• Asian Journal of Atmospheric Environment
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• v.8 no.2
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• pp.89-95
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• 2014

There have been a lot of efforts to keep permissible emission standards and to reduce the amount of emitted air pollutants. There are several air pollution control equipments, however, wet scrubber is used to remove particulate matters and gaseous pollutants simultaneously, even if it has low collection efficiency in the particle size less than $5.0{\mu}m$. To overcome this problem, we introduced a spray tower scrubber with an electrospray system which a high voltage was indirectly applied. We found that collection efficiency of fine particles in the electrospray system was improved by increasing electrical field strength and the ratio of liquid-gas flow rate (from 41% to 84% for $0.3{\mu}m$ particles). In addition, a number of small droplets generated from an electrospray system led high collection efficiency, resulting from electrostatic attraction between droplets and particles and higher collision frequency. Therefore, we can conclude that the introduction of an electrospray system is quite effective to increase the particle removal efficiency of a spray tower scrubber.

• Journal of the Korean Wood Science and Technology
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• v.19 no.4
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• pp.80-84
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• 1991

Lignocellulosic biomass including acetosolv ricestraw and spruce lignin were liquefied and converted into liquid hydrocarbons by catalytic hydroliquefaction reaction. These experimental works were carried out in 1-liter-capacity autoclave using 50% tetralin and m-cresol solution respectively as soluble solvent and Ni. Pd. Fe and red mud as catalyst. $H_2$ gas was supplied into the reactor for escaltion of deoxhydroenolysis reaction. Catalyst concentrations were 1 % of raw material based on weight. The ratio between raw materials and soluble solvent are 1g and 10cc. The reaction conditions are 400-$700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure. The highest yield of hydrocarbon, so called "product oil" showed 32% and 5.5% of lowest char formation when red mud was used as catalyst. The product oil yields from those of other catalysts were in the range of 20-29%. The influence of different initial hydrogen pressures was examined in the range d 30-50 atms. A minimum pressure of 35 atms was necessary to obtain a complete recovery of souble solvent for recycling.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.75-81
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• 1993

The thermochemical stability of $Ni^{2+}-faujasite$ was studied by differential thermal analysis(DTA), thermal gravitational analysis(TGA), X-ray diffraction analysis(XRD) and quantum chemical calculations. Dehydration of $Ni^{2+}-faujasite$ was observed at 373-773K. A CNDO/2 calculations have been applied on cluster models for the representative T sites in faujasite to get total energy and wiberg bond orders. It has proved that the decrease of zeolitic crystallinity is directly related to the weakening of Al-O bonds in framework.

• Proceedings of the Korean Magnestics Society Conference
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• 2013.12a
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• pp.89-89
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• 2013

Rare earth (RE) - transition metal based high energy density magnets are of immense significance in various engineering applications. $Nd_2Fe_{14}B$ magnets possess the highest energy product and are widely used in whole industries. Simultaneously, composite alloys that are cheap, cost effective and strong commercially available have drawn great attention, because rare-earth metals are costly, less abundant and strategic shortage. We designed rare-earth free alloys and fabrication process and developed novel route to prepare $Nd_2Fe_{14}B$ powders by wet process employing spray drying and reduction-diffusion (R-D) without the use of high purity metals as raw material. MnAl-base permanent magnetic powders are potentially important material for rare-earth free magnets. We have prepared the nano-sized MnAl powders by plasma arc discharge and micron-sized MnAl powders by gas atomization. They showed good magnetic property, compared with that from conventional processes. $Nd_2Fe_{14}B$ powders with high coercivity of more than 10 kOe were successfully synthesized by adjusting R-D step, followed by precise washing system. It is considered that this process can be applied for the recycling of RE-elements extracted from ewaste including motors.

• International Journal of Air-Conditioning and Refrigeration
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• v.6
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• pp.36-44
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• 1998

R-410a and R-407c which have the best potential among R-22 alternatives were tested as drop-in refrigerants against a set of R-22 baseline tests. The performance evaluations were carried out in a psychometric calorimeter test facility using the residential spilt type air conditioner under the ARI rating conditions. Except the lubricant and hand-operated expansion valve, the other parts of the air conditioner were the same with the commercial system. Performance characteristics were measured; compressor power, capacity, VCR, mass flow rate and COP. The tests showed that R-407c can be directly charged into the current refrigeration system because its vapor pressure and other thermochemical properties are similar to those of R-22. However, it is required to change the volume flow rate of compressor in order to achieve the volumetric capacity of R-22. This results from its relatively small VCR and capacity. Meanwhile, R-410a has vapor pressure values too high to be substituted for the current system and this resulted relatively low COP of R-410a compared to that of R-22.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.16 no.6
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• pp.1-8
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• 2007

The ultra-fine tungsten carbide(WC) powders have been actively used in the cemented carbides industry, because they have excellent mechanical properties such as high hardness, strength, and toughness. In this study, ultra-fine WC-Co alloys powders have been fabricated by thermochemical and thermomechanical process such as spray conversion process or high energy ball milling. The non-coated end-mill which is made of ultra-fine tungsten carbide is investigated by measuring cutting force, tool wear, tool life, and surface roughness profile according to cutting length. The machining test was conducted with high hardened workpiece and their performances are investigated in high speed cutting conditions. Also, the relationship between the machining characteristics and the Co contents are investigated under various high speed cutting conditions.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• Korean Journal of Crystallography
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• v.7 no.1
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• pp.64-72
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• 1996

Calculation of the amount of excess arsenic charge has been carried out for the single crystal growth of GaAs with 1-T HB(single temperature zone horizontal Bridgman) method which has no low temperature arsenic zone. Based upon the investigation of the thermochemical properties of the Ga and As system, a general equation for the excess dimension of the ampoule and temperature gradient of the furnace. From this result, a theoretical background of the 1-T HB method has been constructed for the single crystal growth of GaAs.

• Journal of Hydrogen and New Energy
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• v.17 no.2
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• pp.218-226
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• 2006

It can be obtained from hydrocarbon and water, specially production of hydrogen from natural gas is most commercial and economical process among the hydrogen production methods, and has been used widely. However, conventional hydrogen production methods are dependent on fossil fuel such as natural gas and coal, and it may be faced with problems such as exhaustion of fossil fuels, production of greenhouse gas and increase of feedstock price. Thermochemical hydrogen production by nuclear energy has potential to efficiently produce large quantities of hydrogen without producing greenhouse gases. However, nuclear hydrogen must be economical comparing with conventional hydrogen production method. Therefore, hydrogen production cost was analyzed and estimated for nuclear hydrogen as well as conventional hydrogen production such as natural gas reforming and coal gasification in various range.

• Journal of Hydrogen and New Energy
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• v.17 no.2
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• pp.141-148
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• 2006

This study was carried out to analyze the microstructure characteristics of electrolyte membrane through XRD, SEM and AC impedance measurement for using in high temperature steam electrolysis(HTE). It was investigated that thermal stability and electric characteristics by sintering condition using dry and wet process, and confirmed growth of particle and density change by sintering temperature. The sintering temperature and behavior had an effect on the relative density of the ceramic and the average grain size. The more amount of dispersant in organic compound increase, the more the density increased. But the binder was shown opposite phenomenon. It was analyzed that electrolyte resistance and electrical characteristics using AC impedance. The electrical properties of YSZ grain boundary changed with the sintering temperature.