• Fire Science and Engineering
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• v.13 no.4
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• pp.7-12
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• 1999

Thermal properties of EVA dust and its risks of coexisting with oxidizer were investigated by a pressure vessel. The decomposition of EVA dust with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of EVA dust. Using the pressure vessel which can estimate ignition and explosion of EVA dust coexisting with oxidizer by bursting of a rupture disc, many experiments have been conducted by varying the orifice diameter, heating rate, the weight ratio of the sample coexisting with oxidizer, and the species of oxidizer. According to the results of the thermal analysis of EVA dust, a little change of the decomposition initiation temperature with the heating rate could be found and the decomposition temperature zone of EVA dust was 250 to 50$0^{\circ}C$. The risk of EVA dust coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the heating rate and the weight ratio of the sample coexisting with oxidizer were increased. In addition, the risk of EVA dust coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer, respectively, at slow heating rate, but it was affected by the oxygen weight percent of oxidizer at fast heating rate.

• Journal of the Korean Institute of Gas
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• v.11 no.4
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• pp.7-11
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• 2007

There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.136-140
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• 2006

We are developing a vol-oxidizer which transforms the spent $UO_2$ pellets into the $U_3O_8$ power through oxidizing process. The vol-oxidizer consists of furnace, filter, heater and valve etc. When the filter is blocked by the powder, the internal pressure of the furnace is increased owing to the air flow restriction. Then, the furnace vessel is swelled and deformed by it. In this paper, we proposed a procedure of the thermal analysis for furnace vessel design of spent fuel vol-oxidizer. In this work, we determined the thickness of the furnace through analyzing the internal pressure and the thermal stress of the furnace with respect to various pressure and temperature. To analyze the thermal stress, we used ANSYS 8.0 for constructing a FEM model of the furnace, and then analyzed it based on the ASME code. We also surveyed the material property and yield stress of SUS304 with various temperature. Analysis results are compared with the yield stress of the material. We manufactured the furnace and conduct the verification experiments.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.4
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• pp.371-381
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• 2004

Numerical simulation of $CO_2$ addition effects to fuel and oxidizer streams on flame structure has been conducted with detailed chemistry in H$_2$-O$_2$ diffusion flames of a counterflow configuration. An artificial species, which displaces added $CO_2$ in the fuel- and oxidizer-sides and has the same thermochemical, transport, and radiation properties to that of added $CO_2$, is introduced to extract pure chemical effects in flame structure. Chemical effects due to thermal dissociation of added $CO_2$ causes the reduction flame temperature in addition to some thermal effects. The reason why flame temperature due to chemical effects is larger in cases of $CO_2$ addition to oxidizer stream is well explained though a defined characteristic strain rate. The produced CO is responsible for the reaction, $CO_2$＋H=CO＋OH and takes its origin from chemical effects due to thermal dissociation. It is also found that the behavior of produced CO mole fraction is closely related to added $CO_2$ mole fraction, maximum H mole fraction and its position, and maximum flame temperature and its position.

• Fire Science and Engineering
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• v.15 no.1
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• pp.16-22
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• 2001

Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

• Progress in Superconductivity and Cryogenics
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• v.22 no.4
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• pp.51-56
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• 2020

In order to increase thrust of the space launch vehicle, liquid oxygen as an oxidizer and kerosene or liquid hydrogen as a fuel are generally used. The oxidizer tank and fuel tanks are manufactured by composite materials such as CFRP (Carbon Fiber Reinforced Plastic) to increase pay load. The thermal stress of the cryogenic propellant tank should be considered because it has large temperature gradient. In this study, to confirm the design integrity of the oxidizer tank of liquid oxygen, a numerical analysis was conducted on the thermal stress and temperature distribution of the tank for various charging speed of the cryogenic fluid from 100 ~ 900 LPM taking into account the evaporation rate of the liquid nitrogen by convective heat transfer outside the tank and boiling heat transfer inside the tank. The thermal stress was also calculated coupled with the temperature distribution of the CFRP tank. Based on the analysis results, the charging speed of the LN2 can majorly affects the charging time and the resultant thermal stress.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.273-277
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• 2009

An oxidizer tunnel-type pipe, which shall transport oxidizer from an oxidizer tank to a turbo-pump of an engine, studied is installed through a fuel tank located under an oxidizer tank. A tunnel-type pipe can save weight compared to a detour-type pipe, however may vary the temperature of fuel stored in a fuel tank because of a broad heat transfer area. Hence in this study the characteristics of main oxidizer pipe and thermal propagation from oxidizer to a fuel tank are monitored by a cryogenic performance test with a tunnel-type pipe. In addition, the possibility of adaptation of an oxidizer tunnel-type pipe to launcher system is also analyzed.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.220.1-220.1
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• 2005

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.63-68
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• 2006

Effects of oxidizer inlet velocity on NO emission characteristics of 0.2MW oxy-fuel combustor have been experimentally investigated. The NO formation process in the oxy-fuel combustion is extremely sensitive even for the small fraction of nitrogen in oxidizer. By increasing the oxidizer velocity, flame length is reduced due to the enhanced turbulent mixing. The increased oxidizer velocity also results in the decreased flame temperature through the elevated entrainment rate of the recirculated product and the corresponding NO emission is drastically decreased. Experimental results clearly indicate that the entrained product gases play a crucial role to decrease the temperature at the flame zone and the post flame zone where the thermal NO is mainly formed.

• Journal of the Korean Society of Propulsion Engineers
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• v.12 no.4
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• pp.33-41
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• 2008

The prelaunch thermal transients in the cryogenic oxidizer tank of liquid propulsion rocket subjected to uniform heat flux from outside are numerically analyzed through thermodynamic equations and heat and mass transfer relations. The prelaunch stage is assumed to be composed of five idealized sub-stages including pressurization process by helium gas injection. The Peng-Robinson equation of state is utilized in the lumped analysis of ullage gas. The liquid region is divided into a number of horizontal layers of uniform properties to account for the thermal stratification. The computational result for the typical case shows that the temperature rise of liquid oxidizer is less than 1K and the adsorbed helium into the liquid is approximately 10g.