• Title/Summary/Keyword: Thermal Process

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A Study on Fire and Explosion Accident Cause in Regenerated Thermal Oxidizer (축열식 소각로의 화재.폭발 사고원인 규명 연구)

  • Lee, Keun-Won;Ma, Byung-Chol;Hwang, Soon-Yong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.7-11
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    • 2007
  • There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

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A study on the Measurement of the Coefficient of Thermal Expansion of Polymer materials Exposed to Different Thermal Environments (서로 다른 열환경에 노출된 고분자 소재의 열팽창계수 측정에 관한 연구)

  • Kim, Dong-Ju;Park, Seul-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.4
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    • pp.80-86
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    • 2021
  • Plastics are widely used in mechanical and other fields due to their light weight, design flexibility, and molding processability. In processing plastics, defective products are mixed and reprocessed to improve production efficiency and reduce costs. In this study, an experiment was conducted to confirm the coefficient of thermal expansion of HDPE during this reprocessing. The coefficient of thermal expansion was measured at different measurement directions and heating rates. As a result, we observed that the coefficient of thermal expansion in the direction perpendicular to the injection direction is greater than that in the horizontal direction.

Thermal Impact Evaluation on Buckling of Cylindrical Structures Using Shell Elements (쉘요소를 활용한 원통형 구조물의 좌굴에 대한 열적 영향평가)

  • Cho, Hee-Keun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.1
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    • pp.7-15
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    • 2021
  • Buckling of cylindrical structures has been extensively researched, because it is an important phenomenon to be considered in structural design. However, the evaluation of thermal effects on the buckling of cylindrical structures has been insufficient; therefore, this study evaluates this thermal effect using shell elements. In addition, the thermal effect on the buckling of temperature-dependent nonlinear materials was evaluated. Nonlinear and linear buckling analyses were performed using the arc-length method to investigate the behavioral characteristics of a cylindrical structure. The basic theory of the linear buckling analysis of a cylindrical structure subjected to thermal stress was derived and presented by applying the thermal stress basic theory.

Technical Development of Flue Gas Control at Commercial Plant Using the Non-thermal Plasma Process (저온 플라즈마 공정을 이용한 상용설비의 배연가스 처리 기술개발)

  • Yoo, J.S.;Paek, M.S.;Kim, T.H.;Kim, J.I.;Kim, Y.S.;Choi, S.H.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.939-944
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    • 2001
  • For the application of simultaneous $DeSO_{2}\;&\;DeNO_{x}$ equipment using non-thermal plasma process to the industrial and power plants, the many types of plasma device and process were studied. The e-beam and pulsed plasma corona discharge process are outstanding for the study to apply commercial large-scale plant from among these. In this paper, non-thermal plasma of technical trends and the characteristics of system developed by Doosan heavy industries & construction Co., Ltd. are explained. We have researched pulsed plasma corona discharge process since 1994. At the basis of reasonable results for the pilot plant, we constructed the demonstration plant at a domestic coal-fired power plant in 1999, as the previous step for commercial use. In near future, enough information about designs and costs of commercial-size system will be obtained.

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Characteristics of Thermal Hazard in Methylthioisocyanate Synthesis Reaction Process (Methylthioisocyanate 합성반응 공정의 열적위험 특성)

  • Han, In-Soo;Lee, Keun-Won;Lee, Joo-Yeob
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.77-87
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    • 2012
  • Compared to a batch reactor, where all reactants are initially charged to the reactor, the semi-batch reactor presents serious advantages. The feed of at least one of the reactants provides an additional way of controlling the reaction course, which represents a safety factor and increases the constancy of the product quality. The aim of this study was to investigate the characteristics of thermal hazard such as a feed time, catalysis concentration and solvent concentration in methylthioisocyanate(MTI) synthesis reaction process. The experiments were carried out by the Multimax reactor system and Accelerating rate calorimeter(ARC). The MTI synthesis reaction process has many reaction factors and complicated reaction mechanism of multiphase reaction. Through this study, we can use as a tool for assessment of thermal hazard of other reaction processes by applying experiment method provided.

Process Optimization for Thermal-sprayed Ni-based Hard Coating by Design of Experiments (실험계획법에 의한 니켈기 경질 용사코팅의 최적 공정 설계)

  • Kim, K.T.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.13 no.5
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    • pp.89-94
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    • 2009
  • In this work, the optimal process has been designed by $L_9(3^4)$ orthogonal array and analysis of variance(ANOVA) for thermal-sprayed Ni-based hard coating. Ni-based hard coatings were fabricated by flame spray process on steel substrate. Then, the hardness test and observation of microstructure of the coatings were performed. The results of hardness test were analyzed by ANOVA. The ANOVA results demonstrated that the acetylene gas flow had the greatest effect on hardness of the coatings. The oxygen gas flow was found to have a neglecting effect. From these results, the optimal combination of the flame spray parameters could be predicted. The calculated hardness of the coatings by ANOVA was found to lie close to that of confirmation experimental result. Thus, it was considered that design of experiments design using orthogonal array and ANOVA was useful to determine optimal process of thermal-sprayed Ni-based hard coating.

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Synthesis of polyphenylcarbosilane via thermal rearrangement of polymethylphenylsilane in supercritical cyclohexane

  • Shin, Hee-Yong;Ryu, Jae-Hun;Bae, Seong-Youl;Lee, Yoon-Joo;Kwon, Woo-Teck;Kim, Young-Hee;Kim, Soo-Ryong
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.9-15
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    • 2013
  • A new process for the synthesis of polyphenylcarbosilane (PPCS) via thermal rearrangement of polymethylphenylsilane (PMPS) in supercritical cyclohexane was proposed and investigated at reaction temperatures of $380-420^{\circ}C$, reaction times of 1-2 h, and a pressure of 15 MPa. The structure, molecular weight, and molecular weight distribution of the product were characterized by FT-IR, Si-NMR, and GPC. The ceramic yield was also measured by TGA analysis. High-quality PPCS with high molecular weight and ceramic yield can be synthesized via a supercritical process. Furthermore, this process, when compared to the conventional method, tends to moderate the reaction conditions such as reaction temperature and time. It is concluded that thermal rearrangement in supercritical fluid is an efficient and viable process in terms of the resulting yield, efficiency, and reaction time compared with those of the conventional PCS production process.

Characterization of Oxidized Porous Silicon Film by Complex Process Using RTO (RTO 공정을 이용한 다공질 실리콘막의 저온 산화 및 특성분석)

  • 박정용;이종현
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.8
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    • pp.560-564
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    • 2003
  • Thick oxide layer was fabricated by anodic reaction and complex oxidation performed by combining low temperature thermal oxidation (50$0^{\circ}C$, 1 hr at $H_2O$/O$_2$) and a RTO (rapid thermal oxidation) process (105$0^{\circ}C$, 1 min). Electrical characteristics of OPSL (oxidized porous silicon layer) were almost the same as those of thermal silicon dioxide prepared at high temperature. The leakage current through the OPSL of 20${\mu}{\textrm}{m}$ thickness was about 100 - 500 ㎀ in the range 0 V to 50 V. The average value of breakdown field was about 3.9 MV/cm. From the XPS analysis, surface and internal oxide films of OPSL prepared by complex process were confirmed completely oxidized and also the role of RTO process was important for the densification of PSL (porous silicon layer) oxidized at low temperature.

Numerical and Experimental Studies on Thermal Strain Analysis of Al Alloy Casting Mold using Metal Foundry (금형주조기를 이용한 알루미늄 합금 금형의 수치해석적 열변형 해석과 실험에 관한 연구)

  • Oh, Yool-Kwon;Kim, Yong-Bum;Yoon, Hee-Sung
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2050-2054
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    • 2007
  • This study numerically and experimentally investigated on thermal strain analysis of aluminum alloy casting mold using metal foundry. To predict the numerical result of thermal strain in Al alloy casting mold during the cooling process, it is performed the investigation of temperature distribution, stress and displacement based on the physical properties of Al alloy. In results of this study, Al alloy casting mold represented rapidly cooling graph during initial 20minutes after beginning cooling process, therefore value of stress and displacement is rapidly changed during initial 20minutes after beginning cooling process. In addition to, temperature distribution obtained by experiment confirmed corresponding pattern then compared numerical analysis with experiment. These results are distribute to make the effective and the high precision casting mold.

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A Study on Flow and Heat Transfer in One Directional Periodic-Oscillating Cylinder (일방향 주기적 진동하는 원통 내의 유동 및 열전달 연구)

  • Park, Jun-Sang
    • The KSFM Journal of Fluid Machinery
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    • v.13 no.5
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    • pp.22-28
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    • 2010
  • A study has been made of cool-down process on an incompressible fluid contained in a periodically oscillating cylinder when an abrupt cooling of wall temperature is imposed. Characteristics of flow and heat transfer are investigated along the variations of oscillating frequency and amplitude. One found the flow regimes are divided into 4-modes : 1 thermal island mode, 2 thermal island mode, 4 thermal island mode and asymmetry mode. Comprehensive analysis for each mode are given with a physical mechanism on cool-down process.