• Title/Summary/Keyword: Thermo-Physical Properties

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Fundamental study on development of latent heat storage material for waste heat recovery of biomass gasification

  • Kim, MyoungJun;Yu, JikSu;Chea, GyuHoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.5
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    • pp.533-540
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    • 2014
  • Recently, latent heat thermal energy storage system (LHTES) has gained attention in order to utilize middle temperature (373~573 K) waste heat from biomass gasification. This paper has investigated thermo-physical properties of erythritol [$CH_2OHCHOH$ $CHOHCH_2OH$], mannitol [$CH_2OH$ $(CHOH)_4CH_2OH$] and their compounds as phase change materials (PCMs). The differential scanning calorimetry (DSC) was applied to measure the melting point and latent heat of these PCMs. Also the melting and solidification characteristics of these PCMs were observed in a glass tube with a digital camera. In the DSC measurement, when the amount of mannitol content was more than 40 mass%, the melting point of these compounds show two melting points. The experimental results showed that the velocity of melting and solidification were different for every mixture ratio of compounds. These compounds had the super-cooling phenomenon during the solidification process.

A Study on Thermal Conductivity Characteristics of Nanofluids (나노유체 열전도도 특성 연구)

  • Hwang, Yu-Jin;Park, Jae-Hong;Kim, Hong-Suk;Lee, Jae-Keun
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.162-167
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    • 2006
  • Nanofluid is a kind of new engineering material consisting of nanoparticles dispersed in base fluid. Nanofluids could have various applications such as magnetic fluids, heat exchanger working fluids, lubricants, drug delivery and so on in present study, various nanoparticles, such as MWCNT (Multi-walled Carbon Nanotube), fullerene, copper oxide, and silicon dioxide are used to produce nanofluids. As base fluids, DI-water, ethylene glycol, oil, and silicon oil are used. To investigate the thermo-physical properties of nanofluids, thermal conductivity and kinematic viscosity are measured. Stability estimation of nanofluid is conducted with UV-vis spectrophoto-meter. In this study, the high pressure homogenizer is the most effective method to produce nanofluid with the prepared nanoparticle and base fluid. Excellently stable nanofluids are produced with the magnetron sputtering system. Thermal conductivity of nanofluid increases with increasing particle volume fraction except water-based fullerene nanofluid which has lower thermal conductivity than base fluid due to its lower thermal conductivity, 0.4 W/mK. The experimental results can't be predicted by Jang and Choi model.

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SMA-based devices: insight across recent proposals toward civil engineering applications

  • Casciati, Sara
    • Smart Structures and Systems
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    • v.24 no.1
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    • pp.111-125
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    • 2019
  • Metallic shape memory alloys present fascinating physical properties such as their super-elastic behavior in austenite phase, which can be exploited for providing a structure with both a self-centering capability and an increased ductility. More or less accurate numerical models have been introduced to model their behavior along the last 25 years. This is the reason for which the literature is rich of suggestions/proposals on how to implement this material in devices for passive and semi-active control. Nevertheless, the thermo-mechanical coupling characterizing the first-order martensite phase transformation process results in several macroscopic features affecting the alloy performance. In particular, the effects of day-night and winter-summer temperature excursions require special attention. This aspect might imply that the deployment of some devices should be restricted to indoor solutions. A further aspect is the dependence of the behavior from the geometry one adopts. Two fundamental lacks of symmetry should also be carefully considered when implementing a SMA-based application: the behavior in tension is different from that in compression, and the heating is easy and fast whereas the cooling is not. This manuscript focuses on the passive devices recently proposed in the literature for civil engineering applications. Based on the challenges above identified, their actual feasibility is investigated in detail and their long term performance is discussed with reference to their fatigue life. A few available semi-active solutions are also considered.

Numerical Study on Skin Burn Injury due to Flash Flame Exposure (돌발화염으로 인한 화상예측에 관한 수치해석적 연구)

  • Lee, Jun-Kyoung;Bang, Chang-Hoon
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.13-20
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    • 2012
  • Many fire-fighters suffer from the burn injuries, and the severe burns are the most catastrophic injury a person can survive, resulting in pain, emotional stress, and tremendous economic costs. It is important to understand the physiology of burns for prevention from skin burns and a successful treatment of a burn patient. But a few researches have been presented because the complex physical phenomena of our inside body like non-linearity characteristics of human skin make them difficult. Thus in this study, thermal analyses of biological tissues exposed to a flash fire causing severe tissue damage were studied by using a finite difference method based on the Pennes bio-heat equation. The several previous models for skin thermo-physical properties were summarized, and the calculated values with those models of tissue injury were compared with the results obtained by the previous experiment for low heat flux conditions. The skin models with good agreement could be found. Also, the skin burn injury prediction results with the best model for high heat flux conditions by flash flame were suggested.

Fabrication and Characterization of Ceramics and Thermal Barrier Coatings of Lanthanum Zirconate with Reduced Rare-earth Contents in the La2O2-ZrO2 System (희토류 저감형 란타눔 지르코네이트(La2O2-ZrO2계) 세라믹스와 열차폐코팅의 제조 및 특성평가)

  • Kwon, Chang-Sup;Lee, Sujin;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seongwon
    • Journal of Powder Materials
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    • v.22 no.6
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    • pp.413-419
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    • 2015
  • Lanthanum zirconate, $La_2Zr_2O_7$, is one of the most promising candidates for next-generation thermal barrier coating (TBC) applications in high efficient gas turbines due to its low thermal conductivity and chemical stability at high temperature. In this study, bulk specimens and thermal barrier coatings are fabricated via a variety of sintering processes as well as suspension plasma spray in lanthanum zirconates with reduced rare-earth contents. The phase formation, microstructure, and thermo-physical properties of these oxide ceramics and coatings are examined. In particular, lanthanum zirconates with reduced rare-earth contents in a $La_2Zr_2O_7-4YSZ$ composite system exhibit a single phase of fluorite or pyrochlore after fabricated by suspension plasma spray or spark plasma sintering. The potential of lanthanum zirconate ceramics for TBC applications is also discussed.

Experimental Study on the Thermal Characteristics According to the Content Change of Biodiesel Mixture (바이오디젤 혼합물의 함량변화에 따른 열적 특성에 대한 실험적인 연구)

  • Ju Suk Kim;Jae Sun Ko
    • Journal of the Society of Disaster Information
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    • v.19 no.3
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    • pp.532-544
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    • 2023
  • Purpose: To identify and evaluate the risk of chemical fire causative substances by using thermal analysis methods (DSC, TGA) for the hazards and physical property changes that occur when newly used biofuels are mixed with existing fuels It is to use it for identification and evaluation of the cause of fire by securing data related to the method and the hazards of the material according to it. Method: The research method used in this experiment is the differential scanning calorimeter (DSC: Difference in heat flux) through quantitative information on the caloric change from the location, shape, number, and area of peaks. flux) was measured, and the weight change caused by decomposition heat at a specific temperature was continuously measured by performing thermogravimetric analyzer (TGA: Thermo- gravimetric Analyzer). Result: First, in the heat flux graph, the boiling point of the material and the intrinsic characteristic value of the material or the energy required for decomposition can be checked. Second, as the content of biodiesel increased, many peaks were identified. Third, it was confirmed through analysis that substances with low expected boiling points were contained. Conclusion: It was shown that the physical risk of the material can be evaluated by using the risk of biodiesel, which is currently used as a new energy source, through various physical and chemical analysis techniques (DSC + TGA).In addition, it is expected that the comparison of differences between test methods and the accumulation and utilization of know-how on experiments in this study will be helpful in future studies on physical properties of hazardous materials and risk assessment of materials.

Stabilization of Dry Immuno-Diagnostic Kit with Immobilized Antibody and Determination of Its Shelf-Life (항체가 건조상태로 고정된 면역진단키트의 안정화와 Shelf-Life 결정)

  • 이창우;조정환;육순학;권오협;박영남;박세환
    • KSBB Journal
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    • v.13 no.5
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    • pp.502-510
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    • 1998
  • Stabilization of antibody, which is specific to Salmonella typhimurium antigens, present in dry states on membranes was accomplished, and its shelf-life, i.e., duration for maintaining minimum 90% of the initial activity, under optimal conditions was determined. To prepare two major components of an immuno-strip, the antibody was not only immobilized on nitrocellulose membrane surfaces but also placed within the pores of glass fiber membrane after conjugating it with old colloids as signal generator. Among potential stabilizers of the immuno-components, a disaccharide, trehalose, showed a significant protection effect of immunoglobulin structure from thermal energy. Optimal concentrations of trehalose for the respective component were significantly different (8-fold higher for the antibody-gold conjugate than for the immobilized antibody), which probably resulted from distinct densities and configurations of antibody present on the membranes. An additional requirement for the gold conjugate was freeze-drying of this substance such that the conjugate can be readily resolubilized upon contact with aqueous medium. By using the components prepared under optimal conditions, immuno-strips were constructed and exposed to thermal energy. Signals with less than 10% decrease in the intensity were maintained for approximately 21 days at 60$^{\circ}C$. Compared to previous reports, this result represented a 2-year shelf-life at room temperature. it was, however, two times longer if determined from thermal acceleration tests based on the theory of inactivation rate of protein. Such discrepancy between the two estimates could be mainly attributed to errors in accurately controlling temperatures and also to changes in the physical properties of membranes due to a high thermal energy.

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Effects of Zn and Mg Amounts on the Properties of High Thermal Conductivity Al-Zn-Mg-Fe Alloys for Die Casting (다이캐스팅용 고열전도도 Al-Zn-Mg-Fe 합금의 특성에 미치는 Zn 및 Mg 첨가량의 영향)

  • Kim, Ki-Tae;Lim, Young-Suk;Shin, Je-Sik;Ko, Se-Hyun;Kim, Jeong-Min
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.113-121
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    • 2013
  • The effects of Zn and Mg amounts on the solidification characteristics, microstructure, thermal conductivity and tensile strength of Al-Zn-Mg-Fe alloys were investigated for the development of high thermal conductivity aluminium alloys for die casting. Zn and Mg amounts in Al-Zn-Mg-Fe alloys had a little effect on the liquidus / solidus temperature, the latent heat for solidification and the fluidity of Al-Zn-Mg-Fe alloys. Thermo-physical modelling of Al-Zn-Mg-Fe alloys by JMatPro program showed $MgZn_2$, AlCuMgZn and Al3Fe phases on microstructure of their alloys. Increase of Zn and Mg amounts in Al-Zn-Mg-Fe alloys resulted in gradual reduction of the thermal conductivity of their alloys. Increase of Mg amounts in Al-2%Zn-Mg-Fe alloys had little effect on the tensile strength of their alloys, but increase of Mg amounts in Al-4%Zn-Mg-Fe alloys resulted in steep increase of the tensile strength of their alloys.

Performance of Natural Circulation Hot Water System with Flat-Plate Solar Collectors (평만형 태양열 집열기 를 설치한 자연 순환식 급탕시스템 의 성능 에 관한 연구)

  • 윤석범;전문헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.5
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    • pp.579-589
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    • 1985
  • The storage tank of the natural-circulation-solar-hot-water system equipped with flat-plate solar collectors is located at higher elevation than the solar collectors. Therefore, the heat loss from the system due to a reversed flow during the night-time is an important factor as well as the day-time thermal performance of the system. The thermal performance of the natural-circulation-solar-hot-water system with flat-plate solar collectors during the day-time depends mainly on the heat collecting efficiency of the solar collectors, whereas its thermal performance during the night-time depends on the system configuration , such as the elevation of the water storage tank with respect to the solar collectors and the piping connections between the storage tank and the solar collectors, as well as thermo-physical properties of the circulating fluid. In the present work, a computer program has been developed to simulate a typical natural-circulation-solar-hot-water-system, and a series of simulation tests have been carried out with the computer program to examine the thermal performance of the system during the day-time as well as the hight-time. In addition , a series of experiment have been conducted under a real sun condition using a natural-circulation-solar-hot-water-system constructed and installed at the KAIST building to compare with the results obtained from computer simulations.

Effects of Alloying Elements on the Properties of High Strength and High Thermal Conductivity Al-Zn-Mg-Fe Alloy for Die Casting (다이캐스팅용 Al-Zn-Mg-Fe 합금의 특성에 미치는 Zn 및 Mg 첨가의 영향)

  • Kim, Ki-Tae;Lim, Young-Suk;Shin, Je-Sik;Ko, Se-Hyun;Kim, Jeong-Min
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.171-180
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    • 2013
  • The effects of alloying elements on the solidification characteristics, microstructure, thermal conductivity, and tensile strength of Al-Zn-Mg-Fe alloys were investigated for the development of high strength and high thermal conductivity aluminium alloy for die casting. The amounts of Zn and Mg in Al-Zn-Mg-Fe alloys had little effect on the liquidus/solidus temperature, the latent heat for solidification, the energy release for solidification and the fluidity of Al-Zn-Mg-Fe alloys. Thermo-physical modelling of Al-Zn-Mg-Fe alloys by the JMatPro program showed $MgZn_2$, AlCuMgZn and $Al_3Fe$ phases in the microstructure of the alloys. Increased amounts of Mg in Al-Zn-Mg-Fe alloys resulted in phase transformation, such as $MgZn_2{\Rightarrow}MgZn_2+AlCuMgZn{\Rightarrow}AlCuMgZn$ in the microstructure of the alloys. Increased amounts of Zn and Mg in Al-Zn-Mg-Fe alloys resulted in a gradual reduction of the thermal conductivity of the alloys. Increased amounts of Zn and Mg in Al-Zn-Mg-Fe alloys had little effect on the tensile strength of the alloys.