• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.41 no.11
• /
• pp.874-882
• /
• 2013

Kerosene(Jet A-1), one of the propellants for each stage's engine of the Korea Space Launch Vehicle-II(KSLV-II), functions as coolant at the same time as it flows inside the cooling jacket of the combustion chambers and is injected through the film cooling holes. A physical surrogate mixture model to reproduce the thermophysical characteristics of Jet A-1 has been selected and the thermodynamic/transport properties of the model fuel under high pressure including supercritical conditions have been estimated using SUPERTRAPP(NIST SRD4). Comparisons with the measured properties suggest that proposed database can be used to extract properties of Jet A-1 for conjugate heat transfer analysis of liquid propellant rocket engine thrust chambers. Predicted combustion/cooling performance of regeneratively cooled thrust chambers shall be validated through comparisons with upcoming firing test results.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.10
• /
• pp.56-60
• /
• 2006

It is essential to predict thermodynamic properties of combustion gas with respect to a propellant mixture ratio for the development of a gas generator for a liquid rocket engine. The present study shows the temperature measurement of exit combustion gas as a function of a mixture ratio through the series of combustion tests of a fuel-rich gas generator with liquid oxygen and Jet A-1. The measurements of dynamic and static pressures, and combustion gas temperatures allowed the estimation of thermodynamic properties like a specific heat ratio, a gas constant, and a constant pressure specific heat of the combustion gas. The comparison of the experimental results with predictions made by interpolation parameters obtained from the modification of the chemical equilibrium code indicates that the interpolation method calibrated using the temperature measurements can be utilized as an effective tool for the initial design of a fuel-rich gas generator.

• Journal of Korean Society on Water Environment
• /
• v.25 no.3
• /
• pp.459-463
• /
• 2009

The adsorption features of malachite green onto activated carbon have been investigated for its treatment from aqueous solution. The influential factors were examined the initial concentration of malachite green, reaction temperature, and pH. Under experimental conditions, adsorption equilibrium of malachite green was attained within 2 hr after the adsorption started. The adsorption reaction of malachite green followed the pseudo-second order rate model, and the adsorption rate constants(k2) decreased with increasing initial concentrations of malachite green. Adsorption behavior of malachite green on activated carbon was found to follow the Freundlich model well in the initial adsorbate concentration range. With increase in temperature, the adsorbed amount of malachite green at equilibrium increased, which indicate that the adsorption reaction was endothermic reaction. Thermodynamic parameters for malachite green adsorption reaction were estimated at varying temperatures, and in the pH range of 2-10, adsorption of malachite green increased.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.2
• /
• pp.184-193
• /
• 2020

One of the technical methods to increase the volumetric energy density of hydrogen is to pressurize the gaseous hydrogen and then contain it in a rigid vessel. Especially for automotive systems, the compressed hydrogen storage can be found in cars as well as at refueling stations. During the charging the pressurized hydrogen into a vessel, the temperature increases with the amount of stored hydrogen in the vessel. The temperature of the vessel should be controlled to be less than a limitation for ensure stability of material. Therefore, the accurate estimation of temperature is of significance for safely storing the hydrogen. In this work, three well-known cubic equations of state (EOSs) were adopted to examine the accuracy in regenerating thermodynamic properties of hydrogen within the temperature and pressure ranges for the compressed hydrogen storage. The formulations representing molar volume, internal energy, enthalpy, and entropy were derived for Redlich-Kwong (RK), Soave-Redlioch-Kwong (SRK), and Peng-Robinson (PR) EOSs. The calculated results using the EOSs were compared with literature data given by NIST. It was revealed that the accuracies of RK and SRK EOSs were satisfactorily compatible and better than the results by PR EOS.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.49 no.4
• /
• pp.311-320
• /
• 2021

A study is performed for the real time fault diagnosis during operation and health estimation relating to performance deterioration in a turbojet engine used for an unmanned air vehicle. For this study the real time dynamic model is derived from the transient thermodynamic gas path analysis. For real fault conditions which are manipulated for the simulation, the detection techniques are applied such as Kalman filter and probabilistic decision-making approach based on statistical hypothesis test. Thereby the effectiveness is verified by showing good fault detection and isolation performances. For the health estimation with measurement parameters, it shows using an assumed performance degradation that the method by adaptive Kalman filter is feasible in practice for a condition based diagnosis and maintenance.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.57 no.1
• /
• pp.79-87
• /
• 2015

A thermochemical equilibrium model was constructed for predicting composition of synthesis gas in biomass gasification. The model included estimation of equilibrium constants using Gibbs free energy. After constructing the model, the results were compared with the experimental values and predictions from a previous model. Gas compositions were reasonably well agreed with them and showed effects of operational and fuel condition. When the reaction temperature increased, the lower heating values decreased due to the decrease in CH4 concentrations. The methane concentrations were lower than those observed in experimental results. The model was used to predict the gas composition and heating values for the cases of mixed fuel of charcoal and un-dry woodchips. Although downdraft gasifiers require fuels less than 15% of moisture contents, the model results indicated that the mixed fuel with charcoal and woodchips which had over 25% of moisture contents could be used in the downdraft gasifiers. It might be explained by increase in energy density resulting from mixing charcoal. The results imply that the efforts and costs for drying biomass fuels could be reduced by mixing charcoal or fuels with higher calorific values.

• Journal of the Korean Society of Safety
• /
• v.7 no.3
• /
• pp.53-59
• /
• 1992

A general theory is developed which enables closed-cup flash points of mixtures of flammable and non-flammable liquid to be estimated from a knowledge of a certain properties of flammability diagram by thermodynamic method. The estimated equations is shown the effect of both the flame inhibiting properties of the vapor of the non-flammable component and the relative volatility of that component. The vapor phase flame inhibition effect results in a even greater elevation of flash points than the rotative volatility of that component. Especially in cases of similar vapor phase flame inhibition of the non-flammable component, the rotative volatility is affected greater elevation of flash points(extinguishing effect).

• Bulletin of the Korean Chemical Society
• /
• v.22 no.9
• /
• pp.1009-1014
• /
• 2001

In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $\beta$ of the regular solution model was estimated to be -5 and this negative value of $\beta$ indicated an overall attractive force in the mixed state.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.11 no.1
• /
• pp.97-104
• /
• 1987

An analysis on the thermodynamic optimum use of thermal water has been accomplished. The systems investigated are power generation and space heating. The space heating systems considered in this study are direct heating, heat pumps and heat pump assisted heating. The object of this study is to find the optimum selection and operation of the system under the given resources. The measure of such optimum conditions is the EFFECTIVENESS, the concept of efficiency based upon the Second Law of Thermodynamics. The temperature of water to waste is identified as the most important parameter to be optimized. The analysis indicates that for high temperature resources (higher than about 425K) power generation yields the best performance and is therefore recommended. The heat pumps are recommended for the resource temperature less than about 327K. The heat pump assisted heating system shows its superiority for the very narrow temperature range (320K-330K) and thus the use of this system should be considered when the flow rate is very limited. thus the direct heating is appropriate for the temperature range of 330K-425K. The analysis also shows the optimum capacity of thermal water, which may be useful for the initial estimation of heating or power generation potentials of given resources.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.05a
• /
• pp.118-122
• /
• 2006

For the development of a gas generator of a liquid rocket engine, the prediction of thermodynamic properties of combustion gas with respect to a propellant mixture ratio becomes critical. The present study focuses on the temperature measurement of exit combustion gas as a function of a mixture ratio through combustion tests of a fuel-rich gas generator propelled by Lox/Jet A-1. The measurement of combustion dynamic and static pressures allowed indirect estimation of thermodynamic properties like specific heat ratio, gas constant, and constant pressure specific heat. Comparing the results with empirical prediction through an interpolation reveals that the interpolation method calibrated using temperature results can be utilized as an effective tool for the design of a fuel-rich gas generator.