• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.240-253
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• 1996

The refrigeration cycle of automobile air-conditioners is simulated in an effort to provide a computational tool for optimum thermodynamic design. In the simulation, thermodynamic and heat transfer analysis was performed for the four major components : evaporator, condenser, compressor, and expansion valve. Effectiveness-NTU method was used for modeling both evaporator and condenser. The evaporator was divied into many subgrids and simultaneous cooling and dehumidifying analysis was performed for each grid to predict the performance accurately. Blance equations were used to model the compressor instead of using the compressor map. The performance of each component was checked against the measured data with CFC-12. Then, all the components were combined to yield the total system performance. Predicted cycle points were compared against the measured data with HFC-134a and the deviation was found to be less than 5% for all data. Finally, the system model was used to predict the performance of CFC-12 and HFC-134a for comparison. The results were very reasonable as compared to the trend deduced from the measured data.

• International Journal of Air-Conditioning and Refrigeration
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• v.6
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• pp.124-135
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• 1998

A thermodynamic cycle analysis is performed for refrigerator-precooled Linde-Hampson hydrogen liquefiers, including catalysts for the ortho-to-para conversion. Three different configurations of the liquefying system, depending upon the method of the o-p conversion, are selected for the analysis. After some simplifying and justifiable assumptions are made, a general analysis program to predict the liquid yield and the figure of merit (FOM) is developed with incorporating the commercial computer code for the thermodynamic properties of hydrogen. The discussion is focused on the effect of the two primary design parameters - the precooling temperature and the high pressure of the cycle. When the precooling temperature is in a range between 45 and 60 K, the optimal high pressure for the maximal liquid yield is found to be about 100 to 140 bar, regardless of the ortho-to-para conversion. However, the FOM can be maximized at slightly lower high pressures, 75 to 130 bar. It is concluded that the good performance of the precooling refrigerator is significant in the liquefiers, because at low precooling temperatures high values of the liquid yield and the FOM can be achieved without compression of gas to a very high pressure.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.15 no.5
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• pp.432-438
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• 2003

This paper describes a modified Roebuck compression device as a potential compression device of a rotating cryogenic refrigeration system in superconducting machine such as generator or motor. The conventional cryogen transfer method from stationary refrigeration system to rotating system can be eliminated by an on-board cryogenic refrigeration system that utilizes well-designed multi-stage modified Roebuck compression device. This paper shows basic thermodynamic analysis of modified Roebuck compression device and its application for compressing neon at 77 K with substantial pressure ratio when the rotor diameter is 0.8 m with rotating speed of 3600 rpm. The device does not require any moving part in rotating frame, but two separate thermal reservoirs to convert thermal energy into mechanical compression work. The high temperature thermal reservoir is atmospheric environment at 300 K and the low temperature thermal reservoir is assumed as a liquid nitrogen bath at 77 K. The concept of the compression device in this paper demonstrates its usefulness of generating high-pressure neon at 77 K for rotating J-T neon refrigeration cycle of superconducting rotor.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1029-1035
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• 2014

The protolytic dissociation process of hydrochloric acid (HCl) and hydrofluoric acid (HF) is studied using the B3LYP and MP2 methods with the 6-311+G(d,p) basis set in the gas phase and in aqueous solution. To study the phenomena in detail, discrete and discrete/continuum models were applied by placing water molecules in various positions around the acid. The dissociation process was studied using the thermodynamic cycle involving the structures optimized both in the gas phase and in aqueous solution and was analyzed with two key energy factors, relaxation free energy (${\Delta}G_{Rex(g)}$) and solvation free energy (${\Delta}G_s$). Based on the results, we could understand the dissociation mechanism and wish to propose the best way to study acid dissociation process using the CPCM methodology in aqueous solution.

• Journal of the Korean Solar Energy Society
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• v.30 no.3
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• pp.124-130
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• 2010

Ocean Thermal Energy Conversion(OTEC) power plants have been examined as a viable option for supplying clean energy. This paper evaluated the thermodynamic performance of the OTEC Power system for the production of electric power and desalinated water. The results show that newly developed fluids such as R32, R125, R143a, and R410A that do not cause stratospheric ozone layer depletion perform as well as R22 and ammonia. Overall cycle efficiency of open cycle is the lowest value of 3.01% because about 10% of the gross power is used for pumping out non-condensable gas. Also, the hybrid cycle is an attempt to combine the best features and avoid the worst features of the open and closed cycles. The overall cycle efficiency of hybrid cycle is 3.44% and the amount of desalinated water is 0.0619 kg/s.

• Atmosphere
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• v.24 no.4
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• pp.457-470
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• 2014

Thermodynamic conditions related with localized torrential rainfall in the middle west region of Korean peninsula are examined using radar rain rate and radiosonde observational data. Localized torrential rainfall events in this study are defined by three criteria base on 1) any one of Automated Synoptic Observing System (ASOS) hourly rainfall exceeds $30mmhr^{-1}$ around Osan, 2) the rain (> $1mmhr^{-1}$) area estimated from radar reflectivity is less than $20,000km^2$, and 3) the rain (> $10mmhr^{-1}$) cell is detected clearly and duration is short than 24 hr. As a result, 13 cases were selected during the summer season of 10 years (2004-13). It was found that the duration, the maximum rain area, and the maximum volumetric rain rate of convective cells (> $30mmhr^{-1}$) are less than 9hr, smaller than $1,000km^2$, and $15,000{\sim}60,000m^3s^{-1}$ in these cases. And a majority of cases shows the following thermodynamic characteristics: 1) Convective Available Potential Energy (CAPE) > $800Jkg^{-1}$, 2) Convective Inhibition (CIN) < $40Jkg^{-1}$, 3) Total Precipitable Water (TPW) ${\approx}$ 55 mm, and 4) Storm Relative Helicity (SRH) < $120m^2s^{-2}$. These cases mostly occurred in the afternoon. These thermodynamic conditions indicated that these cases were caused by strong atmospheric instability, lifting to overcome CIN, and sufficient moisture. The localized torrential rainfall occurred with deep moisture convection result from the instability caused by convective heating.

• Journal of Ocean Engineering and Technology
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• v.25 no.1
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• pp.80-84
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• 2011

The cycle performance of closed ocean thermal energy conversion (OTEC) system with 50 kW gross power was evaluated to obtain the basic data for the optimal design of OTEC using waste heat such as solar power, discharged heat from condenser of power plant. The basic thermodynamic model for OTEC is Rankine cycle, and the surface seawater and deep seawater were used for the heat source of evaporator and condenser, respectively. The cycle performance such as efficiency, heat exchanger capacity, etc. was analyzed on the variation of temperature increase by waste heat. The cycle efficiency increased and necessary capacity of evaporator and condenser decreased under 50kW gross power with respect to the temperature increase of working fluid. Also, when the temperature increase is about $13.5^{\circ}C$, the heat which can be used is generated. By generator with 0.9 effectiveness under the simulated condition, the cycle efficiency was improved approximately 3.0% comparing with the basic cycle.

• Journal of Hydrogen and New Energy
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• v.29 no.2
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• pp.148-154
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• 2018

This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.10
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• pp.548-554
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• 2013

A thermodynamic analysis of the R404A refrigeration system with an internal heat exchanger using R744 as a secondary refrigerant is presented in this paper to optimize the design for operating parameters of the system. The main results are summarized as follows: The COP increases with increasing subcooling and superheating degree of R404A, internal heat exchanger and compression efficiency of the R404A cycle and evaporating temperature of the R744 cycle and decreasing temperature difference of the cascade heat exchanger and condensing temperature of the R404A cycle. The mass flow ratio decreases with increasing evaporating temperature of the R744 cycle and internal heat exchanger efficiency of the R404A cycle and decreasing subcooling and superheating degree of the R744 cycle, temperature difference of the cascade heat exchanger and condensing temperature of the R404A cycle.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.3
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• pp.490-499
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• 1989

These days the closed cycle gas turbine attracts considerable attention due to : (1) The possibility of directly coupling the closed cycle gas turbine with a high temperature gas cooled reactor ; (2) the economical use of dry coolers to reduce the thermal charge of the environment ; and (3) the reduction of pollution and energy consumption, by replacing the domestic hearth by a central heating and power station. In this paper, we selected the optimal cycle from the characteristic of thermodynamic cycle for the optimal design of closed CO$_{2}$ gas turbine cycle usuable in nuclear energy power plant. Also the effects of between the parameters and thermal efficiency were investigated by computer simulation. These results and design data will be added to basics in optimal designing closed CO$_{2}$ cycle gas turbine plant.