• 대한화학회지
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• 제27권2호
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• pp.157-164
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• 1983

N-Methylidene-2,6-diethylaniline (III)은 2,6-diethylaniline (II)과 과량의 paraformaldehyde와의 반응으로 만들었으며, 이 화합물 III에서 N=$CH_2$ 프로톤은 AB 스핀계를 나타냈다. 화합물 III과 chlorocarbonylsulfenyl chloride(IV)를 반응시켜서 N-(chloromethyl)-N-(2,6-diethylphenyl)-carbamoylsulfenyl chloride(V)를 합성하였다. 화합물 V와 여러 종류의 알콜을 반응시켜서 Alkyl N-(chloromethyl)-N-(2,6-diethylphenyl)-carbamoylsulfenate esters(VI ${\sim}$XVI)를 71{\sim}$95%의 수득률로 합성하였다. VI${\sim}$XVI은 서서히 분해되지만 S-O 결합이 S=O결합으로 변하지는 않았다. 과량의 알콜은 V의 2가 황과 N-chloromethyl기의 ${\alpha}$-탄소에 대해 친핵성 공격을 할 수 있었으며, 이렇게 하여 생긴 화합물 (XVII, XVIII)은 상당한 안정성을 가지고 있었다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권6호
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• pp.255-261
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• 2005

Recently, the RF inductive discharge or inductively coupled plasma continues to attract growing attention as an effective plasma source in many industrial applications, the best known of which are plasma processing and lighting technology. To the point of lighting sources, the ring-shaped electrodeless fluorescent lamps utilizing an inductively coupled plasma have been objects of interest and research during the last decades, mainly because of their potential for extremely long life, high lamp efficacies, rapid power switching response. In this paper, maxwell 3D finite element analysis program (Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250 kHz and some specific conditions. The electromagnetic field in the ferrite core was shown to be high and symmetric. An LS-100 luminance meter and a Darsa-2000 spectrum analyzer were used in the experiment. According to data on the lamp tested using high magnetic field ferrite, the optical and thermal wave fields were shown to be high around the ring-shaped electrodeless fluorescent lamp. The optical or light field was high at the center of the bulb rather than around the ferrite core. The light conditions of the bulb were assumed to be complex, depending on the condition of the filler gas, the volume of the bulb, and the frequency of the inverter. Our results have shown coupling between the gas plasma and the field of the light emitted to be nonlinear.

• 한국전기전자재료학회논문지
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• 제22권9호
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• pp.717-723
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• 2009

Ni/Al ('/' denotes deposition sequence) contacts were deposited on Al-implanted 4H-SiC for ohmic contact formation, and the conduction properties were characterized and compared with those of Ni-only contacts. The thicknesses of the Ni and Al thin film were 30 nm and 300 nm, respectively, and the films were sequentially deposited bye-beam evaporation without vacuum breaking. Rapid thermal anneal (RTA) temperature was varied as follows : $840^{\circ}C$, $890^{\circ}C$, and $940^{\circ}C$. The specific contact resistivity of the Ni contact was about $^{\sim}2\;{\pm}\;10^{-2}\;{\Omega}{\cdot}cm^2$, However, with the addition of Al overlayer, the specific contact resistivity decreased to about $^{\sim}2\;{\pm}\;10^{-4}\;{\Omega}{\cdot}cm^2$, almost irrespective of RTA temperature. X-ray diffraction (XRD) analysis of the Ni contact confirmed the existence of various Ni silicide phases, while the results of Ni/Al contact samples revealed that Al-contaning phases such as $Al_3Ni$, $Al_3Ni_2$, $Al_4Ni_3$, and $Ab_{3.21}Si_{0.47}$ were additionally formed as well as the Ni silicide phases. Energy dispersive spectroscopy (EDS) spectrum showed interfacial reaction zone mainly consisting of Al and Si at the contact interface, and it was also shown that considerable amounts of Si and C have diffused toward the surface. This indicates that contact resistance lowering of the Ni/Al contacts is related with the formation of the formation of interfacial reaction zone containing Al and Si. From these results, possible mechanisms of contact resistance lowering by the addition of Al were discussed.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3771-3776
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• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• Nuclear Engineering and Technology
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• 제5권4호
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• pp.265-278
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• 1973

분자의 병진운동과 회전운동의 상관함수에 대한 감쇠함수 모델을 사용하여 분자액체의 비간섭중성자 산란단면적을 분석하였다. 이러한 방법은 직접적으로 산란함수를 구한다는 점에서 중간함수를 거치는 종래의 방법과는 판연히 다르다. 감쇠함수는 그장파장극한과 일반진동수 분포함수간의 간단한 관계에서 결정하였고 병진운동과회전 운동의 결합관계는 무시된다고 가정하였다. 분자질량중심의 병진운동은 그 짧은 시간과 장시간에서의 행위를 적절히 기술하는 물리적 모텔을 사용하였고 회전운동은 쌍극상관함수 또는 적외선진동 홈수스펙트럼의 푸리어 변환으로 된 감쇠함수에 관계된다고 가정하였다. 액체메탄에 대한 이론적 절대 산란강도를 계산하였으며 이는 열 및 냉중성자 측정치와 만족할만한 일치를 보여주고 있다.

• 대한의용생체공학회:의공학회지
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• 제25권6호
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• pp.623-628
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• 2004

본 논문에서는 원적외선 온열효과가 자율 신경계에 미치는 영향을 심박변동(HRV)을 이용하여 평가 하였다. 측정된 심박변동신호를 FFT 의한 전력스펙트럼을 구함으로써 자율 신경계의 반응 특성을 고찰하고 Poincare plot 분석 방법을 이용하여 결과를 비교 분석하였다. 실험을 통해 심박변동 신호분석해보면 원적외선 온열에 노출되기 전에 비해 노출된 후에 매우 복잡한 모습임을 관찰 할 수 있었는데 이것은 자율신경계가 관여하는 심혈관계 제어 메커니즘이 원적외선 온열에 노출되기 전보다 노출된 후에 더욱 복잡함을 반영하는 것으로 분석된다.

• 센서학회지
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• 제17권5호
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• pp.369-374
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• 2008

A novel fiber optic surface plasmon resonance (SPR) sensor using cyclic olefin copolymer (COC) prism with the spectral modulation is presented. The SPR sensor chip is fabricated using the SU-8 photolithography, Ni-electroplating and COC injection molding process. The sidewall of the COC prism is partially deposited with Au/Cr (45/2.nm thickness) by e-beam evaporator, and the thermal bonding process is conducted for micro fluidic channels and optical fibers alignment. The SPR spectrum for a phosphate buffered saline (0.1.M PBS, pH.7.2) solution shows a distinctive dip at 1300.nm wavelength, which shifts toward longer wavelength with respect to the bovine serum albumin (BSA)concentrations. The sensitivity of the wavelength shift is $1.16\;nm{\cdot}{\mu}g^{-1}{\cdot}{\mu}l^{-1}$. From the wavelength of SPR dips, the refractive indices (RI) of the BSA solutions can be theoretically calculated using Kretchmann configuration, and the change rate of the RI was found to be $2.3{\times}10^{-5}RI{\cdot}{\mu}g^{-1}{\cdot}l^{-1}$. The realized fiber optic SPR sensor with a COC prism has clearly shown the feasibility of a new disposable, low cost and miniaturized SPR biosensor for biochemical molecular analyses.

• 센서학회지
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• 제6권4호
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• pp.252-257
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• 1997

ITO(indium-tin-oxide)/PPV(poly(p-phenylenevihylene))/음극 전극의 단층구조와 ITO /PVK(poly(N-vinylcarbazole))/PPV/음극전극의 이층구조를 가진 유기 EL(electroluminescence) 소자를 제작하였으며, 전기-광학적 특성을 측정하였다. 실험 결과, 단층구조에서는 PPV막의 열변환 온도를 $140^{\circ}C$에서 $260^{\circ}C$로 증가할수록 최대 휘도가 $118.8\;cd/m^{2}$(20V)에서 $21.14\;cd/m^{2}$(28V)으로 감소하였고, EL 스펙트럼의 최대 피크가 500nm에서 580nm로 이동하였다. 또한, 음극전극의 일함수가 낮을수록 소자의 발광휘도와 주입 전류는 증가되었다. 이층구조에서는 PVK막의 농도가 감소함에 따라 발광휘도가 $70.71\;cd/m^{2}$(32V)에서 $152.7\;cd/m^{2}$(26V)으로 증가하였다.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 2010년도 한국우주과학회보 제19권1호
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• pp.37.5-38
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• 2010

경희대학교 우주탐사학과에서는 우주공간 탐사를 위해 Trio(TRiplet Ionospheric Observatory)-CINEMA(Cubesat for Ions, Neutrals, Electrons and MAgnetic fields)로 명명된 초소형 위성을 개발하고 있다. 과학임무는 지구 저궤도에서 고에너지 입자를 관측하는 것이며, 이를 위해 고에너지 (2~300keV) 입자 검출기와 자기장 측정기가 탑재된다. 저에너지 입자 검출기 시스템인 STEIN(SupraThermal Electrons, Ions, Neutrals)은 $1\times4$ Array의 개선된 실리콘 검출기와 이온, 전자, 중성입자를 분리할 수 있는 정전장 편향기, 그리고 신호를 처리하는 전자회로로 구성되어있다. 설계된 전자회로는 매우 작은 검출기 기판, 아날로그 기판과 디지털 기판으로 이루어져 있고, 475mW 이하의 저 전력으로 동작한다. 또한 2~100keV의 에너지를 1keV이하의 해상도로 30,000event/sec/pixel 까지 관측 할 수 있도록 회로를 설계하였다. 센서로 들어온 입자로 인해 발생한 펄스의 신호는 4개의 아날로그 회로가 담당하게 되는데, Folded cascode amplifier를 배치하여 증폭률을 높인 Charge sensitive amplifier를 통해 신호를 증폭하고, $2{\mu}s$ unipolar gaussian shaping amplifier를 통해 읽기 쉽게 처리된 신호를 상한파고선별기와 하한파고 선별기를 통해 유효 값 여부를 판단하고, 피크 검출기를 통해 피크의 타이밍을 측정한 뒤 신호를 아날로그-디지털 변환 회로를 통하여 8bit의 값으로 나타내어, 입자들의 Spectrum을 측정하게 된다. 크기와 소비전력이 적음에도 검출성능이 우수하기 때문에 이 시스템은 향후 우주탐사 시스템에 있어 매우 중요한 역할을 수행 할 것으로 생각한다.

• 한국전기전자재료학회논문지
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• 제27권12호
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• pp.820-824
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• 2014

TiNOx multi-layer thin films on aluminum substrates were prepared by DC reactive magnetron sputtering method. 4 multi-layers of $TiO_2$/TiNOx(LMVF)/TiNOx(HMVF)/Ti/substrate have been prepared with ratio of Ar and ($N_2+O_2$) gas mixture. $TiO_2$ of top layer is anti-reflection layer on double TiNOx(LMVF)/TiNOx(HMVF) layers and Ti metal of infrared reflection layer. In this study, the crystallinity and surface properties of TiNOx thin films were estimated by X-ray diffraction(XRD) and field emission scanning electron microscopy(FE-SEM), respectively. The grain size of TiNOx thin films shows to increase with increasing sputtering power. The composition of thin films has been investigated using electron probe microanalysis(EPMA). The optical properties with wavelength spectrum were recorded by UV-Vis-NIR spectrophotometry at a range of 200~1,500 nm. The TiNOx multi-layer films show the excellent optical performance beyond 9% of reflectance in those ranges wavelength.