• Journal of the Microelectronics and Packaging Society
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• v.10 no.3
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• pp.9-17
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• 2003

In this paper, thermo-mechanical and rheological properties of NCPs (Non-Conductive Pastes) depending on silica filler contents and diluent contents were investigated. And then, thermal cycling (T/C) reliability of flip chip assembly using selected NCPs was verified. As the silica filler content increased, thermo-mechanical properties of NCPs were changed. The higher the silica filler content was added, glass transition temperature ($T_g$) and storage modulus at room temperature became higher. While, coefficient of thermal expansion (CTE) decreased. On the other hand, rheological properties of NCPs were significantly affected by diluent content. As the diluent content increased, viscosity of NCP decreased and thixotropic index increased. However, the addition of diluent deteriorated thermo-mechanical properties such as modulus, CTE, and $T_g$. Based on these results, three candidates of NCPs with various silica filler and diluent contents were selected as adhesives for reliability test of flip chip assemblies. T/C reliability test was performed by measuring changes of NCP bump connection resistance. Results showed that flip chip assembly using NCP with lower CTE and higher modulus exhibited better T/C reliability behavior because of reduced shear strain in NCP adhesive layer.

• Journal of the Korean Society for Railway
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• v.8 no.2
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• pp.188-194
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• 2005

Aging characteristics of glass fabric/phenolic composites for tilting train subjected to combined environmental aging factors were investigated. A 2.5KW accelerated aging tester with a xenon-arc lamp was used to provide environmental aging factors such as temperature, moisture, and ultraviolet. A series of aging tests were conducted up to 3000 hours and several types of specimens were prepared along the warp direction and the fill direction. Mechanical degradations for tensile, flexural, and shear properties were evaluated as a function of exposure times through a material testing system. Thermal analysis properties such as storage shear modulus, loss shear modulus, and tan 3 were measured through a dynamic mechanical analyzer. Finally exposed surfaces of the composites were examined using a scanning electron microscope. According to the experimental results, mechanical properties and thermal analysis properties of glass fabric/phenolic composites were found to be slightly degraded as a function of exposure times due to combined environmental effects.

• Journal of Hydrogen and New Energy
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• v.26 no.4
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• pp.308-317
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• 2015

To investigate the effect of microstructure on the formation of the desorption peak, the volumetric thermal analysis technique (VTA) was applied to the Mg-13.5 wt% Ni hydride system. The sample made by the HCS (hydriding combustion synthesis) process had two kinds of Mg microstructures. Linear heating was started with various constant heating rates. Only one peak was appeared in the case of the small initial hydrogen wt% (0.83 wt%). Yet, two peaks were appeared with increasing initial hydrogen wt% (1.85 and 3.73 wt%) when only Mg was hydrogenated. The first peak was formed through the evolution of hydrogen from $MgH_2$, made by eutectic Mg. The second peak was formed through the evolution of hydrogen from $MgH_2$, made by primary Mg. Therefore, this result shows that the microstructure also has a considerable effect on forming the desorption peak. We have also derived the hydrogen desorption equations by VTA to get apparent activation energy when the rate-controlling step for the desorption of the hydrided system is the diffusion of hydrogen through the ${\alpha}$ phase and the chemical reaction ${\beta}{\rightarrow}{\alpha}$.

• Journal of the Korean Institute of Gas
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• v.18 no.1
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• pp.17-24
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• 2014

LNG storage tank is a facility to store liquefied natural gas (LNG) and its safety and stability to be greatly needed. When there is a LNG leakage in case of primary container problem, a special facility such as a bund wall should be constructed to store the leaked LNG. But this method makes the land usage inefficient and construction price high. So nowadays the full containment type LNG storage tank is selected instead of constructing a bund wall. In the full containment type tank, the concrete sidewall has the ability to store LNG temporarily. There are largely two methods to give the concrete sidewall the ability. In a method, rebar should be used when constructing the side wall of the LNG storage tank. In the other method, the protecting material such as sprayed polyurethane foam should be applied on the inner surface of the concrete sidewall. Sprayed PUF keeps the temperature of the sidewall above the specified temperature during the specified periods. Recently the thermal stability reinforcing method using sprayed polyurethane foam has been applied to all LNG storage tank built in Korea.

• Journal of the Korean Solar Energy Society
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• v.24 no.1
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• pp.7-12
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• 2004

Mixtures type PCM, $H_2O$-NaOH that has relatively large capacity of the latent heat and long duration of phase change temperature was developed and experimentally analyzed for the low temperature storage of the food and medical products. The results could be summarized as follows; 1. Borax as nucleating agent and acrylic polymer as thickening agent were added to $H_2O$ to prevent the supercooling and phase separation. 2. Phase change (solid$\leftrightarrows$liquid) duration of $H_2O$ added with NaOH was prolonged longer 50% than that of pure $H_2O$. 3. Phase change temperature of the latent heat material, $H_2O$-NaOH was $1.5\sim2^{\circ}C$ the maximum latent Heat was 279 kJ/kg at the NaOH addition of 1.3 wt.%. 4. The specific heat of $H_2O$-NaOH at the solid and liquid state was increased in proportion to the wt.% of NaOH, when NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the specific heat of the solid state was increased from 3.19 kJ/kg to 5.84 kJ/kg and that of liquid state from 7.8 kJ/kg to 10.28 kJ/kg. 5. When NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the total heat storage capacity composed of sensible and latent heat was $313\sim331.3$ kJ/kg and the maximum heat storage capacity was occurred at NaOH addition of 1.30 wt. %.

• Progress in Superconductivity and Cryogenics
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• v.16 no.1
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• pp.36-41
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• 2014

Since glass microsphere has high crush strength, low density and small particle size, it becomes alternative thermal insulation material for cryogenic systems, such as storage and transportation tank for cryogenic fluids. Although many experiments have been performed to verify the effective thermal conductivity of microsphere, prediction by calculation is still inaccurate due to the complicated geometries, including wide range of powder diameter distribution and different pore sizes. The accurate effective thermal conductivity model for microsphere is discussed in this paper. There are four mechanisms which contribute to the heat transfer of the evacuated powder: gaseous conduction ($k_g$), solid conduction ($k_s$), radiation ($k_r$) and thermal contact ($k_c$). Among these components, $k_g$ and $k_s$ were calculated by Zehner and Schlunder model (1970). Other component values for $k_c$ and $k_r$, which were obtained from experimental data under high vacuum conditions were added. In this research paper, the geometry of microsphere was simplified as a homogeneous solid sphere. The calculation results were compared with previous experimental data by R. Wawryk (1988), H. S. Kim (2010) and the experiment of this paper to show good agreement within error of 46%, 4.6% and 17 % for each result.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.391.2-391.2
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• 2014

Solution-processible hybrid bipolar field effect transistors (HBFETs) with balanced hole and electron mobilities were fabricated using a combination of the organic p-type poly (3-hexylthiophene) (P3HT) layer and inorganic n-type ZnO material. The hole and electron mobilities were first optimized in single layer devices by using acetonitrile as a solvent additive to process the P3HT and annealing to process the ZnO layer. The highest hole mobility of the P3HT-only-devices with 5% acetonitrile was 0.15 cm2V-1s-1, while the largest electron mobility was observed in the ZnO-only-devices annealed at $200^{\circ}C$ and found to be $7.2{\times}10-2cm2V-1s-1$. The inorganic-organic HBFETs consisting of P3HT with 5% acetonitrile and ZnO layer annealed at $200^{\circ}C$ exhibited balanced hole and electron mobilities of $4.0{\times}10-2$ and $3.9{\times}10-2cm2V-1s-1$, respectively. The effect on surface morphology and crystallinity by adding acetonitrile and thermal annealing were investigated through X-ray diffraction and atomic force microscopy (AFM). Our findings indicate that techniques demonstrated herein are of great utility in improving the performance of inorganic-organic hybrid devices

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.11a
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• pp.99-100
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• 2015

Significant amount of bottom ash has been produced in the power plant located at southeast region of Korea, but those were abandoned in the pond site without any treatment. In these days, there is a strong move to enforce environmental regulations to protect surrounding nature, a lot of pressure is given to the power plant industry to remove hazardous chemicals from their waste material before landfill or site storage. The overall objective of this research is to separate hazardous chemicals from the bottom ash, and use it safely as sustainable construction material. In this specific study, magnetic separation of bottom ash was applied, and used as a fine aggregates to make mortar specimens. According to the results, it was found that the use of bottom ash decreased 28-day compressive strength. However, using non-magnetic bottom ash provides best results in terms of thermal conductivity, showing strong possibility to be used as heat insulating material.

• Solar Energy
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• v.6 no.2
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• pp.43-53
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• 1986

The objective of this study is to report on the characterics of convective flow and heat transfer during metling process in order to provide design information for thermal energy storage systems which use phase change material. In present study, flow and heat transfer characteristics of the Phase Change Material in the Open Top Model (O.T.M) and in the Closed Top Model (C.T.M) were studied numerically by the control volume formulation using the algebraic non-orthogonal coordinate transformation. For the calculation procedure, the physical properties of fluid are assumed to be constant except density which is linely dependent on temperature in the bouyancy term of momentum equations. At start of melting process, the thickness of melting layer is assumed from the Stefan Problem assumption. The heat transfer results of Open Top Model and Closed Top Model are compared with the parameters of Grashof number and aspect ratio. It was found that heat transfer phenomena in melted region was greatly affected by buoyancy-driven natural convection and the melting distance of Open Top Model at the upper region is greater than that of Closed Top Model.

• Korea-Australia Rheology Journal
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• v.12 no.2
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• pp.101-105
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• 2000

The crystallization behavior of homo polypropylene (PP) and PP in the PP-poly($\varepsilon$-caprolactone) (PCL) blends during isothermal crystallization has been investigated using differential scanning calorimeter (DSC) and advanced rheometric expansion system (ARES). From the storage modulus data of the homo PP and PP-PCL blends during isothermal crystallization, the volume fraction of crystallized material ($X_t$) of the homo PP and PP in the PP-PCL blends was calculated using the various rheological models. The results of $X_t$ of the homo PP and PP in the PP-PCL blends from ARES measurement were compared with the results from DSC. The $X_t$ of the homo PP was found to be higher in the ARES measurement than in the DSC. The crystallization rate of the homo PP was found to be faster in the rheological measurements than in the thermal analysis. The $X_t$ of PP in the PP-PCL blends with various compositions was obtained from the thermal analysis and rheological measurements. The $X_t$ of PP in the PP-PCL blends obtained from the thermal analysis and rheological measurements are not consistent. This discrepancy of $X_t$ may be due to the morphological changes resulted from the different crystallization kinetics of PP in the PP-PCL blends.