• Title/Summary/Keyword: Thermal activation

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Dopant activation by using CW laser for LTPS processing

  • Kim, Ki-Hyung;Kim, Eun-Hyun;Ku, Yu-Mi;Park, Seong-Jin;Uchiike, Heiju;Kim, Chae-Ok;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.310-313
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    • 2005
  • CW laser dopant activation (CLDA) is suggested as an alternative to conventional thermal annealing. The sheet resistance of the ion doped poly-Si after CLDA is sufficiently low compared to the value measured after thermal annealing. The surface damage due to ion doping on the poly-Si can be recovered while CW laser scan for dopant activation. Therefore, the CLDA can be applied to LTPS processing.

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Synthesis of Fe-TiB2 Nanocomposite by a combination of mechanical activation and heat treatment

  • Hyunh, Xuan Khoa;Nguyen, Quoc Tuan;Kim, Ji-Sun;Gang, Tae-Hun;Kim, Jin-Cheon;Gwon, Yeong-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.91.2-91.2
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    • 2012
  • The TiB2-reinforced iron matrix nanocomposite (Fe-TiB2) was in-situ fabricated from titanium hydride (TiH2) and iron boride (FeB) powders by a simple and cost-effective process that combines the mechanical activation (MA) and a subsequent heat treatment (HT). Effect of milling factors and synthesized temperatures on the formation of the nanocomposite were presented and discussed. A differential thermal analyser (DSC-TG) was employed for examination of thermal behavior of MAed powders. Phases of the nanocomposite were confirmed by X-ray diffraction analysis (XRD). The morphologies and microstructure of nanocomposite were investigated by field emission-scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDS). Phase composition and distribution were analyzed by electron probe X-ray microanalysis (EPMA). Results showed that TiB2 particles formed in nanoscale were uniformly distributed in alloyed Fe matrix.

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Thermal Aging Behaviors of Weather Resistant Rubber Composites of EPDM, IIR, and BIIR (EPDM, IIR, 그리고 BIIR 내후성 고무 복합체의 열노화 거동)

  • Choi, Sung-Seen;Kim, Jong-Chul
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.148-155
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    • 2012
  • EPDM, IIR, and BIIR composites were thermally aged and the crosslink density changes were investigated. Crosslink densities of the EPDM composite increased with increasing the aging time and temperature, whereas those of IIR and BIIR composites for long-term aging at high temperatures tended to decrease. Activation energies for the crosslink density changes of the EPDM composite were higher than those of the BIIR one. The experimental results were explained with the number of allylic hydrogens, activation of the zinc complex, the steric hindrance effect, and oxidation of rubber chain.

Electrochemical Capacitance of Activated Carbons Regenerated using Thermal and Chemical Activation

  • Park, Jung Eun;Lee, Gi Bbum;Hwang, Sang Youp
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.339-345
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    • 2021
  • Spent activated carbons (SACs) collected from a water treatment plant were regenerated and then adopted as electrochemical material in capacitors. The SACs used in this study were regenerated via two steps, namely thermal and chemical activation. However, during the activation process, the adsorbates were converted into ashes, which caused pore blockage and decreased specific surface area. The regenerated SACs were washed with acid solutions with different levels of acidity (strong: HCl, mild: H3PO4, and weak: H2O2) to remove the ashes. The regenerated SACs washed with HCl exhibited the highest specific surface area, although their capacitance was not the highest. Conversely, the specific surface area of regenerated SACs washed using H3PO4 was slightly lower than that of HCl, but exhibited higher capacitance and electrochemical stability. Although the strong acid removed the generated ashes in the pores efficiently, it could adversely affect their structural stability, which would lead to lower capacitance.

Encapsulation of Semiconductor Gas Sensors with Gas Barrier Films for USN Application

  • Lee, Hyung-Kun;Yang, Woo Seok;Choi, Nak-Jin;Moon, Seung Eon
    • ETRI Journal
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    • v.34 no.5
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    • pp.713-718
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    • 2012
  • Sensor nodes in ubiquitous sensor networks require autonomous replacement of deteriorated gas sensors with reserved sensors, which has led us to develop an encapsulation technique to avoid poisoning the reserved sensors and an autonomous activation technique to replace a deteriorated sensor with a reserved sensor. Encapsulations of $In_2O_3$ nanoparticles with poly(ethylene-co-vinyl alcohol) (EVOH) or polyvinylidene difluoride (PVDF) as gas barrier layers are reported. The EVOH or PVDF films are used for an encapsulation of $In_2O_3$ as a sensing material and are effective in blocking $In_2O_3$ from contacting formaldehyde (HCHO) gas. The activation process of $In_2O_3$ by removing the EVOH through heating is effective. However, the thermal decomposition of the PVDF affects the property of the $In_2O_3$ in terms of the gas reactivity. The response of the sensor to HCHO gas after removing the EVOH is 26%, which is not significantly different with the response of 28% in a reference sample that was not treated at all. We believe that the selection of gas barrier materials for the encapsulation and activation of $In_2O_3$ should be considered because of the ill effect the byproduct of thermal decomposition has on the sensing materials and other thermal properties of the barrier materials.

Neutron activation analysis: Modelling studies to improve the neutron flux of Americium-Beryllium source

  • Didi, Abdessamad;Dadouch, Ahmed;Jai, Otman;Tajmouati, Jaouad;Bekkouri, Hassane El
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.787-791
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    • 2017
  • Americium-beryllium (Am-Be; n, ${\gamma}$) is a neutron emitting source used in various research fields such as chemistry, physics, geology, archaeology, medicine, and environmental monitoring, as well as in the forensic sciences. It is a mobile source of neutron activity (20 Ci), yielding a small thermal neutron flux that is water moderated. The aim of this study is to develop a model to increase the neutron thermal flux of a source such as Am-Be. This study achieved multiple advantageous results: primarily, it will help us perform neutron activation analysis. Next, it will give us the opportunity to produce radio-elements with short half-lives. Am-Be single and multisource (5 sources) experiments were performed within an irradiation facility with a paraffin moderator. The resulting models mainly increase the thermal neutron flux compared to the traditional method with water moderator.

The characteristics of mineral hydrate insulation material using activated cement prepared from pilot plant activation system

  • Seo, Sung Kwan;Chu, Yong Sik;Kim, Tae Yeon;Kim, Yoo
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.428-433
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    • 2018
  • In this study, using the pilot plant activation system, the activated cement has been manufactured and then applied to the manufacturing process of mineral hydrate insulating material. The fineness of the activated cement is controlled at $5,000cm^2/g$ and $7,500cm^2/g$ and the features of mineral hydrate insulating material, using OPC and the activated cement for each degree of fineness, has been analyzed. As the result of analyzing the crystal habit of the manufactured mineral hydrate insulting material, it is analyzed that the main crystal phase of specimen is tobermorite and some quartz peak has been detected. As the degree of fineness of the activated cement increases, the height of bubble of slurry increases as well, whereas the tendency for the density character to decrease has been detected. Along with it, as the density character decreases, the compression strength has decreases, whereas the tendency for the thermal characteristic to increases has been detected. The main features of mineral hydrate insulating material, using the activated cement with the fineness of $7,500cm^2/g$, the compression strength of 0.36 MPa, and the thermal conductivity of $0.044W/m{\cdot}K$, presents the excellent features as insulation.

Influence of the Cure Systems on Long Time Thermal Aging Behaviors of NR Composites

  • Choi, Sung-Seen;Kim, Jong-Chul;Lee, Seung-Goo;Joo, Yong-L.
    • Macromolecular Research
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    • v.16 no.6
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    • pp.561-566
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    • 2008
  • NR composites with different curing systems were aged thermally at 60, 70, 80, and $90^{\circ}C$ for 2-185 days in a convection oven, and the changes in the crosslink density were investigated as a function of the accelerated thermal aging. The overall crosslink densities increased with increasing aging time irrespective of the aging temperatures and curing systems. The changes in crosslink density were enhanced by increasing the aging temperature. The degree of the increased crosslink density was in the following order: "the conventional cure system > the semi-EV system > the EV system". For short term thermal aging, the change in crosslink density with the aging time was complicated, particularly for low temperature aging. The activation energies of the change in crosslink density with thermal aging using the conventional and semi-EV cure systems increased and then remained relatively constant with increasing aging time, whereas that of the specimen with an EV cure system tended to increase linearly. The experimental results were explained by the dissociation of the existing polysulfidic linkages and the formation of new cross links through the crosslinking-related chemicals remaining in the sample.

Study on the Development of Recuperative Thermal Oxidation System for the Volatile Organic Compounds (휘발성 유기물질의 고효율 열산화 시스템 개발 연구)

  • Hyun, Ju-Soo;Lee, Si-Hyun;Lee, Jong-Sup;Min, Byoung-Moo
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.225-230
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    • 2004
  • Volatile organic compounds (VOCs) are low calorific value gases (LCVG) emitted from chemical processes such as painting booth, dye works and drying processes etc. Characteristics of VOCs are low calorific values less than 150 kcal/$m^3$, high activation energy for ignition and low energy output. These characteristics usually make combustion unstable and its treatment processes needs high-energy consumption, The cyclone combustion system is suitable for LCVG burning because it can recirculate energy through a high swirling flow to supply the activation energy for ignition, increases energy density to make a combustion temperature higher than usual swirl combustor and also increases mixing intensity, This research was conducted to develop optimized cyclone combustion system for thermal oxidation of VOCs. This research was executed to establish the effect of swirl number with respect to the combustion temperature and composition of exhausted gas in the specific combustor design.

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Cure and Thermal Degradation Kinetics of Epoxy/Organoclay Nanocomposite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.4
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    • pp.204-207
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    • 2012
  • Epoxy nanocomposite was synthesized through the exfoliation of organoclay in an epoxy matrix, which was composed of diglycidyl ether of bisphenol A (DGEBA), 4,4'-methylene dianiline (MDA) and malononitrile (MN). Organoclay was prepared by treating the montmorillonite with octadecyl trimethyl ammonium bromide (ODTMA). The exfoliation of the organoclay was estimated by wide angle X-ray diffraction (WAXD) analysis. In order to measure the cure rate of DGEBA/MDA (30 phr)/MN (5 phr)/organoclay (3 phr), differential scanning calorimetry (DSC) analysis was performed at various heating rates, and the data were interpreted by Kissinger equation. Thermal degradation kinetics of the epoxy nanocomposite were studied by thermogravimetric analysis (TGA), and the data were introduced to the Ozawa equation. The activation energy for cure reaction was 45.8 kJ/mol, and the activation energy for thermal degradation was 143 kJ/mol.