• Title/Summary/Keyword: Thermal Spectrum

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Synthesis and Characterization of Y2O3:Eu Fine Particle

  • Park, Ji-Koon;Kang, Sang-Sik;Kwak, Min-Gi;Choi, Seung-Suk;Kim, Jae-Hyung;Nam, Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.169-172
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    • 2005
  • [ $Y_2O_3:Eu$ ] powder was synthesized using a solution-combustion method by dissolving $(CH_3CO_2)_3Y$ and $(CH_3CO_2)_3$ Eu in methyl-alcohol solution. Results from X-ray diffractometery (XRD), thermogravimetry (TG)-differential thermal analysis (DTA) show that $Y_2O_3:Eu$ crystallizes completely when the dry powder is sintered at $500^{\circ}C$. The investigated optical properties were the photoluminescence emission spectra, the excitation spectra and luminescence decay curve. Europium (Eu) concentration had no observable effect on the optical spectrum which depended on the emission intensity. The mean lifetime of synthesized phosphors was $2.3\~2.6 ms$.

Thermally Assisted Carrier Transfer and Field-induced Tunneling in a Mg-doped GaN Thin Film (Mg가 첨가된 GaN 박막에서 캐리어 전이의 열적도움과 전계유도된 터러링 현상)

  • Chung, Sang-Geun;Kim, Yoon-Kyeom;Shin, Hyun-Gil
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.431-435
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    • 2002
  • The dark current and photocurrent(PC) spectrum of Mg-doped GaN thin film were investigated with various bias voltages and temperatures. At high temperature and small bias, the dark current is dominated by holes thermally activated from an acceptor level Al located at about 0.16 eV above the valence band maximum $(E_v)$, The PC peak originates from the electron transition from deep level A2 located at about 0.34 eV above the $E_v$ to the conduction band minimum $(E_ C)$. However, at a large bias voltage, holes thermally activated from A2 to Al experience the field-in-duces tunneling to form one-dimensional defect band at Al, which determines the dark current. The PC peak associated with the transition from Al to $E_ C$ is also observed at large bias voltages owing to the extended recombination lifetime of holes by the tunneling. In the near infrared region, a strong PC peak at 1.20 eV appears due to the hole transition from deep donor/acceptor level to the valence band.

Review on Molecular Simulation of Graphene from a Tribological Perspective (트라이볼로지 관점에서의 그래핀 분자시뮬레이션 연구동향)

  • Kim, Hyun-Joon;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.55-63
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    • 2020
  • Recently, graphene has attracted considerable attention owing to its unique electrical, optical, thermal, and mechanical properties. The broad spectrum of applications from optics, sensors, and electronics to biodevice have been proposed based on these properties. In particular, graphene has been proposed as a protective coating layer and solid lubricant for microdevices and nanodevices because of its high mechanical strength, chemical inertness, and low friction characteristics. During the past decade, extensive efforts have been made to explore the tribological characteristics of graphene under various conditions and to expand its applicability. In addition to the experimental approaches, the molecular simulations performed provide fundamental insights into the friction and wear characteristics of graphene resulting from molecular interactions. This work is a review of the studies conducted over the past decade on the tribological characteristics of graphene using molecular simulation. These studies demonstrate the principal mechanisms of the superlubricity of graphene and help clarify the influences of surface conditions on tribological behavior. In particular, the investigation of the effects of the number of layers, strength of adhesion to the substrate, surface roughness, and commensurability provides deeper insights into the tribological characteristics of graphene. These fundamental understandings can help elucidate the feasibility of graphene as a protective coating layer and solid lubricant for microdevices and nanodevices.

The Changes of Facial Temperature by Miso Facial Rejuvenation Acupuncture;A case study (미소안면침 시술후 안면부 체온변화에 대한 임상적 고찰;A case study)

  • Hwang, Deok-Sang;Song, Jeong-Hwa;Kim, Yong-Suk;Lee, Kyung-Sub
    • Journal of Acupuncture Research
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    • v.25 no.1
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    • pp.89-95
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    • 2008
  • Objectives : To investigate changes in facial temperature generated by Miso Facial Rejuvenation Acupuncture treatment. Methods : One middle-aged woman with no diseases was recruited. Miso Facial Rejuvenation Acupuncture was performed on only the right side of her face. We measured her facial temperature using digital infrared thermal imaging(DOREX Inc. Spectrum 9,000MB, USA, D.I.T.I) before, immediately after, and 10 minutes after treatment. We also used the Wilcoxon signed rank test(p<0.05) to compare the differences in facial temperature from one side of the face to the other at each time. Results : Facial temperature on the right side(the area treated by acupuncture) increased immediately from $30.02{\pm}1.87^{\circ}C$ to $32.24{\pm}1.03^{\circ}C$, a statistically significant increase. Ten minutes after treatment, facial temperature on the right side decreased a little bit, but there was no statistical significance. Facial temperature on the left side increased a little, but there was no statistical significance. The difference between the right and left sides of the face increased after the Miso Facial Rejuvenation Acupuncture treatment. Conclusions : Miso Facial Rejuvenation Acupuncture could increase facial temperature.

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Desulfurization of Model Oil via Adsorption by Copper(II) Modified Bentonite

  • Yi, Dezhi;Huang, Huan;Li, Shi
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.777-782
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    • 2013
  • In order to further reduce the sulfur content in liquid hydrocarbon fuels, a desulfurization process by adsorption for removing dimethyl sulfide (DMS) and propylmercaptan (PM) was investigated. Bentonite adsorbents modified by $CuCl_2$ for the desulfurization of model oil was investigated. The results indicated that the modified bentonite adsorbents were effective for adsorption of DMS and PM. The bentonite adsorbents were characterized by X-ray diffraction (XRD) and thermal analysis (TGA). The acidity was measured by FT-IR spectroscopy. Several factors that influence the desulfurization capability, including loading and calcination temperature, were studied. The maximum sulfur adsorption capacity was obtained at a Cu(II) loading of 15 wt %, and the optimum calcination temperature was $150^{\circ}C$. Spectral shifts of the ${\nu}$(C-S) and ${\nu}$(Cu-S) vibrations of the complex compound obtained by the reaction of $CuCl_2$ and DMS were measured with the Raman spectrum. On the basis of complex adsorption reaction and hybrid orbital theory, the adsorption on modified bentonite occurred via multilayer intermolecular forces and S-M (${\sigma}$) bonds.

The Fabrication of PVDF Organic Thin Films by Physical Vapor Deposition Method and Their Electrical Conductivity Phenomena (진공증착법을 이용한 PVDF 유기박막의 제조와 전기전도현상)

  • 임응춘;이덕출
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.217-225
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    • 1997
  • In this study, the PVDF organic thin film was fabricated by the physical vapor deposition method to be dry-process. The distance of heat source and substrate was 5[cm] and the temperature of substrate was 30[.deg. C], when the pressure had reached 2.0 x 10$^{-5}$ [Torr], the temperature of heat source was reached to 285[.deg. C] to heat at 6-8[.deg. C/min] rate, the shutter was opened and deposition was started. TG-DTA(Thermogravimetric-Differential Thermal Analysis) spectrum of PVDF pellets showed that endothermic peak arose at 170[.deg. C] and exothermic peak at 524[.deg. C], but that of thin PVDF film showed that endothermic peak arose at 145[.deg. C] and exothermic peak at 443[.deg C]. The current density was increased linearly with increasing voltage but increased nonlinearly with higher electric field than 250[kV/cm] and activation energy was about 0.667[eV] at the temperature of 30-90[.deg. C].

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Comparison of electrical and optical properties between ITO and ZnO:Al films used as transparent conducting films for PDP (PDP용 투명전도막으로 사용되는 ITO 와 ZnO:Al 의 전기적.광학적 특성 비교)

  • Kim, Byung-Sub;Park, Kang-Il;Lim, Dong-Gun;Park, Gi-Yub;Kwak, Dong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.857-860
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    • 2003
  • Tin doped indium oxide(ITO) and Al doped zinc oxide(ZnO:Al) films, which are widely used as a transparent conductor in optoelectronic devices such as solar cell, liquid crystal display, plasma display panel, thermal heater, and other sensors, were prepared by using the capacitively coupled DC magnetron sputtering method. The electrical and optical properties of both the ITO and ZnO:Al thin films were investigated as functions of substrate temperature, working gas pressure and deposition time. ITO and ZnO:Al films with the the present experimental conditions of temperature and pressure showed resistivity of $2.36{\times}10^{-4}{\Omega}-cm,\;9.42{\times}10^{-4}{\Omega}-cm$ and transmittance of 86.28%, 90.88% in the wavelength range of the visible spectrum, respectively.

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The electrical properties of ZnO transparent conducting films by doping amounts of $Al_2O_3$ (ZnO 투명전도막의 $Al_2O_3$의 도핑농도에 따른 전기적 특성)

  • Kim, Byung-Sub;Lee, Sung-Wook;Lee, Soo-Ho;Lim, Dong-Gun;Lee, Se-Jong;Park, Min-Woo;Kwak, Dong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.969-972
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    • 2004
  • Al doped Zinc Oxide(ZnO:Al) films, which is widely used as a transparent conductor in optoelectronic devices such as solar cell, liquid crystal display, plasma display panel, thermal heater, and other sensors, were prepared by using the capacitively coupled DC magnetron sputtering method. In this paper the effect of doping amounts of $Al_2O_3$ on the electrical, optical and morphological properties were investigated experimentally, The results show that the structural and electrical properties of the film are highly affected by the doping. The optimum growth conditions were obtained for films doped with 2 wt% of Al203 which exhibit a resistivity of $8.5{\times}10^{-4}{\Omega}-cm$ associated with a transmittance of 91.7 % for 840 nm in film thickness in the wavelength range of the visible spectrum.

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Thermal Characteristics of an All Optical Add/Drop Multiplexer Using MZI and Fiber Bragg Gratings Filter (광섬유 브래그 격자 필터와 MZI를 이용한 전광 다중화기의 온도 특성)

  • Son, Yong-Hwan;Won, Yong-Yuk;Kim, Jae-Wook;Jung, Jin-Ho;Han, Sang-Kook
    • Journal of IKEEE
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    • v.12 no.1
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    • pp.43-50
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    • 2008
  • In this paper, the output and temperature characteristics for an optical signal of the fiber bragg grating have been considered. Also, output characteristics which depend on the temperature changes have been investigated for an all-optic add/drop multiplexer based on the fiber bragg grating and Mach-Zehnder interferometer. From the obtained results, they show that the center wavelength of output spectrum shifts approximately 0.01230 nm/$^{\circ}C$ within a temperature range $-30^{\circ}C{\sim}90^{\circ}C$.

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Syntheses of CdTe Quantum Dots and Nanoparticles through Simple Sonochemical Method under Multibubble Sonoluminescence Conditions

  • Hwang, Cha-Hwan;Park, Jong-Pil;Song, Mi-Yeon;Lee, Jin-Ho;Shim, Il-Wun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2207-2211
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    • 2011
  • Colloidal cadmium telluride (CdTe) quantum dots (QDs) and their nanoparticles have been synthesized by one pot sonochemical reactions under multibubble sonoluminescence (MBSL) conditions, which are quite mild and facile compared to other typical high temperature solution-based methods. For a typical reaction, $CdCl_2$ and tellurium powder with hexadecylamine and trioctylphosphine/trioctylphosphineoxide (TOP/TOPO) as a dispersant were sonicated in toluene solvent at 20 KHz and a power of 220W for 5-40 min at 60 $^{\circ}C$. The sizes of CdTe particles, in a very wide size range from 2 nm-30 ${\mu}m$, were controllable by varying the sonicating and thermal heating conditions. The prepared CdTe QDs show different colors from pale yellow to dark brown and corresponding photoluminescence properties due mainly to the quantum confinement effect. The CdTe nanoparticles of about 20 nm in average were found to have band gap of 1.53 eV, which is the most optimally matched band gap to solar spectrum.