• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.3
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• pp.126-130
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• 2013

In this study, a shape-stabilized phase change material (SSPCM) was prepared by octadecane and exfoliated graphite nanoplate (xGnP) in a vacuum, to improve thermal storage performance. The octadecane as an organic phase change material (PCM) is very stable against phase separation of PCM, and has the proper temperature range for thermal comfort in the building; and the xGnP is a porous carbon nano-material. Scanning electron microscope (SEM) and Fourier transformation infrared spectrophotometer (FT-IR) were used to confirm the chemical and physical stability of the Ocatadecane/xGnP SSPCM. In addition, thermal properties were determined by Deferential scanning calorimeter (DSC), and Thermogravimetric analysis (TGA). The specific heat of Octadecane/xGnP SSPCM was $14.1J/g{\cdot}K$ at $31.3^{\circ}C$. The melting temperature ranges of melting and freezing were found to be $26{\sim}35^{\circ}C$ and $26{\sim}19^{\circ}C$, respectively. At this time, the latent heats of melting and freezing were 110.9 J/g and 104.5 J/g, respectively. The Octadecane was impregnated into xGnP by as much as about 56.0% of the Octadecane/xGnP SSPCM's mass fraction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.6
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• pp.247-256
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• 2014

The regulations to reduce energy consumption and carbon dioxide emission in building sectors are being developed and promoted all over the world. However, in Korea, as balcony extension of the apartments has been legally allowed, it became prevalent and resulted in excessive energy consumption. This study derived the possibility of PCM application to the thermal storage wall system through theoretical consideration and investigated the problems occurring when the balcony space has been extended to the diverted space. In addition, this study aims at the possibility of verifying the installation and confirming the cooling energy reduction effect, by conducting measuring tests with the actual installation of PCM applied thermal storage wall system. As a result of theoretical consideration, it is determined that the disadvantages with the existing thermal storage wall system can be complemented by applying PCM, and this study suggests the PCM applied Thermal Storage Wall System. The study was conducted on 1/6 of a miniature inner room of a domestic apartment with 84 $m^2$ of exclusive area. From the results of actual measurements, it is confirmed that the balcony extension structure can gain 11.3% of more calories than the existing balcony structure, resulting in the increase in cooling energy usage. It is determined that the installation of the PCM applied Thermal Storage Wall System may gain 25.2% of less calories to reduce cooling energy usage.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.158-164
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• 2004

In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during charging mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also energy stored inside the bed is computed. A comparison between refined model and non refined model is done. Finally using refined model the effect of bed material (Glass, Fine clay ,and aluminum ), and air flow rate per unit area Ga (0.3, 0.4, and 0.5 kg/$m^2$-s) on energy storage characteristics was studied.

• Transactions of the KSME C: Technology and Education
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• v.2 no.1
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• pp.65-72
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• 2014

The purpose of this study is to design a heat insulator for reducing available energy loss in stratified thermal storage tank. Heat insulator is operated by buoyancy effect from density difference between hot and cold water without extra equipment. Analysis model using the Matlab Simulink was developed to estimate the internal temperature distribution in thermal storage tank and also used to select proper material and thickness of the heat insulator. Operational feasibility was confirmed through reduced scale experiment. As a result, heat insulator can effectively delay the formation of thermal boundary layer between hot and cold water. In reduced scale experiment, heat insulator can preserve additional 1540J of available energy. When applied to the real thermal storage tank, increase of 6% thermal storage efficiency can be expected.

• Korean Chemical Engineering Research
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• v.56 no.4
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• pp.555-560
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• 2018

The high temperature stability of a chloride mixture, $NaCl-KCl-ZnCl_2$ (NaKZn-Chloride), is investigated to evaluate its potential as a thermal storage material. A thermal storage media should maintain a stable thermal properties within the temperature range of heat storage. Results from an a priori experiment showed that the NaKZn-chloride is stable only up the much lower temperature, while its stability limit is reported to be $850^{\circ}C$ in the literature. This study aims to investigate if the thermal property is changed by the moisture absorbed in the heat storage material. The effect of moisture content on the thermal properties was measured. The results show that the melting point remains the same regardless of the amount of moisture absorbed. Meanwhile, the high temperature stability is lower for the moisture treated samples. The results of this work infer that the loss of a hygroscopic thermal storage media can be reduced by avoiding its contacts to moisture in designing high temperature thermal storage systems.

• 한국태양에너지학회:학술대회논문집
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• 2011.04a
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• pp.162-167
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• 2011

Thermal storage plays an important role in building energy saving, which is greatly assisted by the incorporation of latent heat storage in building materials. A phase change material is a substance with a high heat of fusion which, melting and solidifying at a certain temperature, can be storing and releasing large amount of energy. Heat is stored or released when the material changes from solid to liquid. Integration of building materials incorporating PCMs into the building envelope can result in increased efficiency of the built environment. The aim of this research is to identify thermal performance of PCMs impregnated building materials which is applied to interior of building such as gypsum and red clay. In order to analyze thermal performance of phase change materials, test-cell experiments and simulation analysis were carried out. The results show that micro-encapsulated PCM has an effect to maintain a constant indoor temperature using latent heat through the test-cell experiments. PCM wallboard makes it possible to reduce the fluctuation of room temperature and heating and cooling load by using EnergyPlus simulation program. Phase change material can store solar energy directly in buildings. Increasing the heat capacity of a building is capable of improving human comfort by decreasing the frequency of indoor air temperature swings so that the interior air temperature is closer to the desired temperature for a long period of time.

• Progress in Superconductivity and Cryogenics
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• v.26 no.1
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• pp.20-24
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• 2024

Over the past four years, as the COVID-19 pandemic has struck the world, cold chain of COVID-19 vaccination has become a hot topic. In order to overcome the pandemic situation, it is necessary to establish a cold chain that maintains a low-temperature environment below approximately 203K (-70℃), which is the appropriate storage temperature for vaccines, from vaccine suppliers to local hospitals. Usually, cryocoolers are used to maintain low temperatures, but it is difficult for small-scale local distribution to have cryocooler due to budget and power supply issues. Accordingly, in this paper, a cryogenic TSU (Thermal storage unit) system for vaccination cold chain is designed that can maintain low temperatures below -70℃C for a long time without using a cryocooler. The performance of the TSU system according to the energy storage material for using as TSU is experimentally evaluated. In the experiments, four types of cold storage materials were used: 20% DMSO aqueous solution, 30% DMSO aqueous solution, paraffin wax, and tofu. Prior to the experiment, the specific heat of the cold storage materials at low temperature were measured. Through this, the thermal diffusivity of the materials was calculated, and paraffin wax had the lowest value. As a result of the TSU system's low-temperature maintenance test, paraffin wax showed the best low-temperature maintenance performance. And it recorded a low-temperature maintenance time that was about 24% longer than other materials. As a result of analyzing the temperature trend by location within the TSU system, it was observed that heat intrusion from the outside was not well transmitted to the low temperature area due to the low thermal conductivity of paraffin wax. Therefore, in the TSU system for vaccine storage, it was experimentally verified that the lower the thermal diffusivity of the cold storage material, the better low temperature maintenance performance.

• Nuclear Engineering and Technology
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• v.52 no.2
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• pp.248-257
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• 2020

This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MW_th. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO₂ TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

• Journal of the Korea Concrete Institute
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• v.28 no.4
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• pp.395-405
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• 2016

The thermal and mechanical properties of fiber-reinforced mortars for thermal energy storage were investigated in this paper. The effect of the combination of different cementitious composite on the thermal and mechanical characteristics of fiber-reinforced mortars was investigated. Experiments were performed to measure mechanical properties including compressive strength before and after thermal cycling and split tensile strength, and to measure thermal properties including thermal conductivity and specific heat. The results showed that the residual compressive strength of mixtures with OPC and graphite was greatest among the mixtures. Thermal conductivity of mixtures with alumina cement was greater than that of mixtures with OPC, indicating favor of alumina cement for charging and discharging in thermal energy storage system. The addition of zirconium into alumina cement increased specific heat of mixtures. Test results of this study could be used to provide information of material properties for thermal energy storage concrete.

• Journal of Biosystems Engineering
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• v.25 no.5
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• pp.379-384
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• 2000

In order to use the natural thermal energy as much as possible for greenhouse heating, the air-air heat pump system involved PCM(phase change material) latent heat storage system was composed, and three types of greenhouse heating system(greenhouse system, greenhouse-PCM latent heat storage system, greenhouse-PCM latent heat storage-heat pump system) were recomposed from the greenhouse heating units to analyze the heating characteristics. The results could be concluded as follows; 1) In the greenhouse heated by the heat pump under the solar radiation of 406.39W/$m^2$, the maximum PCM temperature in the latent heat storage system was 24$^{\circ}C$ and the accumulated thermal energy stored in PCM mass of 816kg during the daytime was 100,320kJ. In the greenhouse without heat pump under the maximum solar radiation of 452.83W/$m^2$, the maximum PCM temperature in the latent heat storage system was 22$^{\circ}C$ and the accumulated thermal energy stored during the daytime was 52.250kJ. 2) In the greenhouse-PCM system without heat pump the heat stored in soil layers from the surface to 30cm of the soil depth was 450㎉/$m^2$. 3) In all of the greenhouse heating systems, the difference between the air temperature in greenhouse and the ambient temperature was about 20~23$^{\circ}C$ in the daytime. In the greenhouse without heat pump and PCM latent heat storage system the difference between the ambient temperature and the air temperature in the greenhouse was about 6~7$^{\circ}C$ in the nighttime, in the greenhouse with only PCM latent heat storage system the temperature difference about 7~13$^{\circ}C$ in the nighttime and in the greenhouse with the heat pump and PCM latent heat storage system about 9~14$^{\circ}C$ in the nighttime.