• Title/Summary/Keyword: Thermite Reaction

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Effects of Mg-Al Alloy and Pure Ti on High Temperature Wetting and Coherency on Al Interface Using the Sessile Drop Method (정적법을 이용한 Mg-Al계 합금과 순수 Ti의 고온 젖음현상 및 Al계면에서의 정합성에 미치는 영향)

  • Han, Chang-Suk;Kim, Woo-Suk
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.38-42
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    • 2021
  • In this study, high temperature wetting analysis and AZ80/Ti interfacial structure observation are performed for the mixture of AZ80 and Ti, and the effect of Al on wetting in Mg alloy is examined. Both molten AZ80 and pure Mg have excellent wettability because the wet angle between molten droplets and the Ti substrate is about 10° from initial contact. Wetting angle decreases with time, and wetting phenomenon continues between droplets and substrate; the change in wetting angle does not show a significant difference when comparing AZ80-Ti and Mg-Ti. As a result of XRD of the lower surface of the AZ80-Ti sample, in addition to the Ti peak of the substrate, the peak of TiAl3, which is a Ti-Al intermetallic compound, is confirmed, and TiAl3 is generated in the Al enrichment region of the Ti substrate surface. EDS analysis is performed on the droplet tip portion of the sample section in which pure Mg droplets are dropped on the Ti substrate. Concentration of oxygen by the natural oxide film is not confirmed on the Ti surface, but oxygen is distributed at the tip of the droplet on the Mg side. Molten AZ80 and Ti-based compound phases are produced by thickening of Al in the vicinity of Ti after wetting is completed, and Al in the Mg alloy does not affect the wetting. The driving force of wetting progression is a thermite reaction that occurs between Mg and TiO2, and then Al in AZ80 thickens on the Ti substrate interface to form an intermetallic compound.

A Study on the Purity Change of Silicon Metal According to the Purity of Silica Stone in Metal Silicon Extraction by Thermit Reaction (테르밋 반응을 이용하여 금속실리콘을 추출할 때 규석 순도에 따라 금속실리콘 순도 변화에 대한 고찰)

  • Kim, Jaehee;Han, Jinho;Shin, Hyunmyung
    • Resources Recycling
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    • v.26 no.4
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    • pp.19-25
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    • 2017
  • The ways of producing metal silicon include a carbon reduction method, a plasma reduction method, and a thermite reaction method. The carbon reduction process produces metal silicon by metallurgical refining. The carbon reduction method is produced by adding a raw material mixed with quartz and coke to an electric arc furnace which is for carbon reduction. The cost of high energy costs and environmental protection facilities is an issue when producing metal silicon using electric arc furnaces. For this reason, there is no metal silicon production facility in Korea yet. Therefore, the optimal manufacturing conditions by the carbon reduction method are being studied through the experimental facilities by the companies and research institutes. The present study investigated the change of metal silicon purity according to the purity of silicon when extracting metal silicon using the thermit reaction, which has a relatively lower manufacturing cost than the carbon reduction method.

Experimental and Numerical Study on the Dynamic Fracture Processes of PMMA Block by NRC Vapor Pressure Fracture Agent (NRC 증기압 암석 파쇄제에 의한 PMMA 블록의 동적 파괴 과정에 관한 실험 및 수치해석적 연구)

  • Gyeongjo Min
    • Journal of Korean Society of Disaster and Security
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    • v.16 no.1
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    • pp.91-103
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    • 2023
  • This study aims to investigate the dynamic fracture characteristics of rocks and rock-like materials subjected to the Nonex Rock Cracker (NRC), a vapor pressure crushing agent that produces vapor pressure by instantaneously vaporizing a liquid mixture crystallized through the thermite reaction. Furthermore, the study seeks to develop an analytical technique for predicting the fracture pattern. A dynamic fracture test was performed on a PMMA block, an artificial brittle material, using the NRC. High-speed cameras and dynamic pressure gauges were employed to capture the moment of vapor pressure generation and measure the vapor pressure-time history, respectively. The 2-dimensional Dynamic Fracture Process Analysis (2D DFPA) was used to simulate the fracture process caused by the vapor pressure, with the applied pressure determined based on the vapor pressure-time history. The proposed analytical method was used to examine various fracture patterns with respect to granite material and high-performance explosives.

The Properties of Aluminium Alloy Powder for Aluminothermy Process with $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진의 Al 테르밋 반응용 Al 합금분말의 특성)

  • Kim, Youn-Che;Song, Youn-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.71-77
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    • 2013
  • Aluminium powder as reductant in aluminothermy process needs a fine particle size under 200 mesh, but it is not easy economically to make that because of its high ductility and powder production cost. In order to reduce the production cost of fine aluminum powder as reductant of $Mn_3O_4$ waste dust, therefore, the properties of aluminium alloy powder were investigated. Aluminium alloy ingot containing large amount of manganese can be crushed easily because of its intermetallic compounds having brittle properties. The manganese is also main element in ferro-manganese. We can obtain economically Al-15%Mn alloy powder by mechanical comminution process. And the result of thermite reaction using Al-15% Mn alloy powder instead of pure Al powder showed the fact that can be obtained the ferro-manganese which have a high purity in case of using pure aluminium powder as reductant. The recovery of manganese from $Mn_3O_4$ waste dust with Al-15%Mn alloy powder was higher level of about 70% than about 65% in case of using aluminium powder, that is due to lower spatter loss.