PG) from E. carotovora subsp. carotovora (Ecc) BR1 were studied, as the characterization of an enzyme is significant in the context of burgeoning biotechnological applications. The thermodynamic parameters for polygalacturonic acid hydrolysis by the purified PG were ${\Delta}H^*$=7.98 kJ/mol, ${\Delta}G^*$=68.86 kJ/mol, ${\Delta}S^*$=-194.48 J/mol/K, ${\Delta}G_{E-S}$=-1.04 kJ/mol, and ${\Delta}G_{E-T}$=-8.96 kJ/mol. In addition, its turnover number ($k_{cat}$) was 21/sec. The purified PG was stable within a temperature range of $20-50^{\circ}C$ and was deactivated at $60^{\circ}C$ and $70^{\circ}C$. The thermodynamic parameters (${\Delta}H^*$, ${\Delta}G^*$, ${\Delta}S^*$) for the irreversible inactivation of the PG at different temperatures ($30-60^{\circ}C$) were determined, where the effectiveness of various salts and different pHs (4-8) for the thermal stability of the PG were also characterized. The efficacy of various salts for the thermal stability of the PG was in the following order: $MgCl_2$ > $BaCl_2$ > KCl > $CaCl_2$ >NaCl. Therefore, the present work presents the biochemical, substrate hydrolysis thermodynamics and the thermal stabilization parameters of the PG from Ecc.

• 한국응용과학기술학회지
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• 제36권4호
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• pp.1050-1059
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• 2019

비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 폴리아미드 섬유고분자 물질의 자체확산, 홀 부피, 유동 열역학 파라메타 등을 계산하였다. 폴리아미드 섬유의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기, 증류수, 산, 염기 용액에서 실행하였다. REM 모델의 이론적인 응력완화 식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 이들 시료의 유동 파라메타는 완화 스펙트럼, 자체확산, 점도 및 유동 활성화 에너지와 직접적인 연관을 갖는 것으로 규명되었다.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.398-401
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• 1996

• Bulletin of the Korean Chemical Society
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• 제21권2호
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• pp.245-250
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• 2000

• Elastomers and Composites
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• 제46권3호
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• pp.245-250
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• 2011

Poly(acrylonitrile)-poly(vinyl chloride) 공중합체 섬유의 비결정성 영역에서의 자체 확산 계수와 홀 부피를 응력완화 실험으로 규명하였다. 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하였다. 이론적인 응력완화식 에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 유동 파라메타로부터 섬유고분자 물질의 홀부피, 자체확산, 점성, 열역학파라메타 등을 계산하였다. 이들 시료의 유동 파라메타는 유동 단위의 홀 부피, 자체확 산, 유동 활성화 에너지와 직접적인 연관을 갖는 것으로 규명되었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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• pp.252-255
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• 2005

가스터빈 엔진은 작동시간이 축적됨에 따라 엔진 주요부품의 성능이 점차적으로 저하되며, 내부구성부품 사이에 결함이 발생하기도 한다. 이러한 엔진의 손상여부를 진단하기 위해 가스경로해석(GPA, Gas Path Analysis)이 사용되고 있다. 본 연구에서는 상용 프로그램에 의존하지 않고, 각 성능변수들과 측정 변수들과의 열역학적 민감도를 이용하여 엔진성능진단 코드를 개발하였으며, 스마트무인기용 터보축 엔진에 적용하여 엔진의 단일 성능 저하를 예측하여 보았다.