• Composites Research
• /
• 제33권2호
• /
• pp.81-89
• /
• 2020

본 리뷰 논문에서는 최근에 연구된 평균장 균질화법을 이용한 다양한 물성치 예측 연구의 동향에 대해 소개한다. 유효 강성 예측에 사용되는 기존의 균질화법을 소개하고 이를 확장하여 유효 열/전기 전도성 및 유전 상수를 예측하는 방법을 소개한다. 압전 및 열전과 같이 2개의 물리현상이 중첩된 다중 물리 현상의 구성방정식은 훅 법칙과 같이 단순한 선형 형태로 변환하여 복합재의 유효 물성치를 예측하는 연구를 소개하고 마지막으로 복합 재료의 유효 물성치를 예측하기 위한 일반화된 식을 제시하고 유한 요소 해석과 비교한 검증/연구를 소개한다.

• Steel and Composite Structures
• /
• 제49권5호
• /
• pp.587-602
• /
• 2023

This article presents the numerical modelling of transient heat transfer in highly heterogeneous composite materials where the thermal conductivity, specific heat and density are assumed to be directional-dependent. This article uses a coupled finite element-finite difference scheme to perform the transient heat transfer analysis of unidirectional (1D) and multidirectional (2D/3D) functionally graded composite panels. Here, 1D/2D/3D functionally graded structures are subjected to nonuniform heat source and inhomogeneous boundary conditions. Here, the multidirectional functionally graded materials are modelled by varying material properties in individual or in-combination of spatial directions. Here, fully spatial-dependent material properties are evaluated using Voigt's micromechanics scheme via multivariable power-law functions. The weak form is obtained through the Galerkin method and solved further via the element-space and time-step discretisation through the 2D-isoparametric finite element and the implicit backward finite difference schemes, respectively. The present model is verified by comparing it with the previously reported results and the commercially available finite element tool. The numerous illustrations confirm the significance of boundary conditions and material heterogeneity on the transient temperature responses of 1D/2D/3D functionally graded panels.

• Applied Microscopy
• /
• 제47권3호
• /
• pp.131-147
• /
• 2017

In this work further optical and electrical investigations of pure and Zr doped $Mn_3O_4$ (from 0 up to 20 at.%) thin films as a function of frequency. First, the refractive index, the extinction coefficient and the dielectric constants in terms of Zr content are reached from transmittance and reflectance data. The dispersion of the refractive index is discussed by means of Cauchy model and Wemple and DiDomenico single oscillator models. By exploiting these results, it was possible to estimate the plasma pulse ${\omega}_p$, the relaxation time ${\tau}$ and the dielectric constant ${\varepsilon}_{\infty}$. Second, we have performed original ac and dc conductivity studies inspired from Jonscher model and Arrhenius law. These studies helped establishing significant correlation between temperature, activation energy and Zr content. From the spectroscopy impedance analysis, we investigated the frequency relaxation phenomenon and hopping mechanisms of such thin films. Moreover, a special emphasis has been putted on the effect of the oxidation in air of hausmannite thin films to form $Mn_2O_3$ ones at $350^{\circ}C$. This intrigue phenomenon which occurred at such temperature is discussed along with this electrical study. Finally, all results have been discussed in terms of the thermal activation energies which were determined with two methods for both undoped and Zr doped $Mn_3O_4$ thin films in two temperature ranges.

• 한국세라믹학회지
• /
• 제44권7호
• /
• pp.343-348
• /
• 2007

Alumina/silver nanocomposites were fabricated using a soaking method through a sol-gel route to construct an intra-type nanostructure. The pulse electric-current sintering (PECS) technique was used to sinter the nanocomposites. Several specimens were annealed after sintering. The microstructure, mechanical properties, critical frontal process zone (FPZ) size, and thermo-mechanical properties of the nanocomposites were estimated. The relative densities of the specimens sintered at 1350 and $1450^{\circ}C$ were 95% and 99%, respectively. The maximum value of the three-point bending strength was found to be 780 MPa for the $2{\times}2{\times}10 mm$ specimen sintered at $1350^{\circ}C$. The fracture toughness of the specimen sintered at $1350^{\circ}C$ was measured to be $3.60 MPa{\cdot}m^{1/2}$ using the single-edge V-notched beam (SEVNB) technique. The fracture mode of the nanocomposites was transgranular, in contrast to the intergranular mode of monolithic alumina. The fracture morphology suggested that dislocations were generated around the silver nanoparticles dispersed within the alumina matrix. The specimens sintered at $1350^{\circ}C$ were annealed at $800^{\circ}C$ for 5 min, following which the maximum fracture strength became 810 MPa and the fracture toughness improved to $4.21 MPam^{1/2}$. The critical FPZ size was the largest for the specimen annealed at $800^{\circ}C$ for 5 min. Thermal conductivity of the alumina/silver nanocomposites sintered at $1350^{\circ}C$ was 38 W/mK at room temperature, which was higher than the value obtained with the law of mixture.

• Bulletin of the Korean Chemical Society
• /
• 제17권9호
• /
• pp.794-798
• /
• 1996

Solid solutions of the nonstoichiometric Dy1-xSrxCoO3-y system with the compositions of x=0.00, 0.25, 0.50, 0.75, and 1.00 have been synthesized by the solid state reaction at 1000 ℃ under atmospheric air pressure. The crystallographic structures of the solid solutions are analyzed by the powder X-ray diffraction patterns at room temperature. The analyses assign the compositions of x=0.00 and 0.25 to the orthorhombic system with space group of Pbnm/D2h16, the compositions of x=0.50 and 0.75 to the tetragonal system like a typical SrCoO2.86, and the composition of x=l.00 or SrCoO2.50 to the brownmillerite type system with space group of I**a. The reduced lattice volumes increase with x value due to the larger radius of Sr2+ ion than that of Dy3+ ion. The mole ratio of Co4+ ion to total Co ion with mixed valence state between Co3+ and Co4+ ions at B sites or τ value has been determined by an iodometric titration. All the samples except for the DyCoO3 compound show the mixed valnce state and thus the composition of x=0.50 has the maximum τ value in the system. The oxygen vacancies increasing with x value are randomly distributed over the crystal lattice except for the composition of x=l.00 which have the ordering of the oxygen vacancies. The nonstoichiometric chemical formulas of the Dy1-xSrxCo3+1-τCo4+τO3-(x-τ)/2 system are formulated from the x, τ, and y values. The electrical conductivity in the temperature range of 100 to 900 K increases with τ value linearly because of positive holes of the Co4+ ions in π* band as a conducting carrier. The activation energy of the x=0.50 as Ea=0.17 eV is minimum among other compouds. Broad and high order transition due to the overlap between σ* and π* bands broadened by the thermal activation is observed near 1000 K and shows a low temperature-semiconducting behavior. Magnetic properties following the Currie-Weiss law show the low to high spin transition in the cobaltate perovskite. Especially, the composition of x=0.75 presents weak ferromagnetic behavior due to the Co3+-O2--Co4+ indirect superexchange interaction.