• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.243-247
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• 2009

This study is purposed to analyze thermodynamic properties on the hydrogen production by ethylene glycol steam reforming. Various reaction conditions of temperatures(300~1,600 K), feed compositions(steam/carbon= 0.5~4.5), and pressures(1~30 atm) were applied to investigate the effects of the reaction conditions on the thermodynamic properties of dimethyl ether steam reforming. An endothermic steam reforming competed with an exothermic water gas shift reaction and an exothermic methanation within the applied reaction condition. Hydrogen production was initiated at the temperature of 400 K and the production rate was promoted at temperatures exceeding 500 K. An increase of steam to carbon ratio(S/C) in feed mixture over 1.0 resulted in the increase of the water gas shift reaction, which lowered the formation of carbon monoxide. The maximum hydrogen yield with minimizing loss of thermodynamic conversion efficiency was achieved at the reaction conditions of a temperature of 900 K and a steam to carbon ratio of 3.0.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.101.1-101.1
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• 2005

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.363-371
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• 2008

As a computational method for the discovery of the effective agonists for PPARd, we address the usefulness of molecular dynamics free energy (MDFE) simulation with explicit solvent in terms of the accuracy and the computing cost. For this purpose, we establish an efficient computational protocol of thermodynamic integration (TI) that is superior to free energy perturbation (FEP) method in parallel computing environment. Using this protocol, the relative binding affinities of GW501516 and its derivatives for PPARd are calculated. The accuracy of our protocol was evaluated in two steps. First, we devise a thermodynamic cycle to calculate the absolute and relative hydration free energies of test molecules. This allows a self-consistent check for the accuracy of the calculation protocol. Second, the calculated relative binding affinities of the selected ligands are compared with experimental IC50 values. The average deviation of the calculated binding free energies from the experimental results amounts at the most to 1 kcal/mol. The computational efficiency of current protocol is also assessed by comparing its execution times with those of the sequential version of the TI protocol. The results show that the calculation can be accelerated by 4 times when compared to the sequential run. Based on the calculations with the parallel computational protocol, a new potential agonist of GW501516 derivative is proposed.

• Tunnel and Underground Space
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• v.21 no.4
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• pp.297-306
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• 2011

In this paper, we performed thermodynamic energy balance analysis of the underground lined rock cavern for compressed air energy storage (CAES) using the results of multi-phase heat flow analysis to simulate complex groundwater-compressed air flow around the cavern as well as heat transfer to concrete linings and surrounding rock mass. Our energy balance analysis demonstrated that the energy loss for a daily compression and decompression cycle predominantly depends on the energy loss by heat conduction to the concrete linings and surrounding rock mass for a sufficiently air-tight system with low permeability of the concrete linings. Overall energy efficiency of the underground lined rock caverns for CAES was sensitive to air injection temperature, and the energy loss by heat conduction can be minimized by keeping the air injection temperature closer to the ambient temperature of the surroundings. In such a case, almost all the heat loss during compression phase was gained back in a subsequent decompression phase. Meanwhile, the influence of heat conductivity of the concrete linings to energy efficiency was negligible.

• Journal of the Korean Solar Energy Society
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• v.26 no.2
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• pp.9-18
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• 2006

In this paper, the thermodynamic performance of OTEC cycle was examined. Computer simulation programs were developed for simple Rankine cycle, regenerative Rankine cycle, Kalina cycle, open cycle and hybrid cycle. For the simple Rankine cycle, the results show that newly developed fluids such as R410A and R32 that do not cause stratospheric ozone layer depletion perform as well as R22 and ammonia. Also, simple Rankine cycle OTEC power plant can practically generate electricity when the difference in warm and cold sea water inlet temperatures are greater than $14^{\circ}C$. The regenerative Rankine cycle showed a 1.5 to 2% increase in energy efficiency compared to the simple Rankine cycle while the Kalina cycle employing ammonia/water mixture showed a 2-to-3% increase in energy efficiency, and the overall cycle efficiencies of hybrid cycle and open cycle were 3.35% and 4.86%, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.11
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• pp.699-707
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• 2017

This study presents a comparative thermodynamic analysis of subcritical and transcritical organic Rankine cycles for the recovery of low-temperature heat sources considering nine substances as the working fluids. The effects of the turbine inlet pressure, source temperature, and working fluid on system performance were all investigated with respect to metrics such as the temperature distribution of the fluids and pinch point in the heat exchanger, mass flow rate, and net power production, as well as the thermal efficiency. Results show that as the turbine inlet pressure increases from the subcritical to the supercritical range, the mismatch between hot and cold streams in the heat exchanger decreases, and the net power production and thermal efficiency increase; however, the turbine size per unit power production decreases.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.234-241
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• 2020

This paper presents a thermodynamic performance analysis of a combined cycle consisting of regenerative organic Rankine cycle (ORC) and liquefied natural gas (LNG) Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the system performances are analyzed in the aspect of thermodynamics. The effects of the turbine inlet pressure and the working fluid on the system performance such as the mass flow rates, heat transfers at heat exchangers, power productions at turbines, and thermal efficiency are systematically investigated. The results show that the thermodynamic performance of ORC such as net power production and thermal efficiency can be significantly improved by the regenerative ORC and the LNG cold energy.

• Journal of Navigation and Port Research
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• v.48 no.2
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• pp.125-136
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• 2024

This research presents an innovative integrated ethanol solid oxide fuel cell (SOFC) system designed for applications in marine vessels. The system incorporates an exhaust gas heat recovery mechanism. The high-temperature exhaust gas produced by the SOFC is efficiently recovered through a sequential process involving a gas turbine (GT), a regenerative system, steam Rankine cycles, and a waste heat boiler (WHB). A comprehensive thermodynamic analysis of this integrated SOFC-GT-SRC-WHB system was performed. A simulation of this proposed system was conducted using Aspen Hysys V12.1, and a genetic algorithm was employed to optimize the system parameters. Thermodynamic equations based on the first and second laws of thermodynamics were utilized to assess the system's performance. Additionally, the exergy destruction within the crucial system components was examined. The system is projected to achieve an energy efficiency of 58.44% and an exergy efficiency of 29.43%. Notably, the integrated high-temperature exhaust gas recovery systems contribute significantly, generating 1129.1 kW, which accounts for 22.9% of the total power generated. Furthermore, the waste heat boiler was designed to produce 900.8 kg/h of superheated vapor at 170 ℃ and 405 kP a, serving various onboard ship purposes, such as heating fuel oil and accommodations for seafarers and equipment.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.4
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• pp.470-476
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• 2010

The thermodynamic performance of closed ocean thermal energy conversion (OTEC) cycle with 1 MW gross power was evaluated to obtain the basic data for the optimal design of OTEC. The basic thermodynamic model for OTEC is Rankine cycle and the thermal effluent from power plant was used for the heat source of evaporator. The cycle performance such as efficiency, heat exchanger capacity, etc. was analyzed on the temperature variation of thermal effluent. The saturated pressure of evaporator increased with respect to the increase of thermal effluent temperature, so the cycle efficiency increased and necessary capacity of evaporator and condenser decreased under 1 MW gross power. As the thermal effluent temperature increases about $15^{\circ}C$, the cycle efficiency increased approximately 44%. So, it was revealed that thermal effluent from power plant is important heat source for OTEC plant. Also, if there is an available waste heat, it can be transferred heat to the working fluid form the evaporator through heat exchanger and cycle efficiency will be increased.

• Journal of Mechanical Science and Technology
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• v.17 no.1
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• pp.122-128
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• 2003

This paper presents a thermodynamic analysis of heat pump system using water as a heat source and heat sink. The primary object in this study is the optimization of exergetic efficiency. Two different systems, 2-stream and 1-stream system, are analyzed in detail. Mass flow ratio (the ratio of mass flow rate of water through evaporator to that through condenser) is identified as the most important parameter to be optimized. It is shown that there exists an optimum mass flow ratio to maximize exergetic efficiency. The variation of optimum exergetic efficiency of 2-stream system is quite small and the value lies between 0.2∼0.23 for the range of investigation in this study. However, far better performance can be obtained from 1-stream system. This means considerable irreversibilities are generated through condenser of the 2-stream system. The effects of adiabatic efficiency of compressor-motor unit on the overall system performance are also examined in the analysis.