• Title/Summary/Keyword: Thermal deterioration

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Nonlinear Modeling and Application of PI Control on Pre-cooling Session of a Carbon Dioxide Storage Tank at Normal Temperature and Pressure (상온 상압의 이산화탄소 저장용 탱크를 위한 예냉과정의 비선형 모델링 및 비례-적분 제어 적용)

  • Lim, Yu Kyung;Lee, Seok Goo;Dan, Seungkyu;Ko, Min Su;Lee, Jong Min
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.574-580
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    • 2014
  • Storage tanks of Carbon dioxide ($CO_2$) carriers utilized for the purpose of carbon capture and storage (CCS) into subsea strata have to undergo a pre-cooling session before beginning to load cryogenic liquid cargos in order to prevent physical and thermal deterioration of tanks which may result from cryogenic $CO_2$ contacting tank walls directly. In this study we propose dynamic model to calculate the tank inflow of $CO_2$ gas injected for precooling process and its dynamic simulation results under proportional-integral control algorithm. We selected two cases in which each of them had one controlled variable (CV) as either the tank pressure or the tank temperature and discussed the results of that decision-making on the pre-cooling process. As a result we demonstrated that the controlling instability arising from nonlinearity and singularity of the mathematical model could be avoided by choosing tank pressure as CV instead of tank temperature.

Preparation and Properties of Shape-Stabilized Phase Change Materials from UHMWPE and Paraffin Wax for Latent Heat Storage (파라핀과 초고분자량 폴리에틸렌으로 구성된 형태안정성 상 전이 물질의 제조 및 특성)

  • Lee, Hyun-Seok;Park, Jae-Hoon;Yim, Jong-Ha;Seo, Hye-Jin;Son, Tae-Won
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.23-32
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    • 2015
  • Phase change materials based on ultra high molecular weight of polyethylene (UHMWPE) blended with paraffin wax (mp $65^{\circ}C$) were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from UHMWPE and paraffin wax (mp $65^{\circ}C$), their basic properties and possible applications to latent heat storage. The preparation method was an absorption method. Also, SSPCM composites were prepared by using a hot press at $200^{\circ}C$ for 10 min. The analysis for the shape ability of SSPCM to improve heat efficiency was measured by FTIR, SEM, DSC, XRD, and ARES. UHMWPE composites with 30 wt% paraffin wax (mp $65^{\circ}C$) demonstrated less deterioration of physical property and effective thermal property compared with other conditions. As a result, these SSPCMs could be used for the heat storage and release materials for various products.

Characterization of Area Installing Combined Geothermal Systems : Hydrogeological Properties of Aquifer (복합지열시스템에 대한 부지특성화: 대수층의 수리지질학적 특성)

  • Mok, Jong-Koo;Park, Yu-Chul;Park, Youngyun;Kim, Seung-Kyum;Oh, Jeong-Seok;Seonwoo, Eun-Mi
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.293-304
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    • 2017
  • This study was performed in order to hydrogeological analysis of aquifer, which is a necessary part for evaluating the efficiency of the combined well and open-closed loops geothermal (CWG) systems. CWG systems have been proposed for the effective utilization of geothermal energy by combining open loop geothermal systems and closed loop geothermal systems. Small aperture CWG systems and large aperture CWG systems were installed at a green house land with water curtain facilities in Chungju City. Aquifer tests include pumping tests and step-drawdown tests were conducted to analyse hydrogeological characteristics of aquifer in the study area. The transmissivity was estimated in the range of $13.49{\sim}58.99cm^2/sec$, and the storativity was estimated in the range of $1.13{\times}10^{-5}{\sim}5.20{\times}10^{-3}$. The geochemical analysis showed $Ca^{2+}$ ion and ${HCO_3}^-$ ion were dominant in groundwater. The Langelier Saturation Index and the Ryznar Stability Index showed low scaling potential of groundwater. In the analysis of vertical water temperature change, the geothermal gradient was estimated as $2.1^{\circ}C/100m$, which indicated the aquifer was enough for geothermal systems. In conclusion, groundwater is rich, can stably use geothermal heat, and it is less likely to cause deterioration of thermal energy efficiency by precipitation of carbonate minerals in study area. Therefore, the study area is suitable for installation of the combined geothermal system.

A Study on the Optimal Design of Soft X-ray Ionizer using the Monte Carlo N-Particle Extended Code (Monte Carlo N-Particle Extended 코드를 이용한 연X선 정전기제거장치의 최적설계에 관한 연구)

  • Jeong, Phil hoon;Lee, Dong Hoon
    • Journal of the Korean Society of Safety
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    • v.32 no.2
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    • pp.34-37
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    • 2017
  • In recent emerging industry, Display field becomes bigger and bigger, and also semiconductor technology becomes high density integration. In Flat Panel Display, there is an issue that electrostatic phenomenon results in fine dust adsorption as electrostatic capacity increases due to bigger size. Destruction of high integrated circuit and pattern deterioration occur in semiconductor and this causes the problem of weakening of thermal resistance. In order to solve this sort of electrostatic failure in this process, Soft X-ray ionizer is mainly used. Soft X-ray Ionizer does not only generate electrical noise and minute particle but also is efficient to remove electrostatic as it has a wide range of ionization. X-ray Generating efficiency has an effect on soft X-ray Ionizer affects neutralizing performance. There exist variable factors such as type of anode, thickness, tube voltage etc., and it takes a lot of time and financial resource to find optimal performance by manufacturing with actual X-ray tube source. MCNPX (Monte Carlo N-Particle Extended) is used for simulation to solve this kind of problem, and optimum efficiency of X-ray generation is anticipated. In this study, X-ray generation efficiency was measured according to target material thickness using MCNPX under the conditions that tube voltage is 5 keV, 10 keV, 15 keV and the target Material is Tungsten(W), Gold(Au), Silver(Ag). At the result, Gold(Au) shows optimum efficiency. In Tube voltage 5 keV, optimal target thickness is $0.05{\mu}m$ and Largest energy of Light flux appears $2.22{\times}10^8$ x-ray flux. In Tube voltage 10 keV, optimal target Thickness is $0.18{\mu}m$ and Largest energy of Light flux appears $1.97{\times}10^9$ x-ray flux. In Tube voltage 15 keV, optimal target Thickness is $0.29{\mu}m$ and Largest energy of Light flux appears $4.59{\times}10^9$ x-ray flux.

Removal of tar and particulate from gasification process using pre-coating technology (바이오매스 가스화 공정의 생성가스 중 타르 및 입자 제거를 위한 pre-coating 기술 연구)

  • Kim, Joon-Yub;Choi, Byoung-Kwon;Jo, Young-Min;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.804-815
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    • 2019
  • Due to the depletion and environmental problems of fossil fuel, biomass has arisen as an alternative energy source. Biomass is a renewable and carbon-neutral source. However, it is moister and has lower energy density. Therefore, biomass needs thermal chemical conversion processes like gasification, and it does not only produce a flammable gas, called 'syngas', which consists of CO, H2, and CH4, but also some unwanted byproducts such as tars and some particulates. These contaminants are condensed and foul in pipelines, combustion chamber and turbine, causing a deterioration in efficiency. Thus this work attempted to find a method to remove tars and particles from syngas with a filter which adopts a pre-coating technology for preventing blockage of the filter medium. Hydrated limestone powder and activated carbon(wood char) powder were used as the pre-coat materials. The removal efficiency of the tars was 86 % and 80 % with activated carbon(wood char) coating and hydrated limestone coating, respectively.

A STUDY ON THE DISTORTION OF THE COPINGS FOR CERAMOMETAL CROWNS DURING REPEATED FIRING (도재전장금관을 위한 코핑의 변형에 관한 연구)

  • Lee, Ki-Hong;Chung, Hun-Young;Lee, Sun-Hyung;Yang, Jae-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.4
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    • pp.706-718
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    • 1997
  • Ceramometal crowns are common restorations in fixed prosthodontics because of their casting accuracy, the high strength properties of the metal, and the cosmetic appearance of porcelain. However, deterioration of the initial fit of the metal coping has been observed after the porcelain firing cycle. The distortion due to repeated firing makes it difficult to fit crown margin and elicits microleakage. The major causes of distortion are the residual stress that accumulate during wax-up, casting, cold work and the induced stress caused by the mismatch of porcelain-metal thermal contraction. This study examined the marginal fit changes of metal copings in relation to repeated firing and the effects of heat treatment that reduce the distortion resulted from residual stress. The marginal changes of the copings that were treated with conventional method and those treated with heat before repeated firing, were evaluated. The metal die which represented preparations of a maxillary central incisor was fabricated, and 45 wax patterns were cast with nonprecious metal alloys. The heat treatment of each group was performed as follows. Group 1(control) : Casting - Devesting - Cold work - Firing Group 2 : Casting - Heat treatment - Devesting - Cold work - Firing Group 3 : Casting - Devesting - Cold work - Reinvesting - Heat treatment - Devesting - Firing The copings were fired 3 times. After each firing, the marginal fit changes were measured with inverted metallurgical microscope at the 4 reference points located at labial, lingual, and both proximal surface. Measurements were compared, and statistically analyzed. The results were as follows ; 1. In all groups, the highest value of marginal fit changes of the copings studied were found after the first firing cycle. 2. When the distortion of each experimental group at the first firing cycle were compared, group 1 exhibited the greatest changes($20-27{\mu}m$), followed by group 2($9-13{\mu}m$), and group 3($8-10{\mu}m$). 3. The copings treated with heat before devesting(group 2) revealed significantly smaller marginal fit changes than the copings treated with conventional method(group 1). (p<0.01) 4. The copings treated with heat after reinvesting(group 3) revealed significantly smaller marginal fit changes than the copings treated with conventional method(group 1). (p<0.01) 5. No siginificant differences in marginal fit changes were found between the copings treated with heat before devesting(group 2) and the copings treated with heat after reinvesting(group 3). (p>0.01)

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A Technical Assessment of Possibility Sanction for Assistance to DPRK (대북 바이오가스플랜트 지원의 제재 가능성에 대한 기술적 평가)

  • Chung, Yongjin;Kwon, Yongchai
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.192-199
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    • 2015
  • Under the economic banner of "self-reliance," North Korea has focused on hydro and thermal power as its main energy supply sources. However, in the face of extreme energy penury caused by machinery and material supply instability in the wake of the collapse of the former communist block as well as equipment aging and deterioration due to floods and other disasters, North Korea and international aid organizations are increasingly turning their attention toward energy source diversification. In particular, renewable energy is recognized as the best strategic energy source for North Korea and it is a decentralized energy option that is suitable in light of North Korea's power distribution networks and its pursuit of self-reliance. Biogas can contribute to improving the human rights situation of North Koreans in conjunction with an increase in food production. For this reason, renewable energy is the most promising option for an energy source that is likely to secure humanitarian aid from international organizations such as the Food and Agricultural Organization (FAO) and the World Food Programme (WFP). However, the implementation of such humanitarian aid has been hampered by rising concerns about the diversion of provided energy materials for military purposes and the disguised introduction of dual use items strategic materials as well as UN Security Council resolutions and sanctions of the international community against North Korea's military provocation, including nuclear tests and missile launches. This paper explores the possibility of solving this dilemma and proceeding with the humanitarian aid to North Korea by evaluating the potential for sanction and the risk of diversion of the possible products for biogas-related aid on the basis of the list of UN-sanctioned items.

A Study on the Durability Improvement by Controlling the Deterioration of Underground Concrete Structures (지하 콘크리트구조물의 열화 억제에 의한 내구성 증진에 관한 연구)

  • 천병식;최춘식;정원우
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.23-31
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    • 2004
  • Normally, coating is used for protecting reinforced concrete. For this purpose, both organic and inorganic coatings are used. The advantages of inorganic coatings are lower absorption of UV, non-burning etc. On the other hand, organic coatings have the advantage of low permeability of $CO_2, SO_2$ and water. Organic coatings provide better protection for reinforced concrete. However, organic coatings such as epoxy, urethane and acryl reduce long-term adhesive strength by the difference of their thermal expansion coefficients and elastic modules from those of concrete, and the formed coating cover of these is blistered by poor breathing. Also, when organic coatings are applied to the wet surface of concrete, they have a problem with adhesion. In this study, a new coating material for protecting concrete was hybridized with polymer and ceramics. And tests were carried out on its physical and durable characteristics, and safety characteristic on elution. All results were compared with organic coating materials and epoxies and showed that the performance of the developed coating material was not inferior to that of other organic coatings in protecting concrete. On the other hand, safety characteristic on elution was superior to epoxies which were used in this study. So, the developed coating material was considered as a suitable protecting coating material which have advantages of inorganic and organic coatings for protecting underground concrete structures, especially in contact with water.

A Study on the Influence of Urban Environment on the Generation of Thermal Diseases (도시 환경이 온열질환 발생에 미치는 영향에 관한 연구)

  • Lee, Su-Mi;Kweon, Ihl;Kim, Yong-Jin
    • The Journal of the Korea Contents Association
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    • v.19 no.12
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    • pp.84-92
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    • 2019
  • The deterioration of the urban heat environment due to climate change and the occurrence of heat-related diseases have emerged as one of the major social problems. This has led to more research on climate change, including heat waves, but it is mainly focused on climate factors. However, the urban heat island phenomenon accelerates the summer heat wave, and the increasing trend of heat-related patients in urban areas suggests the impact of the city's environment. Thus, this study analyzed the effects of physical and social characteristics of urban areas on heat-related patients in Seoul and Gyeonggi-do. The analysis showed that the ratio of the total area of residential, commercial and industrial facilities, the main source of heat energy locality, among the land use statuses, was not statistically significant, but the road area and the green area were found to have a positive and negative The population density and the percentage of people aged 65 or older, the percentage of people living alone and the proportion of people receiving basic living were all shown to be significant, with only the ratio of elderly living alone and the ratio of population density having negative effects. The results of the study can be used to develop urban policy alternatives related to local warming patients.

Prevention of quality deterioration of concentrated blueberry juice by means of pH regulators during thermal treatment (pH 조절제를 이용한 농축 블루베리주스 열처리 시 품질저하억제)

  • Lee, In Gyeong;Min, Seo Cheol;Kim, Hee Sun;Han, Gwi Jung;Kim, Myung Hwan
    • Korean Journal of Food Science and Technology
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    • v.48 no.5
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    • pp.496-501
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    • 2016
  • This study was conducted to minimize the quality degradation of concentrated blueberry juice after $90^{\circ}C$ treatment for 5 min by means of citric acid (CA) and acidic sodium metaphosphate (ASM) as pH modifiers. The highest anthocyanin content was observed at 1% CA+1% ASM (65.747 mg per 100 g) followed by 1% CA (46.022 mg per 100 g) and control (30.864 mg per 100 g). The DPPH radical scavenging activities of 1% CA+1% ASM, 1% CA and control were 87.338, 75.486 and 67.983% in respectively. The elastase inhibitory activity at 1% CA+1% ASM, 1% CA and in the control was 87.338, 75.486 and 67.983%, and the tyrosinase inhibitory of these samples were 77.891, 67.598 and 26.375%, respectively. Anthocyanin contents, DPPH radical scavenging, elastase inhibitory and tyrosinase inhibitory activities were significantly different (p<0.05) between the 1% CA+1% ASM treatment and control. During the heat treatment, quality degradation of concentrated blueberry juice was reduced by the 1% CA+1% ASM treatment, as expected for new acidulants.