• Title/Summary/Keyword: Thermal stabilities

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Antimicrobial Characteristic of Prunus mune extract (매실추출물의 항균특성)

  • Ha Myung-Hee;Park Woo-Po;Lee Seung-Cheol;Choi Sung-Gil;Cho Sung-Hwan
    • Food Science and Preservation
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    • v.13 no.2
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    • pp.198-203
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    • 2006
  • Prunus mume extract showed antimicrobial efface remarkably against the wide spectrum of putrefactive and food spoilage microorganisms above 250 ppm of concentration. Their thermal and pH stabilities were effective under the range of temperature $(40^{\circ}C{\sim}120^{\circ}C)$ and $pH(3{\sim}11)$. Prunus mume extract seemed to be a natural antimicrobial ideally with the view of their effectiveness and thermal & pH stabilities. In addition, their action modes suggested that their hydrophillic components would perturb the fucntions of microbial cell membranes synergistically.

Thermal and temporal stabilities of a electro-optic coefficient $\gamma_{33}$ in a PI-SOT nonlinear polymer thin film (고분자 박막인 PI-SOT의 전기광학계수 $\gamma_{33}$의 열적 . 시간적 안정성)

  • Jeong, Youn-Hong;Jo, Jae-Heung;Chang, Soo;Kim, Tae;lee, Kwang-Sup
    • Korean Journal of Optics and Photonics
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    • v.10 no.3
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    • pp.188-194
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    • 1999
  • We synthesized the nonlinear optical (NLO) PI-SOT(polyimide system, 4-[N,N-bis(hydroxyethyl)amino-4,-($\beta$-cyano-$\beta$-methylsulfonyl)vinyl]azobenzene) polymer with high electro-optic coefficients as well as good thermal and temporal stabilities of the elector-optic coefficient ${\gamma}_33$ by the simple Mitsunobu reaction. By using the simple reflection method of C. C. Teng, we measured the thermal and temporal stabilities of the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer at the wavelength of 632.8 nm and 852 nm, respectively. At the temperature of $20^{\circ}C$, the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer were 25.12 pm/V at the wavelength of 632.8 nm and 5.40 pm/V at the wavelength of 852 nm. These values were highly stabilized for more than 60 days at 2$0^{\circ}C$ and stabilized within 6% for more than 10 hours at $100^{\circ}C$.

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Liquid crystal aligning capabilities for vertical aligned NLC on the $CeO_x$ thin film layer with thermal evaporation

  • Han, Jin-Woo;Kim, Mi-Jung;Kim, Jong-Yeon;Han, Jeong-Min;Kim, Young-Hwan;Kim, Jong-Hwan;Kim, Byoung-Yong;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.371-371
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    • 2007
  • In this study, liquid crystal (LC) aligning capabilities for vertical alignment on the $CeO_x$ thin film by thermal evaporation method were investigated. Also, the control of pretilt angles and thermal stabilities of the NLC treated on $CeO_x$ thin film were investgated. The uniform LC alignment on the $CeO_x$ thin film surfaces and good thermal stabilities with thermal evaporation can be achieved. It is considerated that the LC alignment on the $CeO_x$ thin film by thermal evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $CeO_x$ thin film surface created by evaporation. In addition, it can be achieved the good electro-optical (EO) properties of the VA-LCD on $CeO_x$ thin film layer with oblique thermal evaporation.

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Effects of Dispersivity of Clay on Thermal Stabilities of PP/Clay Nanocomposites (점토의 분산성이 PP/점토 나노복합재료의 열안정성에 미치는 영향)

  • 박수진;전병렬;송시용;최길영;이종문
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.458-463
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    • 2003
  • The effect of ozone surface treatment of montmorillonite (MMT) was investigated in thermal stabilities of polypropylene (PP) nanocomposites. Sodium montmorillonite (Na$\^$+/-MMT) was organically modified with dodecylammonium chloride. The surface properties of MMT, including the specific surface area (S$\_$BET/), equilibrium spreading pressure ($\pi$$\_$e/), and London dispersive component (${\gamma}$s$\^$L/), were studied by the BET method with $N_2$ adsorption. Also, the thermal stabilities of the nanocomposites were investigated in DSC and TGA. As experimental results, $\pi$$\_$e/ and ${\gamma}$s$\^$L/ of the ozonized dodecylammonium chloride (DA-MK ( $O_3$)) were increased in about 1.7 and 3.5 mJ/ $m^2$, resulting from the increasing of the micropores. From the DSC results, it was found that the melting temperature and crystallization temperature of PP/DA-MK and PP/DA-MK ( $O_3$) were higher that those of pure PP. These results were explained that dodecylammonium chloride of nano-scale led to a nucleation effect for PP crystallization. Also, it was found that E$\_$t/ of the PP/DA-MK ( $O_3$) nanocomposies was increased within about 64 kJ/mol. These results were probably explained by the improvement of dispersivity of DA-MK ( $O_3$) in a PP matrix.

Homeotropic Alignment Effect of a Nematic Liquid Crystal on Oblique Deposited SiOx Thin-film with e-beam Evaporation

  • Choi, Dai-Seub
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.274-277
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    • 2007
  • In this study, liquid crystal(LC) aligning capabilities for homeotropic alignment on the $SiO_x$ thin film by electron beam evaporation method were investigated. Also, the control of pretilt angles and thermal stabilities of the nematic liquid crystal(NLC) treated on $SiO_x$ thin film were investigated. A high pretilt angle of about $86.5^{\circ}$ was obtained, and also the suitable pretilt angle of the NLC on the $SiO_x$ thin film at $10{\sim}50nm$ thickness with e-beam evaporation can be achieved. The uniform LC alignment and good thermal stabilities on the $SiO_x$ thin film surfaces with electron beam evaporation can be achieved. It is considered that the LC alignment on the $SiO_x$ thin film by electron beam evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $SiO_x$ thin film surface created by evaporation.

Aging of Length-Extensional Vibration Modes in PZT Ceramics (PZT 세라믹스에 있어서 길이진동모드의 경시변화)

  • 이개명;김병효;황충구;강찬호;현덕수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.10
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    • pp.858-864
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    • 2002
  • Aging stabilities of the operating frequency of piezoelectric devices such as filter, oscillator and discriminator are very important. In this study it was studied aging stabilities of the length-extensional vibration mode of Pb(Zr$\^$y/O$_3$+ x[wt%]Cr$_2$Co$_3$ ceramics. PZT ceramics in morphotropic phase boundary have higher aging rates of k$\_$31/ and resonance frequency than those in tetragonal phase or rhombohedral phase. Thermal aging moves the composition with maximum aging rate to Zr-rich side in Cr$_2$O$_3$ not added PZT system. In the PZT system, aging rates of k$\_$31/ and resonance frequency for first 30 days are bigger than those for the following 90 days. Thermal aging decrease those for first 30 days. Aging rate of resonance frequency of the ceramics with x=0.1, y=0.53 and x=0.3, y=0.53 increased by thermal aging.

Asn124 of Cel5A from Hypocrea jecorina not only provides the N-glycosylation site but is also essential in maintaining enzymatic activity

  • Qin, Yuqi;Qu, Yinbo
    • BMB Reports
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    • v.47 no.5
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    • pp.256-261
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    • 2014
  • To investigate the function of N-glycosylation of Cel5A (endoglucanase II) from Hypocrea jecorina, two N-glycosylation site deletion Cel5A mutants (rN124D and rN124H) were expressed in Saccharomyces cerevisiae. The weights of these recombinant mutants were 54 kDa, which were lower than that of rCel5A. This result was expected to be attributed to deglycosylation. The enzyme activity of rN124H was greatly reduced to 60.6% compared with rCel5A, whereas rN124D showed slightly lower activity (10%) than that of rCel5A. rN124D and rN124H showed different thermal stabilities compared with the glycosylated rCel5A, especially at lower pH value. Thermal stabilities were reduced and improved for rN124D and rN124H, respectively. Circular dichroism spectroscopy showed that the modification of secondary structure by mutation may be the reason for the change in enzymatic activity and thermal stability.

Synthesis of Polyurethane Nanocomposite Filled Inorganic Particles and Their Properties (무기입자를 충전한 폴리우레탄 나노복합체의 합성 및 물성)

  • Son, Bok-Gi;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.379-384
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    • 2007
  • The nanocomposites with inorganic nano powder, improved thermal stability, were prepared by urethane polymerization. The structure and surface properties of the nanocomposites were determined by X-ray diffraction and FT-IR, respectively. The thermal stabilities were studied using TGA and DSC. Their morphologies and mechanical properties were observed by SEM and UTM. As a result, the nanocomposites with MMT led to the increase of the silicate layers. The distance between layers of the nanacomposites with MMT was increased by $7.5{\AA}$ and the new peaks at $1038cm^{-1}$ were shown in the presence of the Si-O groups on the silica. The thermal stabilities of the nanocomposites were higher than those of pore polyurethane matrix. The nanocomposites had higher in mechanical properties than the pure polyurethane matrix.

Liquid Crystal Aligning Capabilities for Nematic Liquid Crystal on the ZrOx Thin Film Layer with E-beam Evaporation

  • Kim, Mi-Jung;Han, Jin-Woo;Kim, Young-Hwan;Kim, Byoung-Yong;Han, Jeong-Min;Moon, Hyun-Chan;Park, Kwang-Bum;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.378-378
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    • 2007
  • In this study, liquid crystal (LC) aligning capabilities for homeotropic alignment on the $ZrO_x$ thin film by electron beam evaporation method were investigated. Also, the control of pretilt angles and thermal stabilities of the NLC treated on $ZrO_x$ thin film were investigated. The uniform LC alignment on the $ZrO_x$ thin film surfaces and good thermal stabilities with electron beam evaporation can be achieved. It is considerated that the LC alignment on the $ZrO_x$ thin film by electron beam evaporation is attributed to elastic interaction between LC molecules and micro-grooves at the $ZrO_x$ thin film surface created by evaporation. In addition, it can be achieved the good electro-optical (EO) properties of the VA-LCD on $ZrO_x$ thin film layer with. oblique electron beam evaporation.

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Static/Dynamic/Thermal Characteristics Analysis of a High-Speed Spindle System with 50,000rpm (50,000rpm급 초고속 주축계의 정적/동적/열적 특성 해석)

  • 김석일;조재완;이원재;이용희
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.494-499
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    • 2003
  • This paper concerns the static, dynamic and thermal characteristics analysis of a high-speed spindle system for horizontal machining centers with 45mm x50,000rpm. The spindle system is designed based on the angular contact ceramic ball bearings, built-in motor, oil-air lubrication method and oil jacket cooling method. The structural and thermal analysis models of spindle system are constructed by the finite element method. The static and dynamic characteristics are estimated based on the static deformation, modal parameter, mode shape and frequency response function, and the thermal characteristics are estimated based on the temperature rise, temperature distribution and thermal deformation. The analysis results illustrate that the designed spindle system has excellent structural and thermal stabilities

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