• Title/Summary/Keyword: Thermal spray process

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Screening of Spray-Dried K2CO3-Based Solid Sorbents using Various Support Materials for CO2 Capture

  • Eom, Tae Hyoung;Lee, Joong Beom;Baek, Jeom In;Ryub, Chong Kul;Rhee, Young Woo
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.115-120
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    • 2015
  • $K_2CO_3$-based dry regenerable sorbents were prepared by spray-drying techniques to improve mass produced $K_2CO_3-Al_2O_3$ sorbents (KEP-CO2P, hereafter), and then tested for their $CO_2$ sorption capacity by a $2,000Nm^3/h$ (0.5 MWe) $CO_2$ capture pilot plant built for Unit 3 of the Hadong thermal power station in 2010. Each of the sample sorbents contained 35 wt.% $K_2CO_3$ as the active materials with various support materials such as $TiO_2$, MgO, Zeolite 13X, $Al_2O_3$, $SiO_2$ and hydrotalcite (HTC). Their physical properties and reactivity were tested to evaluate their applicability to a fluidized-bed or fast transport-bed $CO_2$ capture process. The $CO_2$ sorption capacity and percentage utilization of $K_2CO_3$-MgO based sorbent, Sorb-KM2, was $8.6g-CO_2/100g$-sorbents and 90%, respectively, along with good mechanical strength for fluidized-bed application. Sorbs-KM2 and KT were almost completely regenerated at $140^{\circ}C$. No degradation of Sorb-KM by $SO_2$ added as a pollutant in flue gas was observed during a cycle test.

Friction, Wear and Adhesion of HVOF Coating of Co-alloy Powder

  • Cho, Tong-Yul;Yoon, Jae-Hong;Song, Ki-Oh;Joo, Yun-Kon;Fang, Wei;Zhang, Shihong;Youn, Suk-Jo;Chun, Hui-Gon;Hwang, Soon-Young
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.61-62
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    • 2007
  • HVOF thermal spray coating of micron size Co-alloy powder has been studied for the durability improvement of high velocity spindle (HVS). Optimal coating process of this system for the best surface properties is hydrogen flow rate 75 FMR, oxygen flow rate 38-42 FMR, feed rate 30 g/min at spray distance 5 inch. Friction coefficient (FC) and wear trace (WT) decrease increasing coating surface temperature from 25$^{\circ}$C to 538$^{\circ}$C due to the higher lubricant effects of the oxides at the higher temperature. At the study of adhesion of T800 coating on a light metal alloy Ti-6Al-4V (Ti64) tensile bond strength (TBS) and tensile fracture location (TFL) of Ti64/T800 are 8,740 psi and near middle of T800 coating respectively. This shows that adhesion of Ti64/T800 is higher than the cohesion strength (8,740 psi) of T800 coating. Therefore T800 coating is strongly advisable for the surface coating on HVS such as high speed air-bearing spindle.

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Spin Spray-Deposited Spinel Thin Films for Microbolometer Applications (마이크로볼로미터 응용을 위한 스핀 스프레이로 증착된 스피넬 박막)

  • Jeon, Chang Jun;Lee, Kui Woong;Le, Duc Thang;Jeong, Young Hun;Yun, Ji Sun;Paik, Jong Hoo;Cho, Jeong Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.809-814
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    • 2014
  • Spinel thin films were prepared by the spin spray technique to develop new thermal imaging materials annealed at low temperature for uncooled microbolometer applications. The spinel thin films were deposited from $[(Ni_{0.30}Co_{0.33}Mn_{0.37})_{1-x}Cu_x]_3O_4$ ($0.1{\leq}x{\leq}0.2$) solutions and then annealed at $400^{\circ}C$ for 1 h in argon. Effects of Cu content (x) and deposition time on the electrical properties of the annealed films were investigated. With increasing deposition time, the resistivity of the annealed films increased. For the annealed films deposited for 1 min, the resistivity of x=0.15 films was lower than that of x=0.1 films due to the different grain sizes. The high temperature coefficient of resistance (TCR) of the annealed films could be obtained at temperature below $50^{\circ}C$. Typically, the resistivity of $127{\Omega}{\cdot}cm$ and TCR of -5.69%/K at $30^{\circ}C$ were obtained for x=0.1 films with deposition time of 1 min annealed at $400^{\circ}C$ for 1 h in argon.

Finite Element Analysis of Hot Strip Rolling Process (열간박판압연공정의 유한요소해석)

  • 강윤호;황상무
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.5
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    • pp.829-837
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    • 1992
  • This paper presents a new approach for the analysis of hot strip rolling processes. The approach is based on the finite element method and capable of predicting velocity field in the strip, temperature field in the strip, temperature field in the roll, and roll pressure. Basic finite element formulations for heat transfer analysis are described with emphasis on the treatment of numerical instability resulting from a standard Galerkin formulation. Comparison with the theoretical solutions found in the literature is made for the evaluation of the accuracy of the temperature solutions. An iterative scheme is developed for dealing with strong correlations between the metal flow characteristics and the thermal behavior of the roll-strip system. A series of process simulations are carried out to investigate the effect of various process parameters including interface friction, interface heat transfer coefficient, roll speed, reduction in thickness, and spray zone. The results are shown and discussed.

Selection of Artificial Sand Suitable for Manufacturing Steel Castings through Evaluation of Various Foundry Sand Properties (각종 주물사의 특성과 주강품 주조에 적합한 인공사 선택)

  • Gwang-Sik Kim;Jae-Hyung Kim;Myeong-Jun Kim;Ji-Tae Kim;Ki-Myoung Kwon;Sung-Gyu Kim
    • Journal of Korea Foundry Society
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    • v.43 no.3
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    • pp.107-136
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    • 2023
  • Natural silica sand was commonly used for sand casting of cast steel products, and chromites sand was used to suppress seizure defects due to the lack of thermal properties of silica sand. However there are disadvantages such as deterioration by repeated use, system sand mixing problem, difficulty separating and removing, increased during mold according to high density and to being waste containing chrome. Recently, industrial waste reduction and atmospheric environment improvement have been highlighted as important tasks in the casting industry. In order to solve the problems that occur when using foundry Sand and to improve the environment of casting factories, various artificial sands that can be applied instead of natural silica sand have been developed and introduced. Artificial sands can be classified into artificial sand manufactured by the electric arc atomization or gas flame atomization, artificial sand manufactured by the spray drying & sintering process, artificial sand manufactured by the sintering & crushing process and exhibit different physical properties depending on the type of raw-minerals and manufacturing method. In this study, comparative evaluation tests were conducted on the physical properties of various foundry sands, mold strength, physical durability, thermal durability, and casting test pieces. When comprehensively considering the actual amount of molding sand used according to density, the mold strength according to the shape of sand, the physical and thermal durability of foundry sand, and the heat resistance characteristics of foundry sand, 'Molten artificial sand A1' or 'Molten artificial sand B' is judged to be the most suitable spherical artificial sand for casting of heavy steel castings.

The Effect of Far Infrared Radiation of $\beta$-Spodumene Glass-Ceramics Flims Coated on Iron Substrate by Sol-Gel Technique (졸-겔법에 의한 금속기판상의 $\beta$-spodumene 결정성유리의 박영도포와 원적외선상세성)

  • 양중식;신현택;박종옥
    • Journal of the Korean institute of surface engineering
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    • v.27 no.2
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    • pp.99-108
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    • 1994
  • Films of glass-ceramics $Li_2O-Al_2O_3-SiO_2$(LAS)system were prepared on substrate of an iron plate(SCP) by sol-gel technique using metal alkoxide such as Si$(OC_2H_5)_4$,Al$(OC_2H_9)_3$) and Ti$(OC_2H_6)_4$). Sol which was made by means of simple spray coating, on the substrate was hydrolyzed at 75~$80^{\circ}C$ in moisture cabinet (80~90 % humidity) to form the multicomponent gel. The films up to about 0.8~1.0$mu extrm{m}$ in thickness can be obtained by repeating operation, spraylongrightarrowhydrolysis and condensationlongrightarrowdryinglongrightarrowheating and crystallization at $700^{\circ}C$ for 3~5min. The far-infrared radiation spectra of the coated films on substrate were examined by FT-IR and of films was also observed by scanning electron micrograph technique. The thermal evaluation of the gel-film is followed by TG/DTA measurements. The structure evaluation is followedd X-ray diffraction. These results suggest that this process is applicable to far-infrared radiat at thin film technique.

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Effect of Heat Treatment Conditions on the Microstructure and Wear Behavior of Ni-based Self-flux Alloy Coatings (니켈기 자융성 합금 코팅층의 미세구조 및 마모거동에 미치는 후열처리 조건의 영향)

  • Kim, K.T.;Oh, M.S.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.11 no.1
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    • pp.121-126
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    • 2007
  • This study aims at investigating the effect of heat treatment conditions on the dry sliding wear behavior of thermally sprayed Ni-based self-flux alloy coatings. Ni-based self-flux alloy powders were sprayed onto a carbon steel substrate and then heat-treated at 700, 800, 900 and $1000^{\circ}C$ for 30 minutes in a vacuum furnace. Dry sliding wear tests were performed using sliding speed of 0.4 m/s and applied load of 6 N. AISI 52100 ball(diameter 8 mm) was used as counterparts. Microstructure and wear behavior of both as-sprayed and heat-treated Ni-based self-flux alloy coatings were studied using a scanning electron microscope(SEM), energy dispersive X-ray spectroscopy(EDX), electron probe micro-analysis(EPMA) and X-ray diffraction(XRD). It was revealed that microstructure and wear behavior of thermally sprayed Ni-based self-flux alloy coatings were much influenced by heat treatment conditions.

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Effects of Counterpart Materials on Wear Behavior of Thermally Sprayed STS316 Coatings (STS316 용사코팅층의 마모거동에 미치는 상대마모재의 영향)

  • Lee, Jae-Hong;Kim, Yeong-Sik
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.58-63
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    • 2014
  • This paper deals with the effects of counterpart materials on the wear behavior of thermally sprayed STS316 coatings. STS316 powders were flame-sprayed onto a carbon steel substrate. Dry sliding wear tests were performed using the applied loads of 15 N. AISI52100, $Al_2O_3$, $ZrO_2$ and $Si_3N_4$ balls were used as counterpart materials. Wear behavior of STS316 coatings against different counterpart materials were studied using a scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS). The results show that the wear behavior of thermally sprayed STS316 coatings strongly depends on the type of counterpart material. Dominant wear mechanism was similar for all studied materials as failure of adhesion film except for Si3N4 used as counterpart material. In the case of Si3N4 used as counterpart material, dominant wear mechanism was abrasion.

Numerical analysis on in-core ignition and subsequent flame propagation to containment in OPR1000 under loss of coolant accident

  • Song, Chang Hyun;Bae, Joon Young;Kim, Sung Joong
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2960-2973
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    • 2022
  • Since Fukushima nuclear power plant (NPP) accident in 2011, the importance of research on various severe accident phenomena has been emphasized. Particularly, detailed analysis of combustion risk is necessary following the containment damage caused by combustion in the Fukushima accident. Many studies have been conducted to evaluate the risk of local hydrogen concentration increases and flame propagation using computational code. In particular, the potential for combustion by local hydrogen concentration in specific areas within the containment has been emphasized. In this study, the process of flame propagation generated inside a reactor core to containment during a loss of coolant accident (LOCA) was analyzed using MELCOR 2.1 code. Later in the LOCA scenario, it was expected that hydrogen combustion occurred inside the reactor core owing to oxygen inflow through the cold leg break area. The main driving force of the oxygen intrusion is the elevated containment pressure due to the molten corium-concrete interaction. The thermal and mechanical loads caused by the flame threaten the integrity of the containment. Additionally, the containment spray system effectiveness in this situation was evaluated because changes in pressure gradient and concentrations of flammable gases greatly affect the overall behavior of ignition and subsequent containment integrity.

Heat-treatment of Diffusional Behaviors of Plasma Spray Coated Layer for Fabrication of Abrasive Plates for Diamond (다이아몬드 가공을 위한 연마판의 제조 및 플라즈마 용사 코팅층의 열처리 거동)

  • Choi, Kwangsu;Yang, Seunga;Lee, Jong wan;Kim, Minkyu;Lee, Seong jun;Park, Joon Sik
    • Journal of the Korean Society for Heat Treatment
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    • v.30 no.6
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    • pp.264-270
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    • 2017
  • In this study, while the abrasive plates for diamond have been prepared through mechanical alloying and sintering of elemental powders, a fabrication route of plasma thermal coatings has been adopted for the first time. When diamond knife is sharped or polished, a metal plate has been applied, which is made of mechanical alloying and sintering. In this study, in order to develop a cost - effective manufacturing process, plasma coatings of FeCrNi and Ti on cast iron plate were applied together with Al intermediate layer coatings. The plasma coatings were successfully performed, and the optimum coating layer conditions were discussed in terms of micro-structural observations at the interfaces.