• Title/Summary/Keyword: Thermal Relaxation Time

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Nuclear Magnetic Resonance Study of the Raman Spin-Phonon Processes in the Relaxation Mechanisms of Double Sulfate Li3Rb(SO4)2 Single Crystals

  • Heo, Cheol;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.15 no.1
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    • pp.40-53
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    • 2011
  • The NMR spectra of $Li_3Rb(SO_4)_2$ crystals and their relaxation processes were investigated by using $^7Li$ and $^{87}Rb$ NMR. The relaxation rates of the $^7Li$ and $^{87}Rb$ nuclei in the crystals were found to increase with increasing temperature, and can be described by the relation $T_1^{-1}{\propto}AT^2$. The dominant relaxation mechanism for these nuclei with electric quadrupole moments is provided by the coupling of these moments to the thermal fluctuations of the local electric field gradient via Raman spin-phonon processes.

Fractional magneto-thermoelastic materials with phase-lag Green-Naghdi theories

  • Ezzat, M.A.;El-Bary, A.A.
    • Steel and Composite Structures
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    • v.24 no.3
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    • pp.297-307
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    • 2017
  • A unified mathematical model of phase-lag Green-Naghdi magneto-thermoelasticty theories based on fractional derivative heat transfer for perfectly conducting media in the presence of a constant magnetic field is given. The GN theories as well as the theories of coupled and of generalized magneto-thermoelasticity with thermal relaxation follow as limit cases. The resulting nondimensional coupled equations together with the Laplace transforms techniques are applied to a half space, which is assumed to be traction free and subjected to a thermal shock that is a function of time. The inverse transforms are obtained by using a numerical method based on Fourier expansion techniques. The predictions of the theory are discussed and compared with those for the generalized theory of magneto-thermoelasticity with one relaxation time. The effects of Alfven velocity and the fractional order parameter on copper-like material are discussed in different types of GN theories.

Generalized thermo-elastic interaction in a fiber-reinforced material with spherical holes

  • Hobiny, Aatef D.;Abbas, Ibrahim A.
    • Structural Engineering and Mechanics
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    • v.78 no.3
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    • pp.297-303
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    • 2021
  • In this paper, a mathematical model is used to the evaluation of thermoelastic interactions in fiber-reinforced material with a spherical cavity. With the goal of establishing the generalized thermoelastic model with thermal relaxation time are exploited. inner surface of the spherical cavity is tractions free and loaded by the uniform step in temperature. The finite element scheme is used to get the problem numerical solutions. The numerical results have been discussed graphically to show the impacts of the presence and the absence of reinforcement.

Computational Study on the Heat Transfer Prediction Hypersonic Flows (극초음속 유동의 열전달 예측에 관한 수치해석적 연구)

  • Nagdewe, Suryakant;Kim, H.D.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.27-30
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    • 2007
  • In recent years, scientific community has found renewed interest in hypersonic flight research. These hypersonic vehicles undergo severe aero-thermal environments during their flight regimes. One of the most important topics of research in hypersonic aerodynamics is to find a reasonable way of calculating either the surface temperature or the heat flux to surface when its temperature is held fixed. This requires modeling of physical and chemical processes. Hyperbolic system of equations with stiff relaxation method are being identified in recent literature as a novel method of predicting long time behavior of systems such as gas at high temperatures. In present work, Energy Relaxation Method (ERM) has been considered to simulate the real gas flow over a 2-D cylinder. Present heat flux results over the cylinder compared well with the experiment. Thus, real gas effects in hypersonic flows can be modeled through energy relaxation method.

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Boosting up the photoconductivity and relaxation time using a double layered indium-zinc-oxide/indium-gallium-zinc-oxide active layer for optical memory devices

  • Lee, Minkyung;Jaisutti, Rawat;Kim, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.278-278
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    • 2016
  • Solution-processed metal-oxide semiconductors have been considered as the next generation semiconducting materials for transparent and flexible electronics due to their high electrical performance. Moreover, since the oxide semiconductors show high sensitivity to light illumination and possess persistent photoconductivity (PPC), these properties can be utilized in realizing optical memory devices, which can transport information much faster than the electrons. In previous works, metal-oxide semiconductors are utilized as a memory device by using the light (i.e. illumination does the "writing", no-gate bias recovery the "reading" operations) [1]. The key issues for realizing the optical memory devices is to have high photoconductivity and a long life time of free electrons in the oxide semiconductors. However, mono-layered indium-zinc-oxide (IZO) and mono-layered indium-gallium-zinc-oxide (IGZO) have limited photoconductivity and relaxation time of 570 nA, 122 sec, 190 nA and 53 sec, respectively. Here, we boosted up the photoconductivity and relaxation time using a double-layered IZO/IGZO active layer structure. Solution-processed IZO (top) and IGZO (bottom) layers are prepared on a Si/SiO2 wafer and we utilized the conventional thermal annealing method. To investigate the photoconductivity and relaxation time, we exposed 9 mW/cm2 intensity light for 30 sec and the decaying behaviors were evaluated. It was found that the double-layered IZO/IGZO showed high photoconductivity and relaxation time of 28 uA and 1048 sec.

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Methods in Palaeomagnetism (I) (고자기학(古磁氣學)의 방법(方法) (I))

  • Kim, In-Soo
    • Economic and Environmental Geology
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    • v.17 no.2
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    • pp.141-147
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    • 1984
  • For the discussion of palaeogeomagnetic field direction and the movement and rotation of geotectonic blocks it is prerequisite to eliminate the secondary remanent magnetization component out of the NRM vector of given rock samples. Among various techniques alternating field and thermal demagnetization methods are most easily applicable and most widely used ones. Physical principle underlying these methods is the concept of relaxation time: Either with an action of external magnetic field or with an elevated temperature relaxation time of magnetic minerals can be drastically shortened. It has been furthermore shown experimentally that the secondary remanent magnetization can be more easily demagnetized than the primary remanent magnetization. Through careful stepwise demagnetization it should also be possible to discriminate the kind of various remanent magnetizations. In addition to the introduction to the underlying physical principles and experimental results of the alternating field and thermal demagnetization this paper gives various practical tips in earring out the demagnetization experiments. Each alternating field and thermal demagnetization instrumentation which is easily adaptable to domestic palaeomagnetic laboratories is also introduced. This paper provides a compact and practical introduction to the methods in palaeomagnetism and would be of interest to present workers and to those who want to embark on research in this field.

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The heat transfer characteristics of viscoelastic non-newtonian fluids in the entrance region of circular tube flows (원형관속을 유동하는 점탄성 유체의 입구 영역 열전달 특성에 관한 연구)

  • 엄정섭;황태성;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.1032-1043
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    • 1989
  • The heat transfer characteristics of the drag reducing polymer solutions are investigated experimentally in the thermal entrance region of circular tube flows. Fluids used in experiments are the aqueous solutions of high molecular polymer, polyacrylamide Separan AP-273 and the range of polymer concentrations is from 20 to 1000 wppm. Two stainless steel tubes with inside diameter 8.5mm(L/D=712) and 10.3mm(L/D=1160) are used for the heat transfer flow loops. The flow loop is set up to measure friction factors and heat transfer coefficients of test sections in two different modes; the recirculating flow system and once-through flow system. The test tubes are heated directly by electricity to apply the constant heat flux boundary conditions to the wall. Three different types of adaptors are used to observe the effects of the upstream flow conditions of the heat transfer test sections. The viscosity and characteristic relaxation time of the test fluids circulating in the flow system are measured by the capillary tube viscometer and falling ball viscometer at regular time intervals. The installed adaptors exhibit slight effect on the entrance heat transfer of Newtonian fluid. However, no noticeable effects are observed for the entrance heat transfer of the drag reducing fluids. The order of magnitude of the thermal entrance lengths of the drag reducing fluids which follow the minimum friction asymptote is much longer than that of Newtonian fluids in turbulent flows. A new dimensionless parameter, the viscoelastic Graetz number, is defined and all the experimental data are recasted in terms of the viscoelastic Graetz number. The local Nusselt number of the viscoelastic fluids is represented as a function of flow behavior index n and the viscoelastic Graetz number. As degradation continues the viscosity and the characteristic relaxation time of the testing fluids decrease. Weissenberg number defined by the relaxation time and D/V appears to be a proper dimensionless parameter in describing degradation effects on heat transfer of the viscoelastic fluids.

Structural Dynamics of Myoglobin Probed by Femtosecond Infrared Spectroscopy of the Amide Band

  • Kim, Seong-Heun;Jin, Geun-Young;Lim, Man-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1470-1474
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    • 2003
  • The dynamics of the tertiary conformation of myoglobin (Mb) after photolysis of carbon monoxide was investigated at 283 K solution by probing amide I and II bands using femtosecond IR absorption spectroscopy. Time-resolved spectra in the amide region evolve with 6-12 ps time scale without noticeable subpicosecond dynamics. The spectra measured at 100 ps delay after photolysis is similar to the difference FTIR spectrum at equilibrium. Time-resolved spectra of photoexcited Mb evolve modestly and their amplitudes are less than 8% of those of photolyzed MbCO, indicating that thermal contribution to the spectral evolution in the amide region is negligible. These observations suggest that the conformational relaxation ensuing photolysis of MbCO be complex and the final deoxy protein conformation have been substantially formed by 100 ps, probably with 6- 12 ps time constant.

INVESTIGATION OF TRIPLET STATE AND SINGLET OXYGEN DYNAMICS OF BENZOPHENONE IN POLAR AND NONPOLAR SOLUTIONS WITH TIME-RESOLVED TWO-COLOR THERMAL LENSING METHOD

  • Ha, Jeong-Hyon
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.141-145
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    • 1996
  • The heat generated by nonradiative decay dynamics induces thermal lens effect. From such an effect, photodynamic properties of solutions can be investigated with two-color pulsed thermal lens experiments which have the time resolution of down to nanoseconds. In this study, using nanosecond two-color thermal lens method, we investigated the triplet state of benzophenone and the singlet oxygen state dynamics in various oxygen concentration solvents. The measured triplet state lifetimes, singlet oxygen relaxation times and singlet oxygen formation quantum yields are in good agreement with the reference values. From these parameters the existence of the triplet exciplex formation between benzophenone and benzene is proved, and it is also suggested that the relaxations of triplet states of benzophenone undergo coupled dynamics with some of singlet oxygens in oxygen-rich conditions.

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A Viscoelasitc Finite Element Analysis of Thermal Nanoimprint Lithography Process (열-나노임프린트 공정의 점탄성 유한요소해석)

  • Kim, Nam-Woong;Kim, Kug-Weon;Sin, Hyo-Chol
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.1-7
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    • 2007
  • Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. To successfully imprint a nano-sized pattern, the process conditions such as temperature, pressure, and time should be appropriately selected. This starts with a clear understanding of polymer material behavior during the NIL process. In this work, the squeezing of thin polymer films into nanocavities during the thermal NIL has been investigated based upon a two-dimensional viscoelastic finite element analysis in order to understand how the process conditions affect a pattern quality. The simulations have been performed within the viscoelastic plateau region and the stress relaxation effect has been taken into account.

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