• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.821-827
• /
• 1995

Polychlorodibenzo-p-dioxins(PCDDs) have been prepared by microsacale pyrolysis of trichlorophenates. During the pyrolysis reaction, dechlorinated dibenzo-p-dioxins were also formed by the thermolysis of PCDDs. The dechlorination pathways of PCDDs were suggested in this reaction. The identification of these products was performed using capillary column gas chromatography-mass spectrometry.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10b
• /
• pp.934-939
• /
• 1998

This study discusses the results of adiabatic temperature rise tests which were performed considering various parameters, such as cement type, water-cement ratio, unit cement weigh, admixtures and placing temperature, which influence the temperature rise(K) and reaction velocity ($\alpha$). Theadiabatic temperature rise models obtained from this study are similar to those of Japan Concrete Institute. The models to calculate temperature rise and reaction velocity could be used the analysis f concrete thermal stress.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2005.11b
• /
• pp.141-148
• /
• 2005

Pt/SDBC catalyst, which is used for the hydrogen-water isotopic exchange reaction, was prepared. The various properties of the catalyst, such as the thermal stability, pore structure and the platinum dispersion, were investigated. A hydrophobic Pt/SDBC catalyst which has been developed for the LPCE column of the WTRF (Wolsong Tritium Removal Facility) was tested in a trickle bed reactor. An experimental apparatus was built for the test of the catalyst at various temperatures and gas velocities.

• Archives of Pharmacal Research
• /
• v.13 no.1
• /
• pp.5-8
• /
• 1990

The cycloaddition of the newely synthesized 5-(2-thienyl)methylene derivatives of thiazolidinone-4-thiones, 2a-c to acrylonitrile (3a), ethylacrylate (3b), N-phenylmaleimide (6) and dimethyl fumarate (8) has been evaluated. Under thermal reaction conditions [4 +2] cycloaddition proceeds with complete site and regioselectivity to yield the cycloadduct, 4, 5, 7 and 9, respectively. The antimicrobial activities of some of the new products were tested.

• 한국전기화학회:학술대회논문집
• /
• 2005.07a
• /
• pp.173-176
• /
• 2005

• 제어로봇시스템학회:학술대회논문집
• /
• 1996.10b
• /
• pp.788-791
• /
• 1996

A mathematical model is developed for thermal solution copolymerization of styrene and acrylonitrile in a continuous stirred tank reactor(CSTR). Computational studies are carried out with the continuous copolymerization system model developed in this work to give the monomer conversion, copolymer composition and the average molecular weights of the copolymer. By performing the dynamic analysis of the reaction system, the polymer properties against the changes in the operating conditions are determined quantitatively. The cascade PID and fuzzy controller show satisfactory performances for both set point tracking and disturbance rejection. Especially, the fuzzy controller is superior to the PID controller.

• Journal of Industrial Technology
• /
• v.24 no.B
• /
• pp.65-71
• /
• 2004

The ultra fine gamma-alumina powder was prepared via ammonium aluminium carbonate hydroxide (AACH). The XRD, SEM, BET, thermal analysis were used to characterize the samples. The effects of various reaction parameters as concentration, of solution, anion on specific area, PH, aging time and thermal decomposition condition on the produced AACH and alumina were discussed.

• Bulletin of the Korean Chemical Society
• /
• v.7 no.6
• /
• pp.425-428
• /
• 1986

A new heterocuprate containing 2-pyridyloxy ligand, lithium 2-pyridyloxy-n-butylcuprate, has shown improved thermal stability and it reacts with acid chlorides to afford the corresponding ketones in high yields. Similarly, it can be effectively utilized in conjugate addition reactions of $\alpha,\beta$-unsaturated ketones. Of synthetic significance is that the complete utilization of n-butyl group in lithium 2-pyridyloxy-n-butylcuprate has been observed.

• Journal of the Korean Society of Combustion
• /
• v.10 no.3
• /
• pp.17-24
• /
• 2005

A sub-millimeter scale catalytic combustor with a simple plate-shaped combustion chamber was fabricated. A porous ceramics support coated with platinum catalyst was placed in the chamber. The combustor has a gallium arsenide window on the top that is transparent to infrared ray. The temperature distribution in the combustion chamber was measured using infrared thermal imager while hydrogen-air premixture is steadily supplied to the combustor. The area where the catalytic reaction took place broaden for higher flow rate and lower equivalence ratio made activated area in the combustion chamber broaden. The amount of coated platinum catalyst did not affect the reaction. Stop of reaction, which is similar to flame quenching of conventional combustion, was investigated. Large content of heat generation and broad activated area are essential criteria to prevent stop of reaction that has a bad effect on the combustor performance.

• Journal of the Korean Ceramic Society
• /
• v.21 no.1
• /
• pp.67-73
• /
• 1984

A stable intercalation complex was formed by adsorption of alcanol (ROH, R; $C_{10}H_2$, $C_{12}H_{25}$, $C_{14}H_{29}$) on the surfaces of Yongil bentonite in which the interlayer cation had been exchanged by n-decylammonium ion $(C_{10}H_{21}NH_3^+)$ The layer charge density calculated from the increaments of basal spacings was 0.34 per unit chemical formula. Thermochemical properties of synthesized $C_{10}H_{21}NH_3^+$ montmorillonite were studied by means of DSC, TGA, DTG, Thermal analysis showed two steps of desoption behavior of $C_{10}H_{21}NH_3^+$ ion namely nonyl $(CH_3(CH_2)_8$ decomposition reaction of 40$0^{\circ}C$ and methyleneammonium decomposition reaction of 78$0^{\circ}C$ The activation energy of nonyl decomposition reaction of $C_{10}H_{21}NH_3^+$ -montmorillonite respectively.