• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1074-1081
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• 2021

Nitrous oxide (N₂O) is one of the six major greenhouse gases and is known to produce a greenhouse ef ect by absorbing infrared radiation in the atmosphere. In particular, its global warming potential (GWP) is 310 times higher than that of CO₂, making N₂O a global concern. Accordingly, strong environmental regulations are being proposed. N₂O reduction technology can be classified into concentration recovery, catalytic decomposition, and pyrolysis according to physical methods. This study intends to provide information on temperature conditions and reaction time required to reduce nitrogen oxides with cost. The high-temperature ranges selected for pyrolysis conditions were calculated at intervals of 100 K from 1073 K to 1373 K. Under temperatures of 1073 K and 1173 K, the N₂O reduction rate and nitrogen monoxide concentration were observed to be proportional to the residence time, and for 1273 K, the N₂O reduction rate decreased due to generation of the reverse reaction as the residence time increased. Particularly for 1373 K, the positive and reverse reactions for all residence times reached chemical equilibrium, resulting in a rather reduced reaction progression to N₂O reduction.

• Journal of the Korean Institute of Gas
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• v.26 no.2
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• pp.49-55
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• 2022

According to reinforce environmental regulations, coal power plants have used selective catalytic reduction using ammonia as a reducing agent to reduce the amount of nitrogen oxide generation. The purpose of the present study was to derive a mixing device for effectively mixing dilute air and ammonia in the ammonia mixing pipe by performing computational fluid dynamic analysis. The mixing effect was compared by analysing the %RMS of ammonia concentration at the down stream cross section in the mixing pipe and the 16 outlets based on the case 1-1 shape, which is an existing mixing pipe without a mixing device. The mixing device was performed by changing the positions of a square plate on the downstream side of the ammonia supply pipe and an arc-shaped plate on the wall of the mixing pipe. In the case of the existing geometry(Case 1-1), the %RMS of ammonia concentration at the 16 outlets was 29.50%. The shape of the mixing device for Case 3-2 had a square plate on the downstream side of the ammonia supply pipe and an arc plate was installed adjacent to it. The %RMS of ammonia concentration for Case 3-2 was 2.08% at 16 outlets and it could be seen that the shape of Case 3-2 was the most effective mixing shape for ammonia mixing.

• Journal of Internet Computing and Services
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• v.24 no.1
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• pp.61-69
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• 2023

Recently, as the fishery resources are depleted, expectations for productivity improvement by 'rearing fishery' in land farms are greatly rising. In the case of land farms, unlike ocean environments, it is easy to control and manage environmental and breeding factors, and has the advantage of being able to adjust production according to the production plan. On the other hand, unlike in the natural environment, there is a disadvantage in that operation costs may significantly increase due to the artificial management for fish growth. Therefore, profit maximization can be pursued by efficiently operating the farm in accordance with the planned target shipment. In order to operate such an efficient farm and nurture fish, an accurate growth prediction model according to the target fish species is absolutely required. Most of the growth prediction models are mainly numerical results based on statistical analysis using farm data. In this paper, we present a growth prediction model from a stochastic point of view to overcome the difficulties in securing data and the difficulty in providing quantitative expected values for inaccuracies that existing growth prediction models from a statistical point of view may have. For a stochastic approach, modeling is performed by introducing a Gaussian process regression method based on water temperature, which is the most important factor in positive growth. From the corresponding results, it is expected that it will be able to provide reference values for more efficient farm operation by simultaneously providing the average value of the predicted growth value at a specific point in time and the confidence interval for that value.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.285-290
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• 2023

Poly-lactic acid (PLA) is the most promising polymer in additive manufacturing as an alternative to acrylonitrile butadiene styrene (ABS). Since it is produced from renewable resources such as corn starch and sugar beets, it is also biocompatible and biodegradable. However, PLA has a couple of issues that limit its use. First, it has a comparatively low glass transition temperature of around 60 ℃, such that it exhibits low thermal resistance. Second, PLA has low impact strength because it is brittle. Due to these problems, scientists have found methods to improve the crystallinity and ductility of PLA. Polyethylene glycol (PEG) is one of the most studied plasticizers for PLA to give it chain mobility. However, the blend of PLA and PEG becomes unstable, and phase separation occurs even at room temperature as PEG is self-crystallized. Thus, it is necessary to investigate the optimal mixing ratio of PLA-PEG at the molecular scale. In this study, molecular dynamics will be conducted with various ratios of L-type PLA (PLLA) or DL-type PLA-PEG (PDLA-PEG) systems by using BIOVIA Materials Studio.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.43 no.4
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• pp.449-458
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• 2023

As an adsorption technology for dissolved organic matter, the adsorption capacity of granular activated carbon, GAC, can be applied, but activated carbon whose adsorption capacity is significantly reduced by use is inevitably replaced or regenerated. However, due to the economics of replacement cost, thermal regeneration method is used commercially, but high energy cost and loss of activated carbon occur under high temperature conditions above 800℃. In this study, the Sono-Fenton method, a multi-oxidation technology that combines Fenton oxidation and ultrasonic oxidation, was applied to improve the regeneration efficiency of spent GAC used to treat dissolved organic matter in combined sewer overflows (CSOs), and the regeneration efficiency of spent GAC by oxidant and ultrasonic frequency was investigated. In the applied Sono-Fenton treatment, the highest regeneration efficiency of 68.5% was obtained under the regeneration conditions of Fe²⁺ 10 mmol/L, H₂O₂ concentration 1,000 mmol/L, ultrasonic treatment time of 120 min, and ultrasonic frequency of 40 kHz. And similar efficiency was also obtained at 750 kHz, while ultrasonic waves of other frequencies had poor regeneration efficiency, and the magnitude of frequency and GAC regeneration efficiency did not show a linear relationship. In the case of continuous operation of the GAC adsorption tower with CSOs prepared by diluting raw sewage, about 700 hours of operation without regeneration was possible, and as a result of applying one Sono-Fenton treatment, 40-70% COD_cr removal efficiency was obtained during a total of 1,000 hours of GAC adsorption operation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.43 no.1
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• pp.9-20
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• 2023

For highway concrete structures, the deterioration of the structure is accelerated due to the increase in the use of deicing materials, and sectional repair work is being frequently carried out to restore performance. However, after the repair work, re-damage such as cracks, delamination, and poor bond performance is exhibited in the repaired sectional area. In this study, overseas repair material requirements were first analyzed, and present domestic requirements were improved repair material performance through field surveys of common concrete structures, laboratory experiments, and test construction on a disused concrete bridge. In addition, performancebased quality requirements were presented so that all materials that meet the required performance can be applied, and different test methods for each material were unified into concrete test methods for consistent test results analysis. The considered performance requirements were compression strength, bending strength, and bond strength for structural properties, and length change rate, crack resistance, thermal expansion coefficient, and elasticity coefficient were for dimensional behavior. For resistance to chloride penetration resistance and freeze-thaw resistance were presented as durability. The proposed requirements for concrete repair materials are expected to contribute to the improvement of the quality of concrete sectional repair work in Korea.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1D
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• pp.195-202
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• 2006

The infiltration route analysis is a military application using geospatial information technology. The result of the analysis would present vulnerable routes for potential enemy infiltration. In order to find the susceptible routes, optimal path search algorithms (Dijkstra's and $A^*$) were used to minimize the cost function, summation of detection probability. The cost function was produced by capability of TOD (Thermal Observation Device), results of viewshed analysis using DEM (Digital Elevation Model) and two related geospatial information coverages (obstacle and vegetation) extracted from VITD (Vector product Interim Terrain Data). With respect to 50m by 50m cells, the individual cost was computed and recorded, and then the optimal infiltration routes was found while minimizing summation of the costs on the routes. The proposed algorithm was experimented in Daejeon region in South Korea. The test results show that Dijkstra's and $A^*$ algorithms do not present significant differences, but A* algorithm shows a better efficiency. This application can be used for both infiltration and surveillance. Using simulation of moving TOD, the most vulnerable routes can be detected for infiltration purpose. On the other hands, it can be inversely used for selection of the best locations of TOD. This is an example of powerful geospatial solution for military application.

• Journal of Practical Agriculture & Fisheries Research
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• v.21 no.2
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• pp.59-69
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• 2019

This study was carried out to investigate effects of soil water content on growth and antioxidative enzymes activity of tomato seedlings during the nursery period. The water stress significantly damages morphological, physiological, and biochemical activities in plants. The seedlings planted with soil on the tray were irrigated and categorized into 3 groups with 30 g, 40 g, and 50 g of plant-soil weight. After then, the changes in weight of the soil and the seedling were measured evey 2 hours for 4 days and the leaf temperature was measured with the thermal-camera at the same time. The antioxidant enzymes were measured to determine the level of stress using all of the seedling samples. The result showed that the decrease of soil weight in the day time was faster than that in the night time, but there was no significant difference in the weight loss of the seedlings and soil among the groups. However, the group with 50 g of wight showed the highest SOD and POD contents. This is considered that the continuously wet soil on the root zone of the seedlings caused more stress for the seedlings. Therefore, it is concluded that the excess moisture content causes stress to stimulate the secretion of antioxidant enzymes, and the effect of stress is required to be analyzed comprehensively using environmental data and also the physiological data that are collected over a longer period.

• Journal of Korea Water Resources Association
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• v.56 no.11
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• pp.721-728
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• 2023

Agricultural drought is triggered by a depletion of moisture content in the soil, which hinders photosynthesis and thus increases carbon dioxide (CO₂) concentrations in the atmosphere. The aim of this study is to analyze the relationship between soil moisture (SM) and vegetation activity toward quantifying CO₂ concentration in the atmosphere. To this end, the MODerate resolution imaging spectroradiometer (MODIS), an optical multispectral sensor, was used to evaluate two regions in South Korea for validation. Vegetation activity was analyzed through MOD13A1 vegetation indices products, and MODIS gross primary productivity (GPP) product was used to calculate the CO₂ flux based on its relationship with respiration. In the case of SM, it was calculated through the method of applying apparent thermal inertia (ATI) in combination with land surface temperature and albedo. To validate the SM and CO₂ flux, flux tower data was used which are the observed measurement values for the extreme drought period of 2014 and 2015 in South Korea. These two variables were analyzed for temporal variation on flux tower data as daily time scale, and the relationship with vegetation index (VI) was synthesized and analyzed on a monthly scale. The highest correlation between SM and VI (correlation coefficient (r) = 0.82) was observed at a time lag of one month, and that between VI and CO₂ (r = 0.81) at half month. This regional study suggests a potential capability of MODIS-based SM, VI, and CO₂ flux, which can be applied to an assessment of the global view of the agricultural drought by using available satellite remote sensing products.

• Explosives and Blasting
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• v.41 no.3
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• pp.62-72
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• 2023

The aging of plant structures due to industrialization in the 1970s has increased the demand for blast demolition. While blasting can reduce exposure to environmental pollution by shortening the demolition period, improper blasting design and construction plans pose significant safety risks. Thus, it is vital to consider optimal blasting demolition conditions and other factors through collapse behavior simulation. This study utilizes a 3-D combined finite-discrete element method (FDEM) code-based 3-D DFPA to simulate the collapse of a chimney structure in a thermal power plant in Seocheon, South Korea. The collapse behavior from the numerical simulation is compared to the actual structure collapse, and the numerical simulation result presents good agreement with the actual building demolition. Additionally, various numerical simulations have been conducted on the chimney models to analyze the impact of the duct size in the pre-weakening area. The no-duct, duct, and double-area duct models were compared in terms of crack pattern and history of Z-axis displacement. The findings show that the elapse-time for demolition decreases as the area of the duct increases, causing collapse to occur quickly by increasing the load-bearing area.