• Title/Summary/Keyword: Thermal exposure

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Materials Stabilized Liquid Crystal Molecules on Chemically Modulated Polystyrene Surface Using Various Ion Beam Exposure Time

  • Han, Jeong-Min;Hwang, Hyun-Suk
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.6
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    • pp.285-287
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    • 2010
  • This paper introduces homogeneous liquid crystal (LC) orientations on chemically modulated polystyrene (PS) surfaces using various ion beam (IB) exposure times. Transparent PS was replaced with conventional polyimide material. As a non-contact process, the IB bombardment process induced LC orientation parallel to the IB process. Through x-ray photoelectron spectroscopy, it was shown that the chemical compositional changes of the IB-irradiated PS surfaces were determined as a function of IB exposure time. Using this analysis, the optimal IB bombardment condition was determined at an IB exposure time of up to 15 seconds. Moreover, thermal stability on IB-irradiated PS surfaces were carried out which showed that a relatively high IB exposure time induced a thermally stable LC alignment property.

Study on generation of pretilt angle using a methacrylic copolymers having cholconyl and cholesteryl groups. (Chalconyl과 Cholesteryl group을 가진 methacryl계 공중합체를 이용한 프리틸트 발생에 관한 연구)

  • 황정연;서대식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.7
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    • pp.625-629
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    • 2000
  • We synthesized a new copoly (PM4Ch-ChMA) copoly(poly(4-methacryloyloxy) chalcone-cholesteryl methacrylate) having chalconyl and cholesteryl moiety for homeotropic liquid crystal(LC) alignment. Pretilt angles of nematic(N) LC generated by linearly polarized UV exposure on the copolymer surfaces were investigated. Good thermal stabilities of the synthesized copolymer were obtained by TGA (Thermogravimetric Analysis) measurement. Pretilt angles of the NLC decreased with increasing UV exposure time on the copolymer surfaces. We consider that the pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of 81$^{\circ}$was observed after the UV exposure for 3 min.

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Influence of Regular Jjimjilbang Exposure on Farmers' Physiological Responses (정기적인 찜질노출이 농업인의 생리반응에 미치는 영향)

  • Choi, Jeong-Wha;Song, Eun-Young;Park, Joon-Hee
    • Journal of the Korean Home Economics Association
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    • v.46 no.1
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    • pp.39-45
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    • 2008
  • We analyzed the effects of regular Jjimjilbang(Korean sauna) exposure on the physiological responses in seven elderly farmers(Male=3, Female=4). Jjimjil training group took a bath in Jjimjilbang 8 times twice a week. Jjimjibang exposure was limited three times per day. Rectal temperature, total sweat rate, body fat (%), blood pressure, pulse, $Na^+$ concentration in sweat, and subjective sensation were measured during Jjimjil training exposure. The results are as follow: During Jjimjil exposure, changes of rectal temperature in male farmers were more stabilized than female farmers. The gradual decrease in total sweat rate and Na+ concentration in sweat was observed in both sexes. After Jjimjil exposure, the decrease in blood pressure was observed in both sexes, but not observed changes according to regular Jjimjil exposure. Subjective thermal comfort sensation was changed positively. In conclusion, the regular Jjimjil exposure has positive effects upon improvement in regulation of body temperature, blood pressure, and $Na^+$ concentration especially in heat tolerance.

Thermal reaction of cinnamate oligomers and their effect on the orientational stability of liquid crystals

  • Hah, Hyun-Dae;Sung, Shi-Joon;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.493-495
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    • 2007
  • Cinnamate groups are well-known for a dimerization reaction upon exposure to ultraviolet irradiation and a thermal reaction after being heated. In this study, to verify the thermal reaction of the cinnamate group in detail, we investigated the thermal crosslinking of cinnamate oligomers. The thermal reaction of cinnamate oligomers of low molecular weight is induced more readily by thermal energy compared with that of cinnamate polymers. The orientation of the liquid crystal depended on the length of the spacers in the cinnamate oligomers.

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Characterization of Thermal Degradation of Polymide 66 Composite: Relationship between Lifetime Prediction and Activation Energy (폴리아미드 66 복합소재의 열 열화 특성: 수명 예측과 활성화 에너지의 상관관계)

  • Jung, Won-Young;Weon, Jong-Il
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.712-720
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    • 2012
  • Thermal degradation for glass fiber-reinforced polyamide 66 composite (PA 66) with respect of thermal exposure time has been investigated using optical microscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. As the thermal exposure time was prolonged, a slight increase in tensile strength for only initial stage and afterward, a proportional decrease of tensile strength was observed. These results can be explained by the increase of crystallinity, followed by the increase of crosslinking density, chain scission and the decrease in chain mobility, due to thermal oxidation with the exposure time. Fourier transform infrared spectroscopy results showed the increase of ketone peak and silica peak on the surface of thermally exposed PA 66. In addition, the thermal decomposition kinetics of PA 66 was analyzed using thermogravimetric analysis at three different heating rates. The relationship between activation energy and lifetime-prediction of PA 66 was investigated by several methodologies, such as statistical tool, UL 746B, Ozawa and Kissinger. The activation energy determined by thermogravimetric analysis had a relatively large value compared with that from the accelerated test. This may result in over-estimating the lifetime of PA 66. In this study, a master curve of exponential fitting has been developed to extrapolate the activation energy at various service temperatures.

Thermal Shock Resistance of Bilayered YSZ Thermal Barrier Coating

  • Lee, Dong Heon;Kim, Tae Woo;Lee, Kee Sung;Kim, Chul
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.452-460
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    • 2018
  • This study investigate changes in mechanical behaviors such as indentation load-displacement and hardness of thermal barrier coatings (TBCs) using cycling of thermal shock test. Relatively dense and porous TBCs on nickel-based bondcoat/super alloy are prepared using different starting granules, 204C-NS and 204NS commercial powers, and the effect of double layers of 204C-NS on 204NS and 204NS on 204C-NS are investigated. The highest temperature applied during thermal shock test is $1100^{\circ}C$ and the maximum number of cycles is 1,200. The results indicate that bilayered TBC showed a relatively mechanically resistant property during thermal shock cycles and that the mechanical behavior is influenced by the microstructure of TBCs by exposure to high temperature during tests or different starting granules.

Wear Comfort of Firefighters Protective Gloves in Dry and Wet Conditions at 70℃ Air Temperature with Radiant Heat (기온 70℃의 복사열 노출 환경에서 건조와 젖은 상태의 소방용 보호장갑 착용 시 쾌적성 평가)

  • Kim, Dami;Kim, Dohyung;Lee, Joo-Young
    • Journal of Korean Living Environment System
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    • v.24 no.1
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    • pp.95-106
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    • 2017
  • The purpose of this study was to evaluate comfort functions while wearing firefighters' protective gloves in dry and wet conditions at $70^{\circ}C$ air temperature with radiant heat. Four types of firefighting gloves from Korea, Germany, United States, and Japan were evaluated in both dry and wet conditions by eight male firefighters. Firefighters put their hands and forearms wearing gloves into a hands-radiant chamber that maintained at an air temperature of $70{\pm}2^{\circ}C$ ($T_a$) and globe temperature $106^{\circ}C$ ($T_g$). During the exposure, subjects followed a fixed protocol of manual movements and stopped the exposure when they felt being intolerable. Results showed that completion time was extended by 6 min on average when gloves got wet and 15 min for the Japanese gloves was extended when compared to its dry condition (p<.001); microclimate humidity on the palm at the last stage was greater for wet conditions than dry conditions in the all gloves; and skin temperatures on mid-fingertip, palm, and hand were significantly lower for wet conditions than dry conditions especially for Japanese gloves (p<.001). These results indicate that the exposure time without thermal pain to radiant heat could be extended by wetting gloves during the low radiant heat exposure.

Durability of Carbon/Epoxy Composites for Train Carbody under Salt Water Environment (염수환경에 노출된 철도차량용 탄소섬유/에폭시 복합재의 내구성 평가)

  • Hwang, Young-Eun;Yoon, Sung-Ho;Kim, Jung-Suk;Han, Seong-Ho
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.852-858
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    • 2007
  • The durability of carbon/epoxy composites under salt water environment was investigated through salt water spray tester. Salt water environment was obtained through salt spray and salt immersion. 5% NaCl solution was used for salt water as natural salt water. Mechanical test was performed to obtain tensile properties, flexural properties, and shear properties of carbon/epoxy composite over 12 months under salt water environment. Dynamic mechanical analyzer was used to investigate thermal analysis properties such storage modulus, loss modulus, and tan ${\delta}$. Also FT/IR test was conducted to investigate a change in chemical structure. According to the results, mechanical properties were found to be slowly degraded as a function of exposure times. Regarding to thermal analysis properties, storage modulus was insensitive to exposure times, but loss modulus was shown to be slightly decreased. Although the shape and location of peak in FT/IR were not much changed, the intensity of peak in FT/IR was affected on exposure times. We also found that salt water immersion was more severe to the durability of carbon/epoxy composite rather than salt water spray.

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Classification of Biological Effect of 1,763 MHz Radiofrequency Radiation Based on Gene Expression Profiles

  • Im, Chang-Nim;Kim, Eun-Hye;Park, Ae-Kyung;Park, Woong-Yang
    • Genomics & Informatics
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    • v.8 no.1
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    • pp.34-40
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    • 2010
  • Radiofrequency (RF) radiation might induce the transcription of a certain set of genes as other physical stresses like ionizing radiation and UV. To observe transcriptional changes upon RF radiation, we exposed WI-38, human lung fibroblast cell to 1763 MHz of mobile phone RF radiation at 60 W/kg of specific absorption rate (SAR) for 24h with or without heat control. There were no significant changes in cell numbers and morphology after exposure to RF radiation. Using quantitative RT-PCR, we checked the expression of three heat shock protein (HSP) (HSPA1A, HSPA6 and HSP105) and seven stress-related genes (TNFRSF11B, FGF2, TGFB2, ITGA2, BRIP1, EXO1, and MCM10) in RF only and RF/HS groups of RF-exposed cells. The expressions of three heat shock proteins and seven stress-related genes were selectively changed only in RF/HS groups. Based on the expression of ten genes, we could classify thermal and non-thermal effect of RF-exposure, which genes can be used as biomarkers for RF radiation exposure.

Ingestion Exposure to Nitrosamines in Chlorinated Drinking Water

  • Kim, He-Kap;Han, Ki-Chan
    • Environmental Analysis Health and Toxicology
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    • v.26
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    • pp.2.1-2.7
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    • 2011
  • Objectives: N-Nitrosodimethylamine (NDMA) is classified as a probable human carcinogen by the United States Environmental Protection Agency (US EPA) and is formed during the chlorination of municipal drinking water. In this study, selected nitrosamines were measured in chlorinated drinking water collected from Chuncheon, Kangwon-do, Republic of Korea, and a risk assessment for NDMA was conducted. Methods: Twelve water samples were collected from 2 treatment plants and 10 household taps. Samples were analyzed for 6 nitrosamines via solid-phase extraction cleanup followed by conversion to dansyl derivatives and high-performance liquid chromatography-fluorescence detection (HPLC-FLD). Considering the dietary patterns of Korean people and the concentration change of NDMA by boiling, a carcinogenic risk assessment from ingestion exposure was conducted following the US EPA guidelines. Results: NDMA concentrations ranged between 26.1 and 112.0 ng/L. NDMA in water was found to be thermally stable, and thus its concentration at the end of boiling was greater than before thermal treatment owing to the decrease in water volume. The estimated excess lifetime carcinogenic risk exceeded the regulatory baseline risk of $10^{-5}$. Conclusions: This result suggests that more extensive studies need to be conducted on nitrosamine concentration distributions over the country and the source of relatively high nitrosamine concentrations.