• Journal of Electrochemical Science and Technology
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• v.11 no.2
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• pp.117-131
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• 2020

The adsorption of N-[(E)-Pyridin-2-ylmethylidene] aniline, a Schiff base, on to mild steel surface in 1M HCl and 0.5 M H₂SO₄ solutions and the consequent corrosion protection were studied employing weight loss method, electrochemical impedance spectroscopy and potentiodynamic polarization measurements. DFT calculations were performed to investigate its interaction with the metal surface at the atomic level to understand its inhibition mechanism. The adsorption process is well described by the Langmuir isotherm. The thermodynamic parameters indicated that the adsorption is spontaneous and the interaction of the inhibitor at the mild steel surface is mainly through physisorption. The R_a values obtained in AFM studies for the uninhibited and inhibited sample in HCl media respectively are 0.756 and 0.559 ㎛, and that in H₂SO₄ media are 0.411 and 0.406 ㎛. The lesser roughness values of the inhibited sample shows the adsorption of the molecules onto the mild surface. The inhibition efficiencies were found to improve with concentration of the inhibitor and the maximum efficiency was observed at 400ppm in all the investigation methods adopted. The inhibitor was found to exhibit a higher efficiency in HCl media (95.7%) than in H₂SO₄ (92.8%). The theoretical and experimental results are found to be in good agreement.

• Special Issue of the Society of Naval Architects of Korea
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• 2013.12a
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• pp.103-109
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• 2013

The Present work focuses on application of Organic Rankine Cycle - Waste heat Recovery System (ORC-WHRS) for marine diesel engine. ORC and its combined cycle with the engine were simulated and its performance was estimated theoretically under the various engine operation conditions and cooling water conditions. The working fluid, R245fa, was selected for the consideration of the heat source temperature, system efficiency and safety issues. According to the thermodynamic analysis, ~13.1% of system efficiency of the cycle was performed and it is about 4% of the mechanical power output of the considering Marine Diesel Engine. Also, addition of evaporator and pre-heater were studied to maximize output power of Organic Rankine Cycle as a waste heat recovery system of the marine diesel engine.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.17 no.4
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• pp.91-96
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• 2018

This study is collects design data through the process design of the organic Rankine cycle, which can produce 20kW of electric power through the recovery of waste heat. In this study, the simulation was conducted by using APSEN HYSYS in order to make the model for the process design of the 20kW class waste heat recovery system. For the thermodynamic model, the test was conducted with hot water as the heat source, with the water steam used as the cooling water for the cooler and the refrigerant R245fa in the cycle. In Case 1 and Case 2, it was expected and found that the cycle efficiency was 10.6% and that 36.86kw was produced, considering the margin of 84% of 20kW. In Case 3 and Case 4, it was expected and found from the simulation that the cycle efficiency was 12% and that 30.0kw was produced, considering the margin of 84% of 20kW.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.10
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• pp.548-554
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• 2013

A thermodynamic analysis of the R404A refrigeration system with an internal heat exchanger using R744 as a secondary refrigerant is presented in this paper to optimize the design for operating parameters of the system. The main results are summarized as follows: The COP increases with increasing subcooling and superheating degree of R404A, internal heat exchanger and compression efficiency of the R404A cycle and evaporating temperature of the R744 cycle and decreasing temperature difference of the cascade heat exchanger and condensing temperature of the R404A cycle. The mass flow ratio decreases with increasing evaporating temperature of the R744 cycle and internal heat exchanger efficiency of the R404A cycle and decreasing subcooling and superheating degree of the R744 cycle, temperature difference of the cascade heat exchanger and condensing temperature of the R404A cycle.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2268-2273
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• 2008

The drying model has been used to obtain the fundamental information required to design the heat pump dryer with the simple thermodynamic model. In the model, the input conditions are crucial to obtain the acceptable results. The model includes one-stage heat pump cycle, simple drying process using the drying efficiency. The drying efficiency is defined with the conditions of inlet and outlet in the dryer. The experiment has been carried out in the pilot dryer with one-stage heat pump cycle. Refrigerant 134a is used in the heat pump cycle. In the dryer, some of drying air flows through the heat pump system and the rest of air bypasses the heat pump system and circulates through the drying chamber. Some operating conditions from the pilot dryer are used as input conditions of the model and the results are compared with experimental results for the validation.

• Journal of the Korean Solar Energy Society
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• v.31 no.6
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• pp.49-56
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• 2011

In this study a novel cogeneration system driven by low-temperature sources at a temperature level below $190^{\circ}C$ is investigated by first and second laws of thermodynamics. The system consists of Organic Rankine Cycle(ORC) and an additional heat generation as a parallel circuit. Seven working fluids of R143a, R22, R134a, R152a, $iC_4H_{10}$(isobutane), $C_4H_{10}$(butane), and R123a are considered in this work. Maximum mass flow rate of a working fluid relative to that of the source fluid and optimum turbine inlet pressure are considered to extract maximum power from the source. Results show that due to a combined heat and power generation, both the efficiencies by first and second laws can be significantly increased in comparison to a power generation, however, the second law efficiency is more resonable in the investigation of cogeneration systems. Results also show that the working fluid for the maximum system efficiency depends on the source temperature.

• Journal of Hydrogen and New Energy
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• v.31 no.6
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• pp.637-645
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• 2020

In this paper, entransy analysis is carried out for combined heat and power (CHP) generation system driven by low-grade heat source compared with energy and exergy analyses. The system consists of a regenerative organic rankine cycle (ORC) and an additional process heater in a series circuit. Special attention is paid to the effects of the turbine inlet pressure, source temperature, and the working fluid on the thermodynamic performance of the system. Results showed that the work efficiency of entransy is higher than that of energy but lower than that of exergy, wheress the process heat efficiency of entransy is lower than that of energy but higher than that of exergy. Entrance analysis showed the potential to complement the exergy analysis in the optimal design of the energy system.

• Journal of Hydrogen and New Energy
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• v.32 no.1
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• pp.77-85
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• 2021

In this paper, entransy analysis is carried out for combined heat and power (CHP) generation system driven by low-grade heat source compared with energy and exergy analyses. The system consists of an organic Rankine cycle (ORC) and an additional process heater in a parallel circuit. Special attention is paid to the effects of the source temperature, turbine inlet pressure, and the working fluid on the thermodynamic performance of the system. Results showed that the work efficiency of entransy is higher than that of energy but lower than that of exergy, wheress the process heat efficiency of entransy is lower than that of energy but higher than that of exergy. Entrancy analysis showed the potential to complement the exergy analysis in the optimal design of the energy system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.6
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• pp.483-491
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• 2014

In this study, a thermodynamic analysis was carried out for a combined power generation system using a low-temperature heat source in the form of sensitive energy and liquefied natural gas cold energy. An ammonia-water mixture, which is a zeotropic mixture, was used as the working fluid, and systems with and without a regenerator were comparatively analyzed. The effects of the mass fraction of ammonia and the condensation temperature of the working fluid on the system variables, including the net work production, exergy destruction, and thermal and exergy efficiencies, are analyzed and discussed. The results show that the performance characteristics of the system varied sensitively with the ammonia concentration or condensation temperature of the working fluid. The system without regeneration was found to be better in relation to the net work per unit mass of the source fluid, whereas the system with regeneration was better in relation to the thermal or exergy efficiency.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.237-242
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• 2005

The energy consumed by compressor in gas turbine is equivalent to $30\sim50\%$ of energy produced by turbine and, therefore, research on reducing compression work is important in increasing the efficiency of gas turbine. One of the method to reduce the compression work is to inject small water droplets into the compressor. This method decreases the compression work by decreasing the compressor exit temperature through the evaporation of water. Researches on wet compression, up to now, are focused on thermodynamic analysis of wet compression where the decrease of exit flow temperature and compression work is demonstrated. This paper presents an thermodynamic and aerodynamic analysis of wet compression in centrifugal compressor for microturbine.