• Title/Summary/Keyword: Thermal ignition

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A Study on Hydration kinetics and Mechanical Properties of Cement Paste Incoporating Limestone Filler (석회석 미분말을 혼입한 시멘트 페이스트의 수화반응 및 역학적 특성 분석에 관한 연구)

  • Shin, Ki-Su;Bang, Mi-Jin;Park, Ki-Bong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.230-231
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    • 2017
  • The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.

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Improvement of Thermal Efficiency and Emission by Lean Combustion in a Boosted Spark-Ignition Engine Fueled with Syngas (합성가스 스파크점화 과급 엔진에서 희박 연소를 통한 열효율 및 배기 개선)

  • Park, Hyunwook;Lee, Junsun;Jamsran, Narankhuu;Oh, Seungmook;Kim, Changup;Lee, Yonggyu;Kang, Kernyong
    • Journal of ILASS-Korea
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    • v.26 no.1
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    • pp.40-48
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    • 2021
  • Lean combustion was applied to improve the thermal efficiency and emission in a single-cylinder, spark-ignition engine fueled with syngas. Under naturally aspirated conditions, the lean combustion significantly improved the thermal efficiency compared to the stoichiometric combustion, mainly due to the reduction in heat transfer loss. Intake air boost was applied to compensate the low power output of the lean combustion. The gross indicated power of 24.8 kW was achieved by increasing the intake pressure up to 1.6 bar at excess air ratio of 2.2. The nitrogen oxides showed near zero level, but the carbon monoxide emission was significant.

Combustion Characteristics of Pre-mixed Charge Compression Ignition Engines with Natural Gas Applied to 4-Cylinders Diesel Engine (4기통 디젤기관에 적용한 천연가스 예혼합 압축착화 기관의 연소특성)

  • Jung, S.H.
    • Journal of Power System Engineering
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    • v.13 no.2
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    • pp.5-10
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    • 2009
  • In recently, studies concerned to the diesel engine uses a natural gas as a fuel oil whose infra has been built already was approached to PCCI or HCCI with keeping a high thermal efficiency and reducing NOx and PM have been researching actively in normally single cylinder. An ignition source is required to bum the natural gas by a spark plug in gasoline engines, due to a higher auto-ignition temperature of natural gas. Then gas oil and DME were introduced as the ignition source. In this study as basic data for practical use of natural gas PCCI and HCCI engines, combustion characteristics and emission characteristics on 4-cylinders natural gas PCCI and HCCI engines with gas oil and DME as ignition sources were analyzed and the engine load range that is main object for practical use of PCCI and HCCI engines was made clearly by empirical experiment.

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A Study on Autoignition of Granulated Activated Carbon with Change of Ambient Temperature (주위온도 변화에 따른 입상활성탄의 자연발화에 관한 연구)

  • 목연수;최재욱
    • Journal of the Korean Society of Safety
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    • v.7 no.4
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    • pp.45-53
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    • 1992
  • Sponataneous ignition characteristics for granulated activated carbon were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 5$^{\circ}C$, 1$0^{\circ}C$ and 15$^{\circ}C$ respectively, and the period in each amplitude was varied at an interval of 30minutes from zero to 3hours. As the results of experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample decreased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank-Kamenetskii's thermal Ignition theory was 38.82[kca1/mo1] In case of varying the ambient temperature sinusoidally, the critical spontaneous ignition tempera-ture was lower than that at the constant ambient temperature, and the minimum critical spontaneous ignition temperature decreased with the amplitude of heating sinusoidal curve. At the same amplitude, the critical spontaneous ignition temperature decreased until it reached the minimum point and then in-creased as the period increased.

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A Study on Spontaneous Ignition of Granulated Activated Carbon (입상활성탄의 자연발화에 관한 연구(I))

  • 목연수;최재욱;김상렬;최광재
    • Journal of the Korean Society of Safety
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    • v.6 no.4
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    • pp.66-72
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    • 1991
  • Spontaneous ignition characteristics were observed by performing experiments for granulated activated carbon at constant ambient temperature in an oven. As the results of the experiments, the critical spontaneous ignition temperature of sample for large, intermediate and small vessels was 158.5$^{\circ}C$ , 165.5$^{\circ}C$ and 174.5$^{\circ}C$, respectively. It was found that the critical spontaneous ignition temperature decreased and the ignition induction time increased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank= kamenetskii's thermal ignition theory was 17.81*10$^3$J/mol.

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A Study on Autoignition of Fish Meal with Change of Ambient Temperature (주위온도 변화에 따른 어분의 자연발화에 관한연구)

  • 목연수;최재욱
    • Journal of the Korean Society of Safety
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    • v.7 no.1
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    • pp.47-56
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    • 1992
  • Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

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A Study on Noxious Gases Analysis of Polyurethane foams (Polyurethane foam의 유해가스 분석에 관한 연구)

  • 이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.14 no.2
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    • pp.7-13
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    • 2000
  • We had investigated thermal stability, Ignition temperature and fire gas for polyurethane foams used for manikin, cushion and interior finishing material. Decomposition of polyurethane foams with temperature was investigated using a DSC and the weight loss with temperature increase using a TGA in order to find the thermal hazard of polyurethane foams, and the ignition temperature of polyurethane foams according to species. We studied constant temperature among ignition temperature measuring methods. In addition, noxious gases for polyurethane foams according to combustion condition were analyzed using gas analyzer and GASTEC. As results, initial decomposition temperature of polyurethane foam used for interior finishing material was lower than those for manikin and cushion, and exothermic energy was higher. Ignition temperature of polyurethane foam of interior finishing material was $420^{\circ}$. All of combustion forms at $427^{\circ}$ and under were smoldering combustion, and it was combustion at $500^{\circ}$. As furnace temperature was increased, concentration of noxious gases such as carbon oxide, carbon dioxide, and hydrogen cyanide was increased. And nitrogen oxide at combustion condition($500^{\circ}$) was over 10 ppm.

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An Experimental Study on Performance Characteristics of a Hydrogen Fuelled Spark Ignition Engine

  • Han, Sung Bin
    • Journal of Energy Engineering
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    • v.23 no.1
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    • pp.81-89
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    • 2014
  • The purpose of this study is to obtain low-emission and high-efficiency in LPG engine with hydrogen enrichment. The objective of this paper is to clarify the effects of hydrogen enrichment in LPG fuelled engine on exhaust emission, thermal efficiency and performance. The compression ratio of 8 was selected to avoid abnormal combustion. To maintain equal heating value of fuel blend, the amount of LPG was decreased as hydrogen was gradually added. The relative air-fuel ratio was increased from 0.76 to 1.5, and the ignition timing was controlled to be at minimum spark advance for best torque (MBT).

Fire Characteristics Comparison of Resol-type Phenolic Resin for Interial Materials of Passenger Train (철도차량용 레졸계 페놀수지의 내열특성 비교)

  • Lee Cheul-kyu;Lee Duck Hee;Jung Woo Sung
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.277-283
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    • 2004
  • The time to ignition, heat release rate characteristics and carbon monoxide yield of fiber reinforced and sandwich phenol resin were investigated with cone calorimeter. The fire characteristics of unsaturated polyester, mostly being applied to the existing passenger train, and phenolic resin were compared. Thermal gravimetric analysis(TGA) was used to monitor the degree of thermal decomposition for the phenolic resin. According to the cone calorimeter data, the time to ignition, heat release rate and CO yield was faster and higher as the external heat flux increase. Under the same heat flux, the time to ignition of sandwich type phenolic resin was shorter than that of fiber reinforced. The result of comparison between unsaturated polyester and phenolic resin was that phenolic resin was shown to have better fire resistance than that of unsaturated polyester.

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Combustion Characteristics of Wood Chips(Flame Shape of Combustion and Ignition Delay) (목재의 연소 특성(2)(연소형태와 연소특성))

  • Kim, Chun-Jumg;ARAI, Masataka;Kang, Kyung-Koo
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.139-146
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    • 1999
  • Combustion Characteristics of the wood chips(balsa chips) were experimental studied as fundamental investigation of the thermal recycle system of the urban dust. The urban dust contains plastics vegetable and lot of wood material. Then, a wood was chosen as an example of the component of urban dust. A small wood chip was burned in a electric furnace and mass reduction rate during volatile and combustion states were recorded by the micro-electric balance and the combustion flame shape took a photograph by video camera at the mass of wood chips and ambient temperature in the furance. Ignition delay took the minimum value when the mass of the test chip was 0.3g. When a mass of the test chip was smaller then 0.001g, combustion with flame did not burnt.

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