• 제목/요약/키워드: Thermal mechanism

검색결과 1,234건 처리시간 0.031초

강황지하부 부산물에서 분리한 Quercetin-3-O-${\beta}$-D-glucopyranoside-7-O-${\alpha}$-L-rhamnopyranoside가 선충의 수명연장에 미치는 영향 (Lifespan Extension Property of Quercetin-3-O-${\beta}$-D-glucopyranoside-7-O-${\alpha}$-L-rhamnopyranoside from Curcuma longa L. In Caenorhabditis elegans)

  • 안달래;이은별;김반지;이소연;안민실;은재순;신태용;김대근
    • 생약학회지
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    • 제45권4호
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    • pp.275-281
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    • 2014
  • After harvesting the medicinal parts of Curcuma longa, the remaining underground parts were discarded. From the remaining underground parts of Curcuma longa quercetin-3-O-${\beta}$-D-glucopyranoside-7-O-${\alpha}$-L-rhamnopyranoside (Q37) was isolated. The antioxidant activities in vitro and lifespan-extension effect of Q37 were elucidated using the Caenorhabditis elegans. The 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging effect of Q37 showed similar potent activities in comparison with vitamin C. Q37 also showed potent superoxide quenching activities as measured by the riboflavin- and xanthine-originated superoxide quenching activity tests. Q37 prolonged lifespan of worms under normal culture condition. In terms of protective effect of Q37 on the stress conditions such as thermal and oxidative stresses, Q37-treated worms exhibited enhanced survival rate, as compared to control worms. To know the possible mechanism of Q37-mediated increased lifespan and stress resistance of worms, we examined the activities of Q37on superoxide dismutase (SOD), and invested intracellular reactive oxygen species (ROS) levels. The results revealed that Q37 was able to elevate SOD activity of worms and reduce intracellular ROS accumulation in a dose-dependent manner.

리늄판의 미세경도 온도 및 응력의존성 (Temperature and Dependence of the Microhardness of Rhenium Sheets)

  • 윤석영
    • 한국재료학회지
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    • 제10권5호
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    • pp.335-342
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    • 2000
  • 리늄판의 미세경도를 압흔 하중 및 온도의 함수로 구하였다. 미세경도의 온도의존성은 상온에서 100$0^{\circ}C$까지의 범위에서 Vickers 압흔기가 내장된 고온 미세압흔기를 이용하여 연구되었다. 미세경도의 하중의존성은 Vickers와 Knoop 압흔기를 이용하여 검토되었다. 압흔 크기 영향은 표준화된 Meyers법칙에 위해 충분히 설명 되었다. 압흔도중 압흔기 아래에서의 가공경화 때문에 어닐링된 리늄판 경도값은 높은 압흔 하중에서 압련되 리늄판의 경도값에 접근하였다. 경도의 하중의존성으로부터 외삽하여 얻어진 하중 영에서의 경도값은 경도값이 다른 열활성을 나타내는 두 개의 다른 기구에 의해 제어됨을 제시하였다. 낮은 온도에서 활성화에너지는 0.02eV 였으며, 한편 높은 온도에서 활성화에너지는 0.15eV 였다. 이때 전이온도는 대략 $250^{\circ}C$ 이었다.

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Formation and Photoluminescence of Silicon Oxide Nanowires by Thermal Treatment of Nickel Nanoparticles Deposited on the Silicon Wafer

  • 장선희;이영일;김동훈
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.27.1-27.1
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    • 2011
  • The recent extensive research of one-dimensional (1D) nanostructures such as nanowires (NWs) and nanotubes (NTs) has been the driving force to fabricate new kinds of nanoscale devices in electronics, optics and bioengineering. We attempt to produce silicon oxide nanowires (SiOxNWs) in a simple way without complicate deposition process, gaseous Si containing precursors, or starting material of $SiO_2$. Nickel (Ni) nanoparticles (NPs) were applied on Si wafer and thermally treated in a furnace. The temperature in the furnace was kept in the ranges between 900 and $1,100^{\circ}C$ and a mixture of nitrogen ($N_2$) and hydrogen ($H_2$) flowed through the furnace. The SiOxNWs had widths ranging from 100 to 200 nm with length extending up to ~10 ${\mu}m$ and their structure was amorphous. Ni NPs were acted as catalysts. Since there were no other Si materials introduced into the furnace, the Si wafer was the only Si sources for the growth of SiOxNWs. When the Si wafer with deposition of Ni NPs was heated, the liquid Ni-Si alloy droplets were formed. The droplets as the nucleation sites induce an initiation of the growth of SiOxNWs and absorb oxygen easily. As the droplets became supersaturated, the SiOxNWs were grown, by the reaction between Si and O and continuously dissolving Si and O onto NPs. Photoluminescence (PL) showed that blue emission spectrum was centered at the wavelength of 450 nm (2.76 eV). The details of growth mechanism of SiOxNWs and the effect of Ni NPs on the formation of SiOxNWs will be presented.

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Mechanism for Ni/YSZ Nano-composite Anode from Spherical Core-shell Formation

  • 안용태;최병현;지미정;구자빈;황해진
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.31.2-31.2
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    • 2011
  • We studied a method of manufacturing an anode to restrict contraction in reducing NiO/YSZ by uniformly mixing. In order to mix Ni and YSZ, a sub-micron Ni core surface was coated at high-speed by a mixture of nano-sized YSZ and a spherical core-shell was subsequently formed. The micron-sized core-shell anode powder was then heat treated at $400{\sim}1,450^{\circ}C$ in an air atmosphere and Ni was extruded and synthesized in nano-size. Subsequently, when the nano-sized mixture of the anode was heat treated and maintained at a temperature of $1,450^{\circ}C$, the anode was manufactured, where Ni and YSZ were uniformly distributed with the nano-structure. According to the nano-sized anode powder synthesis process, Ni particles were oxidized at $400{\sim}500^{\circ}C$ and became spherical by surface tension. In the case of the spherical core Ni powder, the heat treatment temperature rose to $1,250^{\circ}C$ and then a gap between the internal and external pressures occurred due to thermal and tensile stresses. A crack subsequently appeared on the surface, and the heat treatment temperature was increased continuously to increase the pressure gap and then the core Ni extruded as a nano-sized powder, Ni and YSZ uniformly distributed. It was found that the anode of 50~200 nm with a consistent structure obtained in this study has electric conductivity that is approximately 3 times larger than that of a commercial anode.

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A Study on the Torsional Vibration Characteristics of Super Large Two Stroke Low Speed Engines with Tuning Damper

  • Barro Ronald D;Kim Sang-Hwan;Lee Don-Chool
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 추계학술대회논문집
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    • pp.776-785
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    • 2006
  • Ship builder's requirement for a higher power output rating has lead to the development of super large two stroke low speed diesel engines. Usually a large-sized bore ranging from 8-14 cylinders, this engine group is capable of delivering power output of more than 100,000 bhp at maximum continuous rating. Other positive aspects of this engine type include higher thermal efficiency, reliability, durability and mobility. This all playa vital role in meeting the propulsion requirement of vessels, specifically for large container ships, of which speed is a primary concern to become more competitive. Consequently, this also resulted in the modification of engine parameters and new component designs to meet the consequential higher mean effective pressure and higher maximum combustion pressure. Even though the fundamental excitation mechanism unchanged, torsional vibration stresses in the propulsion shafting are subsequently perceived to be higher. As such, one important viewpoint in the initial engine design is the resulting vibration characteristic expected to prevail on the propulsion shafting system(PSS). This paper investigated the torsional vibration characteristics of these super large engines. For the two node torsional vibration with a nodal point on the crankshaft, a tuning damper is necessary to reduce the torsional stresses on the crankshaft. Hence, the tuning torsional vibration damper design and compatibility to the shafting system was similarly reviewed and analyzed.

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가속수명시험(ALT)을 이용한 WOLED의 성능 및 신뢰성 평가 (Evaluation of Performance and Reliability of a White Organic Light-Emitting Diode(WOLED) Using an Accelerated Life Test(ALT))

  • 문진철;박형기;최충석
    • 한국안전학회지
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    • 제27권4호
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    • pp.13-19
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    • 2012
  • The purpose of this study is to extract the major factors related to the deterioration mechanism of white organic light-emitting diodes(WOLED) by performing accelerated testing of temperature, voltage, time, etc., and to develop an accelerated life test(ALT) model. The measurement results of the brightness of the WOLED exhibited that their average brightness tended to increase as the operating voltage increased and that the half-life period of the brightness appeared after approximately 400 hours when the operating voltage was 20V and the ambient temperature was $85^{\circ}C$. It could be seen that although the WOLED showed comparatively the same brightness when the initial acceleration began after the operating voltage was applied to it, its brightness changed excessively after the WOLED's thermal storage had been made. In addition, it was observed that the half-life period was reduced as the ambient temperature and applied voltage increased. The strength of the WOLED which had been maintained in the range of visible light at the maximum load was reduced by the deterioration of the organic light emitting material due to the influence of the operating voltage and temperature, and the reduction of emitted light was small at low voltage and temperature. It could be seen that the failure of the WOLED during the ALT was caused by wear due to load accumulation over time, and that Weibull distribution was appropriate for the life distribution and acceleration was established between test conditions. From the WOLED analysis, it is thought that factors influencing the brightness deterioration are voltage, temperature, etc., and that comprehensive analysis considering discharge control, dielectric tangent margin, etc., would further increase the reliability.

얇은 수직 사각유로에서의 포화비등조건 임계열유속 예측 (Prediction of Critical Heat Flux for Saturated Flow Boiling Water in Vertical Narrow Rectangular Channels)

  • 최길식;장순흥;정용훈
    • 대한기계학회논문집B
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    • 제39권12호
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    • pp.953-963
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    • 2015
  • 산업적으로 얇은 사각유로에서의 임계열유속을 포함한 열수력 현상을 이해하고 이를 시스템 설계에 반영해야 될 필요성이 증대되고 있다. 포화비등조건에서 임계열유속이 발생하는 주요기구는 일반적으로 환상유동 영역에서 액막이 건조되는 것이다. 이러한 임계열유속을 예측하기 위하여 원형관에 대한 대표적인 액막건조모델을 고찰하고 환상유동 시작 경계조건을 상수로 가정하는 기존 모델의 한계를 살펴보았다. 균일한 열유속으로 가열되는 얇은 수직사각유로 상향유동에서의 임계열유속을 예측하기 위하여 환상유동을 단순 모델링하고, 새로운 액막건조모델을 적용하였다. 284 개 실험데이타에 대한 예측성능을 확인한 결과 MAE 18.1%, RMSE 22.9% 예측오차로 실험데이타를 잘 예측할 수 있음을 확인하였다.

Fragrance Composition in Six Tree Peony Cultivars

  • Zhao, Jing;Hu, Zeng-Hui;Leng, Ping-Sheng;Zhang, Hui-Xiu;Cheng, Fang-Yun
    • 원예과학기술지
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    • 제30권6호
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    • pp.617-625
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    • 2012
  • Tree peony is a traditional famous flower of China, and plays an important role in Chinese traditional culture. But the floral scent of tree peony in vivo is little known. In this study, in order to explore the floral composition of tree peony, floral volatiles of six cultivars, including Paeonia suffruticosa 'Zhaofen' (ZF), P. suffruticosa 'Luoyanghong' (LYH), P. ostii 'Fengdanbai' (FDB), P. ${\times}$ lemonei 'High noon' (HN), P. ${\times}$ lemonei 'Renown' (R), and P. rockii 'Gaoyuanshenghuo' (GYSH) were collected by dynamic headspace and then identified by Automated Thermal Desorption-Gas Chromatography/Mass Spectometry. The results showed that floral fragrances of the six cultivars were qualitatively and quantitatively distinct. A total of 105 volatiles involving ten categories were detected. But not all volatile categories were emitted from these cultivars. The six peony cultivars emitted some shared compounds and peculiar compounds. The total released amounts of volatiles emitted from six cultivars were found significantly different, which was greatest for 'GYSH'. The most abundant volatile compounds detected from 'ZF', 'LYH', 'FDB', 'HN', 'R', and 'GYSH' were respectively ${\alpha}$-pinene, 2,3-dihydroxy propanal, 3-methyl-1-butanol, 2-ethyl-1-hexanol, acetic acid 1-methylethyl ester, and 5-ethyl-2,2,3-trimethyl heptane. This result may contribute to exploring the biosynthesis and emission mechanism of floral scent in tree peony.

Electrical Properties of Metal-Oxide Quantum dot Hybrid Resistance Memory after 0.2-MeV-electron Beam Irradiation

  • Lee, Dong Uk;Kim, Dongwook;Kim, Eun Kyu;Pak, Hyung Dal;Lee, Byung Cheol
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.311-311
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    • 2013
  • The resistance switching memory devices have several advantages to take breakthrough for the limitation of operation speed, retention, and device scale. Especially, the metal-oxide materials such as ZnO are able to fabricate on the flexible and visible transparent plastic substrate. Also, the quantum dots (QDs) embedded in dielectric layer could be improve the ratio between the low and the high resistance becauseof their Coulomb blockade, carrier trap and induced filament path formation. In this study, we irradiated 0.2-MeV-electron beam on the ZnO/QDs/ZnO structure to control the defect and oxygen vacancy of ZnO layer. The metal-oxide QDs embedded in ZnO layer on Pt/glass substrate were fabricated for a memory device and evaluated electrical properties after 0.2-MeV-electron beam irradiations. To formation bottom electrode, the Pt layer (200 nm) was deposited on the glass substrate by direct current sputter. The ZnO layer (100 nm) was deposited by ultra-high vacuum radio frequency sputter at base pressure $1{\times}10^{-10}$ Torr. And then, the metal-oxide QDs on the ZnO layer were created by thermal annealing. Finally, the ZnO layer (100 nm) also was deposited by ultra-high vacuum sputter. Before the formation top electrode, 0.2 MeV liner accelerated electron beams with flux of $1{\times}10^{13}$ and $10^{14}$ electrons/$cm^2$ were irradiated. We will discuss the electrical properties and the physical relationships among the irradiation condition, the dislocation density and mechanism of resistive switching in the hybrid memory device.

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Effects of Simultaneous Bending and Heating on Characteristics of Flexible Organic Thin Film Transistors

  • Cho, S.W.;Kim, D.I.;Lee, N.E.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.470-470
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    • 2013
  • Recently, active materials such as amorphous silicon (a-Si), poly crystalline silicon (poly-Si), transition metal oxide semiconductors (TMO), and organic semiconductors have been demonstrated for flexible electronics. In order to apply flexible devices on the polymer substrates, all layers should require the characteristic of flexibility as well as the low temperature process. Especially, pentacene thin film transistors (TFTs) have been investigated for probable use in low-cost, large-area, flexible electronic applications such as radio frequency identification (RFID) tags, smart cards, display backplane driver circuits, and sensors. Since pentacene TFTs were studied, their electrical characteristics with varying single variable such as strain, humidity, and temperature have been reported by various groups, which must preferentially be performed in the flexible electronics. For example, the channel mobility of pentacene organic TFTs mainly led to change in device performance under mechanical deformation. While some electrical characteristics like carrier mobility and concentration of organic TFTs were significantly changed at the different temperature. However, there is no study concerning multivariable. Devices actually worked in many different kinds of the environment such as thermal, light, mechanical bending, humidity and various gases. For commercialization, not fewer than two variables of mechanism analysis have to be investigated. Analyzing the phenomenon of shifted characteristics under the change of multivariable may be able to be the importance with developing improved dielectric and encapsulation layer materials. In this study, we have fabricated flexible pentacene TFTs on polymer substrates and observed electrical characteristics of pentacene TFTs exposed to tensile and compressive strains at the different values of temperature like room temperature (RT), 40, 50, $60^{\circ}C$. Effects of bending and heating on the device performance of pentacene TFT will be discussed in detail.

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