• Title/Summary/Keyword: Thermal cycles

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Comparative evaluation of effects of different surface treatment methods on bond strength between fiber post and composite core

  • Mosharraf, Ramin;Yazdi, Najmeh Baghaei
    • The Journal of Advanced Prosthodontics
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    • v.4 no.2
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    • pp.103-108
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    • 2012
  • PURPOSE. Debonding of a composite resin core of the fiber post often occurs at the interface between these two materials. The aim of this study was to evaluate the effects of different surface treatment methods on bond strength between fiber posts and composite core. MATERIALS AND METHODS. Sixty-four fiber posts were picked in two groups (Hetco and Exacto). Each group was further divided into four subgroups using different surface treatments: 1) silanization; 2) sandblasting; 3) Treatment with 24% $H_2O_2$, and 4) no treatment (control group). A cylindrical plexiglass matrix was placed around the post and filled with the core resin composite. Specimens were stored in 5000 thermal cycles between $5^{\circ}C$ and $55^{\circ}C$. Tensile bond strength (TBS) test and evaluation using stereomicroscope were performed on the specimen and the data were analyzed using two-way ANOVA, Post Hoc Scheffe tests and Fisher's Exact Test (${\alpha}$=.05). RESULTS. There was a significant difference between the effect of different surface treatments on TBS ($P$ <.001) but different brands of post ($P$=.743) and interaction between the brand of post and surface treatment ($P$=.922) had no significant effect on TBS. Both silanization and sandblasting improved the bonding strength of fiber posts to composite resin core, but there were not any significant differences between these groups and control group. CONCLUSION. There was not any significant difference between two brands of fiber posts that had been used in this study. Although silanization and sandblasting can improve the TBS, there was not any significant differences between surface treatments used.

COMPARATIVE STUDY OF GAS-TO-LIQUID (GTL) AS AN ALTERNATIVE FUEL USED IN A DIRECT INJECTION COMPRESSION IGNITION ENGINE

  • Wu, T.;Huang, Z.;Zhang, W.G.;Fang, J.H.
    • International Journal of Automotive Technology
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    • v.8 no.4
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    • pp.421-428
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    • 2007
  • This paper investigates the combustion and emission characteristics of a compression ignition engine fueled with neat and blended Shell's gas-to-liquid (GTL) fuel, which was derived from natural gas through the Fischer-Tropsch process. The experiments were conducted in a 6-cylinder DI diesel engine with pump timing settings of $6^{\circ},\;9^{\circ}\;and\;12^{\circ}$crank angle before TDC over ECE R49 and US 13-mode cycles separately and compared to a conventional diesel fuel. The results show that GTL exhibited almost the same power and torque output, improved fuel economy and effective thermal efficiency. It was found that GTL displayed lower peak in-cylinder combustion pressure and maximum heat release rate (HRR), the timings of the peak pressure and the maximum HRR were generally delayed, and the combustion durations were almost equivalent for diesel and GTL under the same speed-load condition. The results also indicate that, compared to diesel fuel, GTL blends showed a trend forward decreasing four regulated emissions simultaneously and a higher GTL fraction in blends contributing to further reductions in the emissions. In particular and on average, neat GTL significantly reduced HC, CO, NOx and PM by 16.4%, 17.8%, 18.3% and 32.4%, respectively, for all cases.

Photocatalytic Property of Nano-Structured TiO$_2$ Thermal Sprayed Coating - Part II: TiO$_2$ -WO$_3$ Coating - (나노구조 TiO$_2$용사코팅의 미세조직 제어 공정기술 개발과 광촉매 특성평가 - Part II: TiO$_2$- WO$_3$ 코팅 -)

  • 이창훈;최한신;이창희;김형준;신동우
    • Journal of Welding and Joining
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    • v.21 no.4
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    • pp.46-55
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    • 2003
  • TiO$_2$-WO$_3$(8.2wt%) coatings were prepared by the APS (Atmospheric Plasma Spraying) process to clarify the relationship between the process parameters(H$_2$ gas flow rate of plasma 2nd gas and spraying distance) of the APS coating and photo-decomposition efficiency kinetics of the MB(methylene blue) aqueous solution decomposition and to understand the effect of addition of WO$_3$ on photocatalytic properties of TiO$_2$ sprayed coating. Further, the temperature and velocity of flying particles were measured by DPV-2000 to investigate the relationship between microstructure of coatings and process parameters. Properties of coatins were investigated by XRD, SEM, XPS, RAMAN, UV/VIS spectrometer. In case of the TiO$_2$-WO$_3$(8.2wt%) coating, it had a lower anatase fraction than that of pure-TiO$_2$ coatings because of flying in the higher temperature plasma plume by the heavy weight of TiO$_2$, WO$_3$. And, when WO$_3$ added powders were spayed, the doping effects of W ions substituted into the Ti ion sites was not occured during melting and solidification cycles of spraying. It was found that the addition of WO$_3$ was ineffective effective on increasing photo-decomposition efficiency of TiO$_2$ sprayed coating.

A Numerical Analysis on Transient Fuel temperatures in a Military Aircraft under Non-operating Ground Static Condition (지상 정적 상태에서의 항공기내 연료온도변화에 대한 수치해석)

  • 김영준;김창녕
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.11-16
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    • 2003
  • A numerical study was performed on the transient fuel temperatures of a military aircraft stationed under non-operating static condition. Numerical calculation was peformed by an explicit method using modified Dufort-Frankel scheme. It was assumed that the non-operating aircraft is subjected to repeated daily cycles of air temperature with the solar radiation and wind speed corresponding to the 1 % hot day ambient condition. And, the aircraft was assumed to be in turbulent flow. The convective heat transfer coefficient for turbulent flow on the flat plate suggested by Eckert was employed to calculate heat transfer between the aircraft surface and the ambience. The energy conservation equation on fuel was used as governing equation for this analysis. As a result of this analysis, the wing tank temperature showed the highest temperature and the largest rate of temperature changes among fuel tanks. The results of this analysis could be used as initial foe] temperatures for analysis of the transient fuel temperatures in various flight missions. Also, this analysis method could be used to analysis and design of an aircraft thermal energy management system.

An Estimation on Two Stroke Low Speed Diesel Engines' Shaft Fatigue Strength due to Torsional Vibrations in Time Domain (시간영역에서 과도 비틀림 진동에 의한 저속 2행정 디젤엔진의 축계 피로강도 평가)

  • Lee, Don-Chool;Kim, Sang-Hwan
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.17 no.7 s.124
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    • pp.572-578
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    • 2007
  • Two stroke low speed diesel engines are widely used for marine propulsion or as power plant prime mover. These engines have many merits which includes higher thermal efficiency, mobility and durability. Yet various annoying vibrations occur sometimes in ships or at the plant itself. Of these vibrations, torsional vibration is very important and dictates a careful investigation during the engme's initial design stage for safe operation. With the rule and limit on torsional vibration in place, shaft strength fatigue due to torsional vibration however demands further analysis which possibly can be incorporated in the classification societies' rule and limit. In addition, the shaft's torsional vibration stresses can be calculated equivalently from accumulated fatigue cycles number due to transient torsional vibration in time domain. In this paper, authors suggest a new estimation method combined with Palmgren-Miner equation. A 6S70MC-C ($25,320ps{\times}91rpm$) engine for ship propulsion was selected as a case study. Angular velocity was measured, instead of shaft's strain, for simplified measurement and it was converted to torsional vibration stress for accumulated fatigue cycle numbers in shafting life time. Likewise, the accumulated fatigue calculation was compared with shaft fatigue strength limit. This new method can be further realized and confirmed in ship with two stroke low speed diesel engine.

Immobilization of Laccase on $SiO_2$ Nanocarriers Improves Its Stability and Reusability

  • Patel, Sanjay K.S.;Kalia, Vipin C.;Choi, Joon-Ho;Haw, Jung-Rim;Kim, In-Won;Lee, Jung Kul
    • Journal of Microbiology and Biotechnology
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    • v.24 no.5
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    • pp.639-647
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    • 2014
  • Laccases have a broad range of industrial applications. In this study, we immobilized laccase on $SiO_2$ nanoparticles to overcome problems associated with stability and reusability of the free enzyme. Among different reagents used to functionally activate the nanoparticles, glutaraldehyde was found to be the most effective for immobilization. Optimization of the immobilization pH, temperature, enzyme loading, and incubation period led to a maximum immobilization yield of 75.8% and an immobilization efficiency of 92.9%. The optimum pH and temperature for immobilized laccase were 3.5 and $45^{\circ}C$, respectively, which differed from the values of pH 3.0 and $40^{\circ}C$ obtained for the free enzyme. Immobilized laccase retained high residual activities over a broad range of pH and temperature. The kinetic parameter $V_{max}$ was slightly reduced from 1,890 to 1,630 ${\mu}mol/min/mg$ protein, and $K_m$ was increased from 29.3 to 45.6. The thermal stability of immobilized laccase was significantly higher than that of the free enzyme, with a half-life 11- and 18-fold higher at temperatures of $50^{\circ}C$ and $60^{\circ}C$, respectively. In addition, residual activity was 82.6% after 10 cycles of use. Thus, laccase immobilized on $SiO_2$ nanoparticles functionally activated with glutaraldehyde has broad pH and temperature ranges, thermostability, and high reusability compared with the free enzyme. It constitutes a notably efficient system for biotechnological applications.

A Design Process for Reduction of Pressure Drop of Air-cooled Condenser for Waste Heat Recovery System (폐열 회수 시스템용 공랭식 응축기의 압력 손실 저감 설계)

  • Bae, Sukjung;Heo, Hyungseok;Park, Jeongsang;Lee, Hongyeol;Kim, Charnjung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.81-91
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    • 2013
  • A novel design process of a parallel multi-flow type air-cooled condenser of a dual-loop waste heat recovery system with Rankine steam cycles for improving the fuel efficiency of gasoline automobiles has been investigated focusing on reduction of the pressure drop inside the micro-tubes. The low temperature condenser plays a role to dissipate heat from the system by condensing the low temperature loop working fluid sufficiently. However, the refrigerant has low evaporation temperature enough to recover the waste from engine coolant of about $100^{\circ}C$ but has small saturation enthalpy so that excessive mass flow rate of the LT working fluid, e.g., over 150 g/s, causes enormously large pressure drop of the working fluid to maintain the heat dissipation performance of more than 20 kW. This paper has dealt with the scheme to design the low temperature condenser that has reduced pressure drop while ensuring the required thermal performance. The number of pass, the arrangement of the tubes of each pass, and the positions of the inlet and outlet ports on the header are most critical parameters affecting the flow uniformity through all the tubes of the condenser. For the purpose of the performance predictions and the parametric study for the LT condenser, we have developed a 1-dimensional user-friendly performance prediction program that calculates feasibly the phase change of the working fluid in the tubes. An example is presented through the proposed design process and compared with an experiment.

Properties of MFS capacitors with various gate electrodes using $LiNbO_3$ferroelectric thin film ($LiNbO_3$ 강유전체 박막을 이용한 MFS 커패시터의 게이트 전극 변화에 따른 특성)

  • 정순원;김광호
    • Journal of the Korean Vacuum Society
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    • v.11 no.4
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    • pp.230-234
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    • 2002
  • Metal-ferroelectric-semiconductor(MFS) capacitors by using rapid thermal annealed $LiNbO_3$/Si structures were successfully fabricated and demonstrated nonvolatile memory operations of the MFS capacitors. The C-V characteristics of MFS capacitors showed a hysteresis loop due to the ferroelectric nature of the $LiNbO_3$thin film. The dielectric constant of the $LiNbO_3$film calculated from the capacitance in the accumulation region in the capacitance-voltage(C-V) curve was about 25. The gate leakage current density of MFS capacitor using a platinum electrode showed the least value of $1{\times}10^{-8}\textrm{A/cm}^2$ order at the electric field of 500 kV/cm. The minimum interface trap density around midgap was estimated to be about $10^{11}/cm^2$.eV. The typical measured remnant polarization(2Pr) value was about 1.2 $\mu\textrm{C/cm}^2$, in an applied electric field of $\pm$ 300 kv/cm. The ferroelectric capacitors showed no polarization degradation up to about $10^{10}$ switching cycles when subjected to symmetric bipolar voltage pulse in the 500 kHz.

Characteristics of electrodes using V-Ti based hydrogen storage alloys (V-Ti계 수소저장합금의 전극특성)

  • 김주완;이성만;백홍구
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.284-291
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    • 1997
  • The electrode characteristics of two kinds of metal hydride electrodes using V-Ti (V-rich) based alloy were studied, in which one electrode was prepared by sintering the mixture of V-Ti alloy and Ni powders by a rapid thermal annealing technique and the other one was prepared using V-Ti-Ni ternary alloy, The discharge capacities of all electrodes during the charge-discharge cycling were completely deteriorated within 10 cycles. It appeared that the deterioration of the electrodes was caused by the dissolution of V in the near-surface region into the electrolyte and the formation of $TiO_2$ layer on the alloy particle surface. This degradation mechanism was supported by the facts that V is main hydride forming element and $TiO_2$ has very low electrical conductivity and hydrogen diffusivity.

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Practical Application of Sn-3.0Ag-0.5Cu Lead Free Solder in Electronic Production

  • Chae Kyu-Sang;Min Jae-Sang;Kim Ik-Joo;Cho Il-Je
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.1 s.34
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    • pp.65-71
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    • 2005
  • At present, Electronic industries push ahead to eliminate the Pb(Lead) -a hazardous material-from all products. Especially, we have performed to select the optimum standard composition of lead free alloy for the application to products for about 3 years from 2000. These days, we have the chance for applying to the mass-production. This project constructed the system for applying the lead free solders on consumer electronic products, which is one of the major products of the LG Electronics. To select the lead free solders with corresponding to the product features, we have passed through the test and applied with Sn-3.0Ag-0.5Cu alloy system to our products, and for the application to the high melting temperature composition, we secured the thermal resistance of the many parts and substrate and optimized the processing conditions. We have operated the temperature cycling test and the high temperature storage test under the standards to confirm the reliability of the products. On these samples, we considered the consequence of our decision by the operating test. For the long life time of the product, we have operated the temperature cycling test at $-45^{\circ}C\;-\;+125^{\circ}C$, 1 cycle/hour, 1000 cycles. Also we have tested the tin whisker growth about lead free plating on lead finish. We have analyzed with the SEM, EDS and any other equipment for confirming the failure mode at the joint and the tin whisker growth on lead free finish.

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