• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.19-24
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• 2020

In this study, the O/W emulsions prepared from coconut oil and the non-ionic mixed surfactant as Tween-Span system were evaluated and optimized in order to upgrade the stability of manufactured emulsions. For the optimization, a central composite design model-response surface methodology, so called as CCD-RSM was implemented. Quantitative factors were the hydrophile-lipophilie balance (HLB), amount of non-ionic mixed surfactant and emulsification speed while experimental results included the mean droplet size (MDS), emulsion stability index (ESI), and thermal instability index (TII). Optimized values of the HLB, amount of non-ionic mixed surfactant and emulsification speed obtained from CCD-RSM were 9.1, 8.7 wt.%, and 6,200.8 rpm, respectively. Expected experimental results for MDS, ESI, and TII under the optimized experimental condition were 151.0 nm, 99.86, and 3.17%, respectively. The average error from actual experiments which established for validation of the conclusions was lower than 3.5%. Therefore, a highly favorable level could be obtained when the optimized CCD-RSM was applied to manufacturing the O/W emulsion in this study.

• Clean Technology
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• v.19 no.4
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• pp.355-369
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• 2013

Economic feasibility is one of the most important factors in energy production from regenerative biomass. From the aspect, biogas from anaerobic digestion of wastewater sludge is regarded as the most economical because of its cheap substrate and additional income from the disposal of waste sludge. Sludge hydrolysis has been regarded as the rate limiting step of anaerobic digestion and many sludge pre-treatment technologies have been developed to accelerate anaerobic sludge digestion for enhanced biogas production. Various sludge pre-treatment technologies including biological, thermo hydrolysis, ultrasonic, and mechanical methods have been applied to full-scale systems. Sludge pre-treatment increased the efficiency of anaerobic digestion by enhancing hydrolysis, reducing residual soilds, and increasing biogas production. This paper introduces the characteristics of various sludge pre-treatment technologies and the energy balance and economic feasibility of each technology were compared to prepare a guideline for the selection of feasible pre-treatment technology. It was estimated that thermophilic digestion and thermal hydrolysis were most economical technology followed by Cell rupture$^{TM}$, OpenCEL$^{TM}$, MicroSludge$^{TM}$, and ultrasound. The cost for waste sludge disposal shares the biggest portion in the economic analysis, therefore, water content of the waste sludge was the most important factor to be controlled.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.1
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• pp.419-425
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• 2019

The objective of this study was to investigate the cooling performance characteristics of a hybrid refrigeration system in a heavy duty vehicle. The tested hybrid refrigeration system had additionally an electric compressor besides the present mechanical compressor for selective use according to the operating conditions. The applied electric compressor was a scroll type and with 18.0 cc displacement. In order to analyze the performance characteristics of the hybrid refrigeration system with respect to the cooling capacity and Coefficient of Performance (COP), other components, including two different types of compressors, were installed and tested under various operating conditions such as compressor speed and air flow rate of the evaporator. When the electric compressor was operated at 4,500 rev/min, the cooling capacity was about 4.0kW and COP was 3.5. When the mechanical compressor was operated, whereas the cooling capacity was higher than the electric controlled compressor, COP was lower due to the larger displacement and higher power consumption. To analyze the hybrid system operating characteristics due to reasonable cooling capacity with electric compressor operation, the mechanical compressor and electric compressor were operated by turns every 10 minutes under certain system operating conditions. Because surge pressure occurred when both compressors were switched on, the operating strategy required some time to balance the system pressure.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.250-250
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• 2012

Organic light-emitting diodes (OLED) and polymer light emitting diodes (PLED) have been regarded as the candidate for the next generation light source and flat panel display. Currently, the most common OLED industrial fabrication technology used in producing real products utilizes a fine shadow mask during the thermal evaporation of small molecule materials. However, due to high potential including low cost, easy process and scalability, various researches about solution process are progressed. Since polymer has some disadvantages such as short lifetime and difficulty of purifying, small molecule OLED (SMOLED) can be a good alternative. In this work, we have demonstrated high efficient solution-processed OLED with small molecule. We use CBP (4,4'-N,N'-dicarbazolebiphenyl) as a host doped with green dye (Ir(ppy)3 (fac-tris(2-phenyl pyridine) iridium)). PBD (2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole) and TPD (N,N'diphenyl-N,N'-Bis (3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine) are employed as an electron transport material and a hole transport material. And TPBi (2,2',2''-(1,3,5-phenylene) tris (1-phenyl-1H-benzimidazole)) is used as an hole blocking layer for proper hole and electron balance. With adding evaporated TPBi layer, the current efficiency was very improved. Among various parameters, we observed the property of OLED device by changing the thickness of hole transporting layer and solvent which can dissolve organic material. We could make small molecule OLED device with finding proper conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.111.1-111.1
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• 2010

This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

• Transactions of the KSME C: Technology and Education
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• v.4 no.1
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• pp.49-56
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• 2016

Commercial buildings are generally cooling-dominated and therefore reject more heat to a vertical ground heat exchanger(GHE) than they extract over the annual cycle. Shallow ponds can provide a cost-effective means to balance the thermal loads to the ground and to reduce the length of GHE. The objective of this work has been to develop a design tool for surface water heat exchanger(SWHE) submerged in shallow pond. This paper presents the analysis results of the impact of design parameters on the length of SWHE and its application effect on geothermal heat pump(GHP) system using vertical GHE. In order to analysis, We applied ${\epsilon}-NTU$ method on designing the length of SWHE. Analysis results show that the required pipe length of SWHE was decreased with the increase of approach temperature difference and with the decrease of pipe wall thickness. In addition, when the SWHE was applied to the GHP system, the temperature of vertical GHE was more stable than that of standalone GHE system.

• Particle and aerosol research
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• v.9 no.4
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• pp.231-238
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• 2013

Carbon nanotubes (CNTs) are one of the nanomaterials that were discovered by Iijima in 1991 for the first time. CNTs have long cylindrical and axi-symmetric structures. CNTs are made by rolling graphene sheets. Because of their large length-to-diameter ratio, they are called nanotubes. CNTs are categorized as single-walled carbon nanotubes (SWCNTs) or multi-walled carbon nanotubes (MWCNTs) based on the shell structures. CNTs are broadly used in various fields, such as scanning probe microscopy, ultra fine nano balance and medicine, due to their extraordinary thermal conductivity, electrical and mechanical properties. Because long, straight CNTs have the same shape as asbestos, which cause cancer in cells lining the lung, there have been many studies on the effects of MWCNTs on human health that have been conducted. Stable atomization of CNTs is very important for the estimation of inhalation toxicity. In the present study, electro-static assisted axial atomizer (EAAA), which is the instrument that uses MWCNTs and aerosolizes them by transforming the single fiber shape using ultrasonic dispersion and electric field, was invented. EAAA consists of a ultrasonic bath for dispersion of MWCNTs and a particle generator for atomizing single fibers. The performance evaluation was conducted in order to assess the possibilities of 6-hour straight atomization with stability, which is the suggested exposure time in a day for the estimation of inhalation toxicity.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.9 s.240
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• pp.1022-1031
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• 2005

Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to obtain an appropriate calibration curve for determining primary particle size by comparing the gated signal ratio and double-exponential curve fitting methods. Not only the effects of laser fluence and gas temperature on the cooling behavior but also heat transfer mechanisms of heated soot particle have been investigated. The second-order exponential curve fitting showed better agreements with the LII signals than the gated signal ratio method which was based on the lust-order exponential curve fit. And the temporal decay rate of the LII signal and primary particle size showed nearly linear relationship, which was little dependent on the laser fluence. And it also could be reconfirmed that vaporization was dominant process of heat loss during first loons after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.2
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• pp.150-157
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• 2014

Li-Ion battery is used in the most satellites now due to advantages such as weight, thermal dissipation and self discharge compared to the previous generations of electrochemical batteries. The performance analysis model of the Li-Ion battery is needed to aid the design of new satellite electrical power subsystem. This paper develops the performance analysis model of the Li-Ion battery to apply to the electrical power subsystem design and energy balance analysis on geostationary orbit. The analysis model receives the satellite bus power, solar array power and battery temperature and gives the battery voltage, charge and discharge currents, taper index, state of charge and power dissipation. The results from the performance analysis are compared and analyzed with the flight data to verify the model. The compared results show satisfactory without significant difference with the flight data.

• Journal of the korean Society of Automotive Engineers
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• v.7 no.4
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• pp.1-8
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• 1985

인류에 필수불가경한 에너지는, 석유, 석탄과 같은 화석연료에 의한 염에너지와 수력, 조력, 파력, 풍력 등의 비열에너지가 있으나, 에너지이용량중 열에너지가 절대적 우위를 점하고 있다. 열에너 지는 전기한 화석연료 뿐만 아니라, 태양집, 태양열발전소와 같은 태양열에너지의 직접이용, 핵에 너지의 열에너지전환, 지열, 해수의 온도차이용등, 열에너지는 다량하면서 막대한 에너지량을 보 유하고 있는 실정이지만, ㅈ로 석유자원에 의존하여 온 것이 현상이다. 그러나, 1970년대 초기에 엄습한 석유파동이래, 세계적으로 에너지위기감에 사로잡혀, 세계각국은 탈석유화에 따른 에너지 의 다양화와 에너지절약이 감소되게 되었다. 연료절약에 관하여 말하면, 에너지이요의 효율화를 적극적으로 도모함에 있어서 열에너지이용에 관한 평가방법에 새로운 검토가 가해져서, 더 합 리적인 평가방법의 확립이 필요하게 되었다. 이를 위해서는 종래의 열역학 제1법칙에 의한 열 에너지의 양적평가 뿐만 아니라, 열역학 제2법칙에 의한 질적평가의 중요성이 인식되어, 유효에 너지(available energy) 또는 엑세르기(Exergie)의 개념이 위상되고 있다. 물론 이 개념을 적용 하여 열역학 제2법칙에 의한 해석에 따른 일정산(heat balance)에 있어서 전혀 새로운 결과가 얻어지는 것은 아니지만, 지금까지는 열정산에 있어서 열역학 제1법칙에 의한 평가방법만이 강 조되어, 열역학 제2법칙에 의한 평가방법은 거의 도외시되어온 것이 실정이며, 우리나라에서 발 간되는 열역학에 관한 도서에서도 이에 관한 검토 내용이 거의 찾아볼수 없거나, 가령 언급된 것이 있다 하더라도 그 내용이 간략하여 그 중요성이 경시되어온 것이 사실이다. 그러나 열역학 제2법칙에 의한 에너지정산에 의하여, 제1법칙에 의한 것보다 열에너지의 합리적이고 또한 유 효한 과학적평가가 가능하게 되어, 장치나 기기의 개선에 구체적이면서 합리적인 지침이 주어 지게 된다. 그리하여 이들 개념과 방법의 소개가 필요하다고 생각되어, 지금부터 우리들이 잘 아는 용어를 사용하여 해설을 서로 하기로 한다.