• Journal of the Korean Chemical Society
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• v.27 no.2
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• pp.157-164
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• 1983

N-Methylidene-2,6-diethylaniline (III) was prepared by the reaction of 2,6-diethylaniline (II) with an excess paraformaldehyde. The protons of N=$CH_2$in the compound III exhibited a second order NMR spectrum. The compound III reacted with bifunctional chlorocarbonylsulfenyl chloride(IV) to give N-(chloromethyl)-N-(2,6-diethylphenyl)-carbamoylsulfenyl chloride(V). The reaction of the compound V with various alcohols resulted in the formation of Alkyl N-(chloromethyl)-N-(2,6-diethylphenyl)-carbamoylsulfenate esters(VI${\sim}$XVI) in 71${\sim}$95% yields. The compound VI${\sim}$XVI decomposed gradually, but the thermal rearrangement of S-O bonding to S=O bonding was not found. The nucleophilic attack of an excess alcohol to the compound Ⅴ was made on both divalent sulfur and ${\alpha}$-carbon of N-chloromethyl group. The corresponding substituted products(XVII, XVIII) had considerable stability.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.54 no.6
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• pp.255-261
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• 2005

Recently, the RF inductive discharge or inductively coupled plasma continues to attract growing attention as an effective plasma source in many industrial applications, the best known of which are plasma processing and lighting technology. To the point of lighting sources, the ring-shaped electrodeless fluorescent lamps utilizing an inductively coupled plasma have been objects of interest and research during the last decades, mainly because of their potential for extremely long life, high lamp efficacies, rapid power switching response. In this paper, maxwell 3D finite element analysis program (Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250 kHz and some specific conditions. The electromagnetic field in the ferrite core was shown to be high and symmetric. An LS-100 luminance meter and a Darsa-2000 spectrum analyzer were used in the experiment. According to data on the lamp tested using high magnetic field ferrite, the optical and thermal wave fields were shown to be high around the ring-shaped electrodeless fluorescent lamp. The optical or light field was high at the center of the bulb rather than around the ferrite core. The light conditions of the bulb were assumed to be complex, depending on the condition of the filler gas, the volume of the bulb, and the frequency of the inverter. Our results have shown coupling between the gas plasma and the field of the light emitted to be nonlinear.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.9
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• pp.717-723
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• 2009

Ni/Al ('/' denotes deposition sequence) contacts were deposited on Al-implanted 4H-SiC for ohmic contact formation, and the conduction properties were characterized and compared with those of Ni-only contacts. The thicknesses of the Ni and Al thin film were 30 nm and 300 nm, respectively, and the films were sequentially deposited bye-beam evaporation without vacuum breaking. Rapid thermal anneal (RTA) temperature was varied as follows : $840^{\circ}C$, $890^{\circ}C$, and $940^{\circ}C$. The specific contact resistivity of the Ni contact was about $^{\sim}2\;{\pm}\;10^{-2}\;{\Omega}{\cdot}cm^2$, However, with the addition of Al overlayer, the specific contact resistivity decreased to about $^{\sim}2\;{\pm}\;10^{-4}\;{\Omega}{\cdot}cm^2$, almost irrespective of RTA temperature. X-ray diffraction (XRD) analysis of the Ni contact confirmed the existence of various Ni silicide phases, while the results of Ni/Al contact samples revealed that Al-contaning phases such as $Al_3Ni$, $Al_3Ni_2$, $Al_4Ni_3$, and $Ab_{3.21}Si_{0.47}$ were additionally formed as well as the Ni silicide phases. Energy dispersive spectroscopy (EDS) spectrum showed interfacial reaction zone mainly consisting of Al and Si at the contact interface, and it was also shown that considerable amounts of Si and C have diffused toward the surface. This indicates that contact resistance lowering of the Ni/Al contacts is related with the formation of the formation of interfacial reaction zone containing Al and Si. From these results, possible mechanisms of contact resistance lowering by the addition of Al were discussed.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3771-3776
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• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• Nuclear Engineering and Technology
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• v.5 no.4
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• pp.265-278
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• 1973

The incoherent neutron scattering cross section of molecular liquids is analyzed using a damping function model for correlation functions of molecular translations and rotations. The present approach is different from recent works in that the scattering function is evaluated directly, not through the intermediate scattering function. The damping fuction is determined from a simple relation between its long-wavelength limit and the generalized frequency distribution function, and translation-rotation couplings are assumed to be neglected. A physical model is used for the translational motions of center-of-mass of a molecule, including properly its short-time and long-time behaviors. A simple model for the rotational motions is suggested which relates the damping function to the Fourier transform of the dipole correlation function, or equivalently, the infrared vibrational absorption spectrum. Theoretical absolute scattering intensities are computed for liquid methane and shown to be in satisfactory agreement with both thermal and cold neutron measurements.

• Journal of Biomedical Engineering Research
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• v.25 no.6
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• pp.623-628
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• 2004

This paper describes autonomic nervous system activities caused by hyperthermia of far-infrared ray on human body. Designed protocol and analysis algorithm were evaluated by experiments on 20 subjects to analyze the characteristic of heart rate variability(HRV) signals which could be analyzed by FFT power spectrum and time-frequency analysis. Using Poincare' plot analysis, LF and HF were compared with SD1 and SD2. During the experiment, subject was exposed to hyperthermic effects of far-infrared radiation. We could confirm that far-infrared ray, which was known to improve the blood circulation, stress state and enhancing thermal effect into human body, had an effect on human nervous system. As the hyperthermic temperature of far-infrared ray increased, the activity of cardiovascular system to sustain the homeostasis was observed by means of investigating the increase of the sympathetic activity.

• Journal of Sensor Science and Technology
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• v.17 no.5
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• pp.369-374
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• 2008

A novel fiber optic surface plasmon resonance (SPR) sensor using cyclic olefin copolymer (COC) prism with the spectral modulation is presented. The SPR sensor chip is fabricated using the SU-8 photolithography, Ni-electroplating and COC injection molding process. The sidewall of the COC prism is partially deposited with Au/Cr (45/2.nm thickness) by e-beam evaporator, and the thermal bonding process is conducted for micro fluidic channels and optical fibers alignment. The SPR spectrum for a phosphate buffered saline (0.1.M PBS, pH.7.2) solution shows a distinctive dip at 1300.nm wavelength, which shifts toward longer wavelength with respect to the bovine serum albumin (BSA)concentrations. The sensitivity of the wavelength shift is $1.16\;nm{\cdot}{\mu}g^{-1}{\cdot}{\mu}l^{-1}$. From the wavelength of SPR dips, the refractive indices (RI) of the BSA solutions can be theoretically calculated using Kretchmann configuration, and the change rate of the RI was found to be $2.3{\times}10^{-5}RI{\cdot}{\mu}g^{-1}{\cdot}l^{-1}$. The realized fiber optic SPR sensor with a COC prism has clearly shown the feasibility of a new disposable, low cost and miniaturized SPR biosensor for biochemical molecular analyses.

• Journal of Sensor Science and Technology
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• v.6 no.4
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• pp.252-257
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• 1997

Organic EL devices, which have the sing3e-layer structure of ITO(indium-tin-oxide) /PPV(poly(p-phenylene vinylene))/cathode and the double-layer structure of ITO/PVK (poly(N- vinylcarbazole)) /PPV/cathode, were fabricated and their electro-optical properties were investigated. Experimental results, in single-layer structure, shown that the increment of temperature for thermal conversion of PPV film from $140^{\circ}C$ to $260^{\circ}C$ decreases the maximum luminance from $118.8\;cd/m^{2}$(20V) to $21.14\;cd/m^{2}$(28V) and shift the maximum peak of EL spectrum from 500nm to 580nm. The lower the work function of cathode is, the more the luminance and injection current of device. In double-layer structure, as the concentration of PVK solution decreases from 0.5 wt% to 0.05 wt%, the luminance of device increases from $70.71\;cd/m^{2}$(32V) to $152.7\;cd/m^{2}$(26V).

• Bulletin of the Korean Space Science Society
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• 2010.04a
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• pp.37.5-38
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• 2010

경희대학교 우주탐사학과에서는 우주공간 탐사를 위해 Trio(TRiplet Ionospheric Observatory)-CINEMA(Cubesat for Ions, Neutrals, Electrons and MAgnetic fields)로 명명된 초소형 위성을 개발하고 있다. 과학임무는 지구 저궤도에서 고에너지 입자를 관측하는 것이며, 이를 위해 고에너지 (2~300keV) 입자 검출기와 자기장 측정기가 탑재된다. 저에너지 입자 검출기 시스템인 STEIN(SupraThermal Electrons, Ions, Neutrals)은 $1\times4$ Array의 개선된 실리콘 검출기와 이온, 전자, 중성입자를 분리할 수 있는 정전장 편향기, 그리고 신호를 처리하는 전자회로로 구성되어있다. 설계된 전자회로는 매우 작은 검출기 기판, 아날로그 기판과 디지털 기판으로 이루어져 있고, 475mW 이하의 저 전력으로 동작한다. 또한 2~100keV의 에너지를 1keV이하의 해상도로 30,000event/sec/pixel 까지 관측 할 수 있도록 회로를 설계하였다. 센서로 들어온 입자로 인해 발생한 펄스의 신호는 4개의 아날로그 회로가 담당하게 되는데, Folded cascode amplifier를 배치하여 증폭률을 높인 Charge sensitive amplifier를 통해 신호를 증폭하고, $2{\mu}s$ unipolar gaussian shaping amplifier를 통해 읽기 쉽게 처리된 신호를 상한파고선별기와 하한파고 선별기를 통해 유효 값 여부를 판단하고, 피크 검출기를 통해 피크의 타이밍을 측정한 뒤 신호를 아날로그-디지털 변환 회로를 통하여 8bit의 값으로 나타내어, 입자들의 Spectrum을 측정하게 된다. 크기와 소비전력이 적음에도 검출성능이 우수하기 때문에 이 시스템은 향후 우주탐사 시스템에 있어 매우 중요한 역할을 수행 할 것으로 생각한다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.27 no.12
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• pp.820-824
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• 2014

TiNOx multi-layer thin films on aluminum substrates were prepared by DC reactive magnetron sputtering method. 4 multi-layers of $TiO_2$/TiNOx(LMVF)/TiNOx(HMVF)/Ti/substrate have been prepared with ratio of Ar and ($N_2+O_2$) gas mixture. $TiO_2$ of top layer is anti-reflection layer on double TiNOx(LMVF)/TiNOx(HMVF) layers and Ti metal of infrared reflection layer. In this study, the crystallinity and surface properties of TiNOx thin films were estimated by X-ray diffraction(XRD) and field emission scanning electron microscopy(FE-SEM), respectively. The grain size of TiNOx thin films shows to increase with increasing sputtering power. The composition of thin films has been investigated using electron probe microanalysis(EPMA). The optical properties with wavelength spectrum were recorded by UV-Vis-NIR spectrophotometry at a range of 200~1,500 nm. The TiNOx multi-layer films show the excellent optical performance beyond 9% of reflectance in those ranges wavelength.