• Title/Summary/Keyword: Thermal barrier coating

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추력 30톤급 연소기의 냉각 성능

  • Cho, Won-Kook;Lee, Soo-Yong;Cho, Gwang-Rae
    • Aerospace Engineering and Technology
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    • v.3 no.1
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    • pp.197-204
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    • 2004
  • A design of regenerative cooling system of 30 ton level thrust combustion chamber for ground test has been performed. The 1-D design code has been validated by comparing with the heat flux of the NAL calorimeter for high chamber pressure and water-cooling performance of the ECC engine of MOBIS. The present design code has been confirmed to predict accurately the heat flux and water-cooling performance for high chamber pressure condition. The maximum hot-gas-side wall temperature is predicted to be about 720 K without thermal barrier coating and the coolant-side wall temperature is less than the coking temperature of RP-1. The coolant temperature rises nearly 100 K with thermal barrier coating when Jet-A1 is used as coolant.

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Analysis and structural design of various turbine blades under variable conditions: A review

  • Saif, Mohd;Mullick, Parth;Imam, Ashhad
    • Advances in materials Research
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    • v.8 no.1
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    • pp.11-24
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    • 2019
  • This paper presents a review study for energy-efficient gas turbines (GTs) with cycles which contributes significantly towards sustainable usage. Nonetheless, these progressive engines, operative at turbine inlet temperatures as high as $1600^{\circ}C$, require the employment of highly creep resistant materials for use in hotter section components of gas turbines like combustion chamber and blades. However, the gas turbine obtain its driving power by utilizing the energy of treated gases and air which is at piercing temperature and pushing by expanding through the several rings of steady and vibratory blades. Since the turbine blades works at very high temperature and pressure, high stress concentration are observed on the blades. With the increasing demand of service, to provide adequate efficiency and power within the optimized level, turbine blades are to be made of those materials which can withstand high thermal and working load condition for longer cycle time. This paper depicts the recent developments in the field of implementing the best suited materials for the GTs, selection of proper Thermal Barrier Coating (TBC), fracture analysis and experiments on failed or used turbine blades and several other designing and operating factors which are effecting the blade life and efficiency. It is revealed that Nickel based Superalloys were promising, Cast Iron with Zirconium and Pt-Al coatings are used as best TBC material, material defects are the foremost and prominent reason for blade failure.

The heat treatment characteristics of plasma sprayed ZrO$_2$-Y$_2$O$_3$ coatings (플라즈마 용해법에 의한 ZrO$_2$-Y$_2$O$_3$ 피복층의 가열처리효과)

  • 정병근;김한삼;김수식
    • Journal of the Korean institute of surface engineering
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    • v.27 no.1
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    • pp.12-18
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    • 1994
  • The plasma spray process was used to deposit coatings of $ZrO_2$-8wt%Y2O3 powders on mild steel sub-strate, and the characteristics of as-deposited and heat treated coatings have been investigated. Particulary, the variations of porosity, wear resistance, thermal barrier and thermal shock resistance in $ZrO_2$-8wt% $Y_2O_3$coatings after heat treatment under vacuum circumstance have been investigated. The porosity of the coating layer was increased with increased spray distance. In the case of the arc current of 450A and at the spray distance of 50mm, it was obtained the lowest amount of porosity. After heat treatment, the amount of porosity was found to be decreased, and the wear resistance, microhardness and thermal shock resistance were im-proved. However, the thermal barrier was decreased.

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A Study on the Thermal Shock Resistance of Sintered Zirconia for Electron Beam Deposition (전자빔 증착을 위한 소결체 지르코니아의 열충격 저항성 연구)

  • Oh, Yoonsuk;Han, Yoonsoo;Chae, Jungmin;Kim, Seongwon;Lee, Sungmin;Kim, Hyungtae;Ahn, Jongkee;Kim, Taehyung;Kim, Donghoon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.3
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    • pp.83-88
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    • 2015
  • Coating materials used in the electron beam (EB) deposition method, which is being studied as one of the fabrication methods of thermal barrier coating, are exposed to high power electron beam at focused area during the EB deposition. Therefore the coating source for EB process is needed to form as ingot with appropriate density and microstructure to sustain their shape and stable melts status during EB deposition. In this study, we tried to find the optimum powder condition for fabrication of ingot of 8 wt% yttria stabilized zirconia which can be used for EB irradiation. It seems that the ingot, which is fabricated through bi-modal type initial powder mixture which consists of tens of micro and nano size particles, was shown better performance than the ingot which is fabricated using monolithic nanoscale powder when exposed to high power EB.

Corrosion Behavior of Ytterbium Silicates in Water Vapor Atmosphere at High Temperature for Environmental Barrier Coating Applications (환경차폐코팅용 이터븀 실리케이트의 고온 수증기부식 거동)

  • Min-Ji Kim;Jae-Hyeong Choi;Seongwon Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.6
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    • pp.443-450
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    • 2023
  • SiC/SiCf CMC is vulnerable to water vapor corrosion at a high temperature of 1500℃. So, EBC (Environmental Barrier Coating) materials are required to protect Si-based CMCs. Ytterbium silicates are reported to have coefficient of thermal expansion (CTE) similar to that of the base material, such as SiC/SiCf CMC. When the EBC are materials exposed to high temperature environment, the interface between ytterbium silicates and SiC/SiCf CMC is not separated, and the coating purpose can be safely achieved. For the perspective of EBC applications, thermally grown oxide (TGO) layer with different CTE is formed by the reaction with water vapor in EBC, which leads to a decrease in life time. In this study, we prepare two types of ytterbium silicates to observe the corrosion behavior during the expose to high temperature and water vapor. In order to observe this behavior, the steam-jet furnace is prepared. In addition, phase formation of these ytterbium silicates is analyzed with microstructures by the before/after steam-jet evaluation at 1500℃ for 100 h.

Electrochemical Properties of LiNi0.8Co0.16Al0.04O2 and Surface Modification with Co3(PO4)2 as Cathode Materials for Lithium Battery

  • Ryu, Kwang-Sun;Lee, Sang-Hyo;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.29 no.9
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    • pp.1737-1741
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    • 2008
  • The electrochemical and thermal stability of $LiNi_{0.8}Co_{0.16}Al_{0.04}O_2$ were studied before and after $Co_3(PO_4)_2$ coating. Different to conventional coating material such as $ZrO_2$ or AlPO4, the coating layer was not detected clearly by TEM analysis, indicating that the $Co_3(PO_4)_2$ nanoparticles effectively reacted with surface impurities such as $Li_2CO_3$. The coated sample showed similar capacity at a low C rate condition. However, the rate capability was significantly improved by the coating effect. It is associated with a decrease of impedance after coating because impedance can act as a major barrier for overall cell performances in high C rate cycling. In the DSC profile of the charged sample, exothermic peaks were shifted to high temperatures and heat generation was reduced after coating, indicating the thermal reaction between electrode and electrolyte was sucessfully suppressed by $Co_3(PO_4)_2$ nanoparticle coating.

Corrosion Performance of Al and Zn Coatings Deposited by Arc Thermal Spray Process in 3.5 wt.% NaCl-Contaminated Concrete Pore Solution (3.5wt.% NaCl로 오염된 콘크리트 기공 용액에서 아크 용사 공정에 의해 부착된 Al 및 Zn 코팅의 부식 성능)

  • Singh, Jitendra Kumar;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.59-60
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    • 2023
  • The corrosion of steel rebar embedded in the coastal areas is corroding once the chloride ions ingress through the pores of the concrete. Therefore, in the present study, a 100 ㎛ thick Al and Zn coating was deposited by an arc thermal spray process onto the steel. The corrosion studies of these deposited coatings were assessed in 3.5 wt.% NaCl contaminated concrete pore (CP) solution with immersion periods. The results show that the Al coating is more corrosion resistance compared to the Zn coating attributed to the formation of gibbsite (γ-Al(OH)3) whereas Zn coating exhibits Zn(OH)2 onto the coating surface as passive layer. The Zn(OH)2 is readily soluble in an alkaline solution. Alternatively, γ-Al(OH)3 on the Al coating surface is less solubility in the alkaline pH, which further provides barrier protection against corrosion.

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Electrochemical Characteristics in Sea Water of Al-3%Mg Arc Spray Coating Layer for Corrosion Protection with Sealing Treatment (후처리 적용에 따른 방식용 Al-3%Mg 용사코팅 층의 해수 내 전기화학적 특성)

  • Park, Il-Cho;Kim, Seong-Jong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.40 no.5
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    • pp.974-980
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    • 2015
  • Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.

Sand particle-Induced deterioration of thermal barrier coatings on gas turbine blades

  • Murugan, Muthuvel;Ghoshal, Anindya;Walock, Michael J.;Barnett, Blake B.;Pepi, Marc S.;Kerner, Kevin A.
    • Advances in aircraft and spacecraft science
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    • v.4 no.1
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    • pp.37-52
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    • 2017
  • Gas turbines operating in dusty or sandy environment polluted with micron-sized solid particles are highly prone to blade surface erosion damage in compressor stages and molten sand attack in the hot-sections of turbine stages. Commercial/Military fixed-wing aircraft engines and helicopter engines often have to operate over sandy terrains in the middle eastern countries or in volcanic zones; on the other hand gas turbines in marine applications are subjected to salt spray, while the coal-burning industrial power generation turbines are subjected to fly-ash. The presence of solid particles in the working fluid medium has an adverse effect on the durability of these engines as well as performance. Typical turbine blade damages include blade coating wear, sand glazing, Calcia-Magnesia-Alumina-Silicate (CMAS) attack, oxidation, plugged cooling holes, all of which can cause rapid performance deterioration including loss of aircraft. The focus of this research work is to simulate particle-surface kinetic interaction on typical turbomachinery material targets using non-linear dynamic impact analysis. The objective of this research is to understand the interfacial kinetic behaviors that can provide insights into the physics of particle interactions and to enable leap ahead technologies in material choices and to develop sand-phobic thermal barrier coatings for turbine blades. This paper outlines the research efforts at the U.S Army Research Laboratory to come up with novel turbine blade multifunctional protective coatings that are sand-phobic, sand impact wear resistant, as well as have very low thermal conductivity for improved performance of future gas turbine engines. The research scope includes development of protective coatings for both nickel-based super alloys and ceramic matrix composites.

Phase Formation and Thermo-physical Properties of GdO1.5-ZrO2 System for Thermal Barrier Coating Application (열차폐코팅용 GdO1.5-ZrO2계 희토류 지르코네이트 세라믹스의 상형성과 열물리 특성)

  • Kim, Sun-Joo;Lee, Won-Jun;Kwon, Chang-Sup;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Im, Dae-Soon;Kim, Seongwon
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.554-559
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    • 2014
  • Gadolinium zirconate, $Gd_2Zr_2O_7$, is one of the most promising candidates for replacing yttira-stabilized zirconia (YSZ) in thermal barrier coating (TBC) applications due to its low thermal conductivity and chemical stability at high temperature. In this study, rare-earth zirconate ceramics in the $GdO_{1.5}-ZrO_2$ system with reduced gadolinia contents were fabricated via solid-state reaction as well as hot-pressing at $1800^{\circ}C$. The phase formation, microstructure, and thermo-physical properties of these oxides were examined. The potential application of $GdO_{1.5}-ZrO_2$ ceramics for TBC was also discussed.