• 제목/요약/키워드: Thermal Process

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축열식 소각로의 화재.폭발 사고원인 규명 연구 (A Study on Fire and Explosion Accident Cause in Regenerated Thermal Oxidizer)

  • 이근원;마병철;황순용
    • 한국가스학회지
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    • 제11권4호
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    • pp.7-11
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    • 2007
  • 축열식 소각로에서 화재폭발 사고보고서가 있었다. 본 논문은 수지 재처리공정에서 축열식 소각로의 사고원인을 조사하였다. 실험은 인화점 시험기, 폭발한계장치, 자동발화 시험기, 가스크로마토그래프를 사용한 물리화학적 특성과 열안정성시험기 활용한 열안정성을 분석하였다. 축열식 소각로를 가동하는 공정의 사고예방을 위해 화재폭발 사고원인을 규명하였다.

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서로 다른 열환경에 노출된 고분자 소재의 열팽창계수 측정에 관한 연구 (A study on the Measurement of the Coefficient of Thermal Expansion of Polymer materials Exposed to Different Thermal Environments)

  • 김동주;박설현
    • 한국기계가공학회지
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    • 제20권4호
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    • pp.80-86
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    • 2021
  • Plastics are widely used in mechanical and other fields due to their light weight, design flexibility, and molding processability. In processing plastics, defective products are mixed and reprocessed to improve production efficiency and reduce costs. In this study, an experiment was conducted to confirm the coefficient of thermal expansion of HDPE during this reprocessing. The coefficient of thermal expansion was measured at different measurement directions and heating rates. As a result, we observed that the coefficient of thermal expansion in the direction perpendicular to the injection direction is greater than that in the horizontal direction.

쉘요소를 활용한 원통형 구조물의 좌굴에 대한 열적 영향평가 (Thermal Impact Evaluation on Buckling of Cylindrical Structures Using Shell Elements)

  • 조희근
    • 한국기계가공학회지
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    • 제20권1호
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    • pp.7-15
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    • 2021
  • Buckling of cylindrical structures has been extensively researched, because it is an important phenomenon to be considered in structural design. However, the evaluation of thermal effects on the buckling of cylindrical structures has been insufficient; therefore, this study evaluates this thermal effect using shell elements. In addition, the thermal effect on the buckling of temperature-dependent nonlinear materials was evaluated. Nonlinear and linear buckling analyses were performed using the arc-length method to investigate the behavioral characteristics of a cylindrical structure. The basic theory of the linear buckling analysis of a cylindrical structure subjected to thermal stress was derived and presented by applying the thermal stress basic theory.

저온 플라즈마 공정을 이용한 상용설비의 배연가스 처리 기술개발 (Technical Development of Flue Gas Control at Commercial Plant Using the Non-thermal Plasma Process)

  • 유정석;백민수;김태희;김정일;김유석;최석호
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.939-944
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    • 2001
  • For the application of simultaneous $DeSO_{2}\;&\;DeNO_{x}$ equipment using non-thermal plasma process to the industrial and power plants, the many types of plasma device and process were studied. The e-beam and pulsed plasma corona discharge process are outstanding for the study to apply commercial large-scale plant from among these. In this paper, non-thermal plasma of technical trends and the characteristics of system developed by Doosan heavy industries & construction Co., Ltd. are explained. We have researched pulsed plasma corona discharge process since 1994. At the basis of reasonable results for the pilot plant, we constructed the demonstration plant at a domestic coal-fired power plant in 1999, as the previous step for commercial use. In near future, enough information about designs and costs of commercial-size system will be obtained.

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Methylthioisocyanate 합성반응 공정의 열적위험 특성 (Characteristics of Thermal Hazard in Methylthioisocyanate Synthesis Reaction Process)

  • 한인수;이근원;이주엽
    • 한국안전학회지
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    • 제27권5호
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    • pp.77-87
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    • 2012
  • Compared to a batch reactor, where all reactants are initially charged to the reactor, the semi-batch reactor presents serious advantages. The feed of at least one of the reactants provides an additional way of controlling the reaction course, which represents a safety factor and increases the constancy of the product quality. The aim of this study was to investigate the characteristics of thermal hazard such as a feed time, catalysis concentration and solvent concentration in methylthioisocyanate(MTI) synthesis reaction process. The experiments were carried out by the Multimax reactor system and Accelerating rate calorimeter(ARC). The MTI synthesis reaction process has many reaction factors and complicated reaction mechanism of multiphase reaction. Through this study, we can use as a tool for assessment of thermal hazard of other reaction processes by applying experiment method provided.

실험계획법에 의한 니켈기 경질 용사코팅의 최적 공정 설계 (Process Optimization for Thermal-sprayed Ni-based Hard Coating by Design of Experiments)

  • 김균택;김영식
    • 동력기계공학회지
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    • 제13권5호
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    • pp.89-94
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    • 2009
  • In this work, the optimal process has been designed by $L_9(3^4)$ orthogonal array and analysis of variance(ANOVA) for thermal-sprayed Ni-based hard coating. Ni-based hard coatings were fabricated by flame spray process on steel substrate. Then, the hardness test and observation of microstructure of the coatings were performed. The results of hardness test were analyzed by ANOVA. The ANOVA results demonstrated that the acetylene gas flow had the greatest effect on hardness of the coatings. The oxygen gas flow was found to have a neglecting effect. From these results, the optimal combination of the flame spray parameters could be predicted. The calculated hardness of the coatings by ANOVA was found to lie close to that of confirmation experimental result. Thus, it was considered that design of experiments design using orthogonal array and ANOVA was useful to determine optimal process of thermal-sprayed Ni-based hard coating.

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Synthesis of polyphenylcarbosilane via thermal rearrangement of polymethylphenylsilane in supercritical cyclohexane

  • Shin, Hee-Yong;Ryu, Jae-Hun;Bae, Seong-Youl;Lee, Yoon-Joo;Kwon, Woo-Teck;Kim, Young-Hee;Kim, Soo-Ryong
    • 한국응용과학기술학회지
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    • 제30권1호
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    • pp.9-15
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    • 2013
  • A new process for the synthesis of polyphenylcarbosilane (PPCS) via thermal rearrangement of polymethylphenylsilane (PMPS) in supercritical cyclohexane was proposed and investigated at reaction temperatures of $380-420^{\circ}C$, reaction times of 1-2 h, and a pressure of 15 MPa. The structure, molecular weight, and molecular weight distribution of the product were characterized by FT-IR, Si-NMR, and GPC. The ceramic yield was also measured by TGA analysis. High-quality PPCS with high molecular weight and ceramic yield can be synthesized via a supercritical process. Furthermore, this process, when compared to the conventional method, tends to moderate the reaction conditions such as reaction temperature and time. It is concluded that thermal rearrangement in supercritical fluid is an efficient and viable process in terms of the resulting yield, efficiency, and reaction time compared with those of the conventional PCS production process.

RTO 공정을 이용한 다공질 실리콘막의 저온 산화 및 특성분석 (Characterization of Oxidized Porous Silicon Film by Complex Process Using RTO)

  • 박정용;이종현
    • 대한전자공학회논문지SD
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    • 제40권8호
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    • pp.560-564
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    • 2003
  • 본 논문에서는 RTP(rapid thermal process)를 이용한 새로운 산화방법을 고안했으며, 이는 짧은 시간에 다공질 실리콘을 산화시킴으로써 이 기술은 여타 방법에 비해 경제적이고 간편한 방법으로 짧은 시간에 두꺼운 산화막을 성장시킬 수 있는 장점을 가지고 있다. 먼저, 양극반응을 통해 PSL(porous silicon layer)을 형성한 후 이를 저온 산화시킨 후에 급속 열처리 산화공정(RTO: rapid thermal oxidation)를 이용해서 OPSL(oxidized porous silicon layer)을 제조하고, 그 물성 및 전기적 특성을 조사하여, 열 산화로 제작된 OPSL과 그 특성을 비교하였다. 시편의 절연 파괴전압은 약 3.9 MV/cm의 값을 보여 벌크 산화막보다는 적은 값이지만 절연 재료로서는 충분한 값이고, 누설전류는 0 ∼ 50 V의 인가 전압에서 100 ∼ 500 ㎀의 값을 보였다. 그리고, XPS 결과는 RTO 공정 추가가 저온 산화막의 완전 산화에 크게 기여함을 확인하였으며, 저온 산화막의 표면 및 내부에서도 산화반응이 완전하게 이루어졌음을 확인하였다. 이 결과로부터 저온 OPSL을 제조할 때, RTO 공정이 OPSL의 산화 및 치밀화(densification)의 증가에 크게 기여함을 알 수 있었다. 따라서, 이의 방법으로 제조된 OPSL은 저온을 요구하는 공정에서 소자의 절연막, 전기적인 분리층 그리고 실리콘 고주파용 기판 등으로 활용될 수 있을 것으로 보인다.

금형주조기를 이용한 알루미늄 합금 금형의 수치해석적 열변형 해석과 실험에 관한 연구 (Numerical and Experimental Studies on Thermal Strain Analysis of Al Alloy Casting Mold using Metal Foundry)

  • 오율권;김용범;윤희성
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2050-2054
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    • 2007
  • This study numerically and experimentally investigated on thermal strain analysis of aluminum alloy casting mold using metal foundry. To predict the numerical result of thermal strain in Al alloy casting mold during the cooling process, it is performed the investigation of temperature distribution, stress and displacement based on the physical properties of Al alloy. In results of this study, Al alloy casting mold represented rapidly cooling graph during initial 20minutes after beginning cooling process, therefore value of stress and displacement is rapidly changed during initial 20minutes after beginning cooling process. In addition to, temperature distribution obtained by experiment confirmed corresponding pattern then compared numerical analysis with experiment. These results are distribute to make the effective and the high precision casting mold.

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일방향 주기적 진동하는 원통 내의 유동 및 열전달 연구 (A Study on Flow and Heat Transfer in One Directional Periodic-Oscillating Cylinder)

  • 박준상
    • 한국유체기계학회 논문집
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    • 제13권5호
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    • pp.22-28
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    • 2010
  • A study has been made of cool-down process on an incompressible fluid contained in a periodically oscillating cylinder when an abrupt cooling of wall temperature is imposed. Characteristics of flow and heat transfer are investigated along the variations of oscillating frequency and amplitude. One found the flow regimes are divided into 4-modes : 1 thermal island mode, 2 thermal island mode, 4 thermal island mode and asymmetry mode. Comprehensive analysis for each mode are given with a physical mechanism on cool-down process.