• 제목/요약/키워드: Thermal Stabilizer

검색결과 61건 처리시간 0.03초

열안정제에 의한 제전성 폴리에틸렌테레프탈레이트의 고유점도 및 수분율의 거동 변화 (Behavior of Intrinsic Viscosity and Moisture Content of Antistatic Polyethyleneterephthalate by Thermal Stabilizer)

  • 김문찬;이철규
    • 공업화학
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    • 제10권5호
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    • pp.707-710
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    • 1999
  • 제전성 폴리에틸렌테레프탈레이트(PET)에 열안정제를 첨가하여 수분율과 고유점도의 거동변화를 연구하였다. 제전 PET의 최종 수분율은 건조시간보다는 건조온도의 함수로 나타났다. 용융방사후 제전 PET의 고유점도 강하는 수분율이 증가함에 따라 증가했다. 용융방사후 제전 PET의 고유점도가 감소했는데 이것은 제전제 성분중 폴리옥시알킬렌글리콜(POAG) 성분의 열화 열분해에 의한 것이다. 열안정제로서 trimethylphosphate(TMP)를 사용하는 것보다 triphenylphosphate(TPP)를 사용한 것이 더 효과적이었다. 열안정제로서 TPP를 300ppm 사용한 것이 용융방사후 고유점도의 저하가 적었다.

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Investigation on stability characteristics of 2G HTS coated conductor tapes with various stabilizer thickness

  • Quach, Huu Luong;Kim, Ji Hyung;Hyeon, Chang Ju;Chae, Yoon Seok;Moon, Jae Hyung;Kim, Ho Min
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권1호
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    • pp.19-22
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    • 2018
  • The thermal and electrical properties of the conductor are critical parametersfor the design and optimization of the superconducting magnet. This paper presents simulation code to analyze electrical and thermal stability characteristics of the second generation (2G) high-temperature superconductor (HTS) by varying copper stabilizer thickness. Two types of commercial 2G HTS coated conductor tapes, YBCO and GdBCO were used in this study. These samples were cooled by Liquid Nitrogen ($LN_2$) having boiling at 77.3 K and an equivalent electrical circuit model for them is choosen and analysed in details. Also, an over-current pulse test in which a current exceeding a critical current was performed. From the simulation results, the influences of the copper stabilizer thickness on the stability characteristics of these samples are presented.

Phase Transition and Thermal Expansion Behavior of Zirconia Setter Fabricated from Fused CaO Stabilized Zirconia

  • Park, Ji-Hoon;Bang, Il-Hwan;Lee, Sang-Jin
    • 한국세라믹학회지
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    • 제56권2호
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    • pp.184-190
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    • 2019
  • To improve resistance in thermal shock of zirconia setter which is frequently and repeatedly exposed to high temperature, high degree of porosity and control of thermal expansion are needed for which the fused CSZ (CaO stabilized zirconia) is used to produce the zirconia setter. In the present study, the effects of sintering temperature, cool down condition, addition of CaO stabilizer, and addition of other additives on phase transition and thermal expansion behavior of the fabrication process of zirconia setter, were examined. The zirconia setter, fabricated with fused CSZ at 1550℃, exhibited 20.4 MPa of flexural strength, 6.8% of absorbance, and 27.9% of apparent porosity. The rapid change in thermal expansion of zirconia setter is observed at temperature around 800℃, and it was reduced by low firing temperature, slowed cooled down, and addition of CaO.

첨가제를 이용한 액체연료의 열안정성 향상 (Thermal Stability Improvement of Liquid Fuel by Using Some Additives)

  • 박선희;김중연;전병희;한정식;정병훈;김성현
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.294-299
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    • 2010
  • 본 연구의 목적은 열안정성을 향상시키는 첨가제 (열안정제)를 이용하여 exo-tetrahydrodicyclopentadiene (exo-THDCP, $C_{10}H_{16}$)의 열안정성을 향상시키는 것이다. 실험은 반응 진행 중 미량의 시료 추출이 가능한 회분식 반응기에서 수행되었다. 추출한 시료를 gas chromatography-mass spectrometry (GC-MS)를 이용해 성분 분석하여 첨가제 성능-exo-THDCP의 열분해성-을 확인하고, 반응시간에 따른 exo-THDCP의 분해생성물의 성분 및 조성 변화를 통해 첨가제의 작용 메커니즘을 규명하였다. 열안정제로써 수소공여체를 사용하여 실험한 결과 1,2,3,4-tetrahydroquinoline (THQ), benzyl alcohol (BnOH) 등을 첨가하였을 때 exo-THDCP의 열안정성이 향상되었다. 이러한 수소공여체 물질들은 개시반응이 진행된 exo-THDCP 라디칼에 수소원자 (hydrogen radical)를 제공함으로 라디칼의 반응성을 완화시켜 1차 생성물의 활성을 감소시키어 2차생성물질인 $C_{11}$ 이상 생성물의 발생을 감소시키는 것으로 밝혀졌다.

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스테인레스 강 안정화 YBCO 초전도선재의 접합 특성에 관한 연구 (A study on the bonding properties of YBCO coated conductors with stainless steel stabilizer)

  • 김태형;오상수;송규정;김호섭;고락길;신형섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.262-263
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    • 2005
  • For mechanical and electrical stability and environment protection, Cu and stainless steel stabilizer is laminated to Ag layer to produce a composite neutral-axis(N-A) architecture in which the YBCO layer is centered between the oxide buffered metallic substrate and stabilizer strip lamination. this architecture allows the wire to meet operational requirements including stresses at cryogenic temperature, winding tensions, mechanical bending requirements thermal and electrical stability under fault conditions. we have experimentally studied mechanical properties of laminated stainless steel stabilizer on YBCO coated conductors. we have laminated YBCO coated conductors by continuous dipping soldering process. we have investigated lamination interface between solder and stabilizer, YBCO coated conductor. we evaluated bonding properties tensile / shear bonding strength, peeling strength laminated YBCO coated conductors.

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SmBCO 고온 초전도 선재의 안정화재 특성 (A study on the properties of SmBCO coated conductors with stabilizer tape)

  • 김태형;오상수;김호섭;고락길;송규정;하홍수;이남진;박경채;하동우
    • 한국초전도ㆍ저온공학회논문지
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    • 제9권3호
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    • pp.9-12
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    • 2007
  • In this study. we searched for the mechanical and electrical properties of laminated coated conductors with stabilizer tape. Stabilizer tape plays a role for mechanical and electrical stability and environmental protection. Cu material stabilizer was laminated to Ag capping layer on SmBCO conductor layer. This architecture allows the wire to meet operational requirements including the stressless at cryogenic temperature and winding tension as well as mechanical bending requirements including thermal and electrical stability under fault current conditions. First, we have experimentally studied mechanical bonding properties of the laminated Cu stabilizers on SmBCO coated conductors. We have laminated SmBCO coated conductors by continuous dipping soldering process, Second, we have investigated electrical properties of the SmBCO coated conductors with stabilizer lamination. We evaluated bonding properties, peeling strength and critical current for laminated SmBCO coated conductors with Cu stabilizers.

이성분 나노에멀전의 입도 및 열전도도 측정 (Droplet Size and Thermal conductivity Measurements of Binary Nanoemulsion)

  • 조창환;설혜연;정정열;강용태
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.815-820
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    • 2009
  • Binary nanoemulsions which are defined as the, oil-droplet suspensions in binary solution ($H_2O$/LiBr), are developed to enhance the heat and mass transfer performance of absorption refrigeration systems. In this study, a novel two-step method is proposed to prepare the stable oil-in-binary solution (O/S) emulsion. Polymer is used as a steric stabilizer to stabilize the oil-droplets in a strong electrolyte ($H_2O$/LiBr). It is found that the thermal conductivity of the binary nanoemulsion is inversely proportional to the emulsion size while the concentrations of oil and $H_2O$/LiBr are less dominant for the thermal conductivity of binary nanoemulsions.

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폐플라스틱의 재활용에 관한 연구 (Studies on Recycling Technology Wasted Plastic)

  • 이수근
    • 한국포장학회지
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    • 제11권1호
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    • pp.47-52
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    • 2005
  • The wasted plastic PC/ABS retainer, polyurethane foam (PUF) and vinyl (PVC) skin. In order to investigate the recycling process, the multi-layered instrument panel Each of materials separated was shredded and crushed to create many small particles respectively. The separation of the foam and skin and retainer of zigzagged air blower. Pilot tests performed at the equipment yielded 98.8% by weight of the available PVC and 99.3% by weight of the available PC/ABS respectively. Secondly, the thermal stabilizer and the compatabilizer have been used to improve the physical propertied of recycled materials.. The properties of recycled PVC materials resulted in about 50% compared to that of virgin materials after treatment by Pb-St thermal stabilizer. In addition, the properties of recycled PC/ABS materials was also obtained about 80% compared to that of virgn materials after treatment by PMMA compatabilizer.

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A Practical Power System Stabilizer Tuning Method and its Verification in Field Test

  • Shin, Jeong-Hoon;Nam, Su-Chul;Lee, Jae-Gul;Baek, Seung-Mook;Choy, Young-Do;Kim, Tae-Kyun
    • Journal of Electrical Engineering and Technology
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    • 제5권3호
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    • pp.400-406
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    • 2010
  • This paper deals with parameter tuning of the Power System Stabilizer (PSS) for 612 MVA thermal power plants in the KEPCO system and its validation in a field test. In this paper, the selection of parameters, such as lead-lag time constants for phase compensation and system gain, is optimized using linear and eigenvalue analyses. This is then verified through the time-domain transient stability analysis. In the next step, the performance of PSS is finally verified by the generator's on-line field test. After the field test, measured and simulated data are also compared to prove the effectiveness of the models used in the simulations.

안정화 선재의 YBCO 초전도 접합 특성 (A study on the bonding properties of YBCO coated conductors with stabilizer tape)

  • 김태형;오상수;하동우;김호섭;고락길;신형섭;박경채
    • 한국초전도ㆍ저온공학회논문지
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    • 제8권3호
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    • pp.23-26
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    • 2006
  • For mechanical and electrical stability and environment protection. Cu and stainless steel stabilizers are laminated to a Ag layer to produce a composite neutral-axis(N-A) architecture in which the YBCO layer is centered between the oxide buffered metallic substrate and stabilizer strip lamination. This architecture allows the wire to meet operational requirements including stresses at cryogenic temperature. winding tensions as well as mechanical bending requirements including thermal and electrical stability under fault current conditions. We have experimentally studied mechanical properties of the laminated stainless steel and Cu stabilizers on YBCO coated conductors. We have laminated YBCO coated conductors by continuous dipping soldering process. We have investigated lamination interface between solder and stabilizer of the YBCO coated conductor. We evaluated bonding properties. tensile / shear bonding strength. and peeling strength laminated YBCO coated conductors.